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2. 发明专利

JP2017128556A 有機塩素化合物を分解し無害化する方法审中-公开
公开(公告)号：JP2017128556A
公开(公告)日：2017-07-27
申请号：JP2016018376
申请日：2016-01-18
申请人：澤田重美
发明人：澤田重美
IPC分类号： C07B37/06 , C07C25/18 , C07C1/26 , C07C15/14 , A62D3/37 , A62D101/22 , A62D101/28 , C07B35/06
摘要：【課題】化学的に安定なPCB等の有機塩素化合物を分解し、無害化する方法を提供。【解決手段】常温常圧下でクエン酸とマグネシウムで活性水素を発生させて還元反応により、有機塩素化合物を分解し、無害化する。【選択図】なし

3. 发明专利

JP5615781B2 ハロゲン化合物含有油の無害化処理方法及び無害化処理装置有权
标题翻译：解毒方法和含有油解毒设备卤素化合物
公开(公告)号：JP5615781B2
公开(公告)日：2014-10-29
申请号：JP2011196592
申请日：2011-09-08
申请人：中国電力株式会社
发明人：賢治徳政 , 賢治徳政
IPC分类号： A62D3/34 , B01J8/20 , C07B35/06 , C07C25/18

4. 发明专利

JP5545950B2 Hazardous substances containing liquid processing equipment 有权
公开(公告)号：JP5545950B2
公开(公告)日：2014-07-09
申请号：JP2009281009
申请日：2009-12-10
申请人：オリエンタル機電株式会社
发明人：強大石 , 俊介細川
IPC分类号： A62D3/19 , C07B35/06 , C07B37/06

5. 发明专利

JP5377413B2 Detoxification method of Pcb contaminated insulating oil 有权
公开(公告)号：JP5377413B2
公开(公告)日：2013-12-25
申请号：JP2010129602
申请日：2010-06-07
申请人：中国電力株式会社
发明人：賢治徳政
IPC分类号： A62D3/34 , A62D101/22 , C07B35/06
CPC分类号： Y02W30/821
摘要： PROBLEM TO BE SOLVED: To provide a method of de-toxifying PCB mixed-in insulating oil, preventing trouble or bad influence caused by the PCB mixed-in insulating oil containing impurity to stably de-toxify the PCB mixed-in insulating oil. SOLUTION: According to the method of de-toxifying the PCB mixed-in insulating oil, the PCB mixed-in insulating oil containing impurity is taken as oil to be processed, and after water contained in the oil to be processed is removed, metallic sodium and PCB are caused to react with each other to thereby de-toxify the oil to be processed. The impurity is oxidized alteration oil, and one or more selected from a metal oxide, a metal hydroxide and carbonate are added to the oil to be processed before removing water contained therein at the latest. COPYRIGHT: (C)2012,JPO&INPIT

6. 发明专利

JP5368201B2 Processing methods and apparatus of chemical pollution 有权
公开(公告)号：JP5368201B2
公开(公告)日：2013-12-18
申请号：JP2009169843
申请日：2009-07-21
申请人：オルガノ株式会社
发明人：岳志野本 , 正浩江口
IPC分类号： B09C1/02 , A62D3/30 , A62D101/22 , B09C1/08 , C02F1/72 , C07B35/06 , C07B37/06 , C07C15/04 , C07C21/10
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for treating chemical substance contamination, with which the chemical substances can be more safely and more efficiently treated as compared with the conventional treatment with persulfate, in cleaning the soil and ground water contaminated with chemical substances, particularly, a chlorinated organic compound or an aromatic hydrocarbon. SOLUTION: The method for treating chemical substance contamination includes a step of adding persulfate and chelated iron to the soil and ground water contaminated with chemical substances and a step of cleaning the contaminated soil and ground water. Persulfate and chelated iron are added so that the concentration of the added persulfate becomes ≥5,000 mg/L and the molar ratio (the persulfate/the iron) of the added persulfate to the added iron becomes ≥5. COPYRIGHT: (C)2011,JPO&INPIT

7. 发明专利

JP2013202314A Method and apparatus for decomposing organic halogen compound 审中-公开
标题翻译：用于分解有机卤化物的方法和装置
公开(公告)号：JP2013202314A
公开(公告)日：2013-10-07
申请号：JP2012077146
申请日：2012-03-29
申请人： Tokyo Electric Power Co Inc:The , 東京電力株式会社 , Tokyo Energy & Systems Inc , 株式会社東京エネシス
发明人： SHIMOJO MIKIO , KANAMORI SATORU , FURUHASHI TETSUTARO , OGAWA HITOSHI , ITO KOICHI , OTSUKI SHIGERU , KUSUNOKI TOSHIHARU
IPC分类号： A62D3/30 , A62D3/178 , A62D101/22 , C07B35/06 , C07B37/06 , C07B61/00 , C07C25/18
摘要： PROBLEM TO BE SOLVED: To provide a method for decomposing an organic halogen compound and a decomposing apparatus, capable of decomposing an organic halogen compound remaining in a container of a large transformer in which a large amount of organic halogen compound contained in one batch of treatment liquid should be decomposed without causing fixation of a catalyst.SOLUTION: A method for decomposing an organic halogen compound includes: adding a hydrogen donor and an alkali compound to an organic halogen compound to prepare a mixed liquid; taking out all or some of the mixed liquid; allowing the taken mixed liquid to circulate in a catalyst-filled device; and irradiating the mixed liquid circulating in the catalyst-filled device with a microwave to decompose the organic halogen compound. In this method, the catalyst-filled device is formed by stacking a filling member layer on the top and an organic halogen compound decomposition catalyst layer on the bottom. The mixed liquid is introduced from the upper part of the catalyst layer on the top and discharged through the filling member layer on the bottom. A decomposing device is used for the method.
摘要翻译：要解决的问题：提供一种有机卤素化合物和分解装置的分解方法，其能够分解保留在一次处理中所含的大量有机卤素化合物的大型变压器的容器中的有机卤素化合物分解有机卤素化合物的方法包括：向有机卤素化合物中加入氢供体和碱化合物以制备混合液体; 取出全部或部分混合液体; 使得所采集的混合液体在催化剂填充装置中循环; 并用微波照射在催化剂填充装置中循环的混合液体以分解有机卤素化合物。在该方法中，催化剂填充装置通过在顶部堆叠填充构件层和底部的有机卤素化合物分解催化剂层而形成。混合液从顶部的催化剂层的上部引入，并通过底部的填充构件层排出。该方法使用分解装置。

8. 发明专利

JP2013095736A Method of decomposition-treating perfluorocarbon by zeolite 审中-公开
标题翻译：通过沸石分解处理全氟化碳的方法
公开(公告)号：JP2013095736A
公开(公告)日：2013-05-20
申请号：JP2011242398
申请日：2011-11-04
申请人： Kansai Univ , 学校法人関西大学 , Tosoh Corp , 東ソー株式会社
发明人： YAMAMOTO HIDEKI , INOUE HAJIME , HAYASHI YUKIO , HIRANO SHIGERU
IPC分类号： C07B35/06 , B01D53/86 , B01J20/18 , B01J20/34 , B01J29/08 , C07B37/06
CPC分类号： Y02C20/30
摘要： PROBLEM TO BE SOLVED: To solve a problem wherein secondary treatment for a decomposition product after decomposed is required separately in a rotary kiln method and a catalytic decomposition that are conventional methods of detoxifying a chlorofluorocarbon substitute gas.SOLUTION: A perfluorocarbon is brought into contact catalytically with zeolite having calcium as a cationic species, at 750 to 1,073K, to be decomposed, and the decomposition product is adsorbed by the zeolite.
摘要翻译：解决的问题为了解决分解后的分解产物的二次处理需要在回转窑方法和催化分解中分离的问题，这是常规的氯氟烃替代气体的解毒方法。解决方案：使全氟化碳与750〜1073K的钙作为阳离子物质的沸石催化接触，分解产物被沸石吸附。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2013081570A Pcb detoxification method 审中-公开
标题翻译： PCB脱氧剂方法
公开(公告)号：JP2013081570A
公开(公告)日：2013-05-09
申请号：JP2011222509
申请日：2011-10-07
申请人： Akira Suzuki , 明鈴木
发明人： SUZUKI AKIRA
IPC分类号： A62D3/13 , A62D3/34 , A62D3/40 , A62D101/22 , B01F7/26 , C07B35/06 , C07C25/18
摘要： PROBLEM TO BE SOLVED: To provide a PCB detoxification method for continuously detoxifying PCB with high efficiency.SOLUTION: A mixed liquid containing a PCB liquid and kerosene of 10:90 to 80:20 in weight ratio, and a processing liquid in which metal sodium having the same equivalent weight as that of chlorine in PCB and having an average grain size of 1-3 μm is suspended and distributed are supplied to a processing chamber 1 having a fixed circular body 20 and a rotating disc 10, while supplying an inert gas 4 into the processing chamber 1 from the bottom. The rotating disc 10 is rotated at 10,000 to 18,000 rpm, and is increased in temperature to 150 to 250°C.
摘要翻译：要解决的问题：提供一种PCB排毒方法，以高效率连续排除PCB。
解决方案：含有重量比为10:90至80:20的PCB液体和煤油的混合液体和其中与PCB中具有相同当量的金属钠的处理液，其具有平均颗粒在从底部向处理室1供给惰性气体4的同时，将1-3μm的尺寸悬浮和分配供给到具有固定圆形体20和旋转盘10的处理室1。旋转盘10以10,000〜18,000rpm的速度旋转，温度上升到150〜250℃。版权所有（C）2013，JPO＆INPIT

10. 发明专利

JP2013056067A Method and apparatus for detoxicating halogen compound-containing oil 有权
标题翻译：用于脱除含卤化合物的油的方法和装置
公开(公告)号：JP2013056067A
公开(公告)日：2013-03-28
申请号：JP2011196592
申请日：2011-09-08
申请人： Chugoku Electric Power Co Inc:The , 中国電力株式会社
发明人： TOKUMASA KENJI
IPC分类号： A62D3/34 , A62D101/22 , B01J8/20 , C07B35/06 , C07C25/18
摘要： PROBLEM TO BE SOLVED: To provide a method and apparatus for detoxicating halogen compound-containing oil, capable of obtaining dehalogenated oil from which unreacted metal sodium is sufficiently eliminated with a little energy.SOLUTION: The dehalogenated oil obtained by dehalogenating halogen compounds in the oil with metal sodium is introduced to a quenching device 19, is brought into contact with a solid quenching agent 33a having hydroxyl groups on the surface and insoluble to the oil, the unreacted metal sodium remaining in the dehalogenated oil and hydroxyl groups of the solid quenching agent 33a are reacted, and the metal sodium is quenched.

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