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    • 1. 发明专利
    • Production of boride diffused alloy
    • 生产硼化物扩散合金
    • JPS5923835A
    • 1984-02-07
    • JP13145782
    • 1982-07-28
    • Tokai Rika Co LtdToyota Central Res & Dev Lab Inc
    • FUJITA HIRONORIMIZUNO JIROUARAI TOORUKASUYA OSAMIOONO KOUICHIANDOU HISAHIRO
    • C22C1/10C22C5/00C22C5/02C22C5/06C23C8/00C23C8/42C23C8/68C23C12/00
    • C23C8/00C23C12/00
    • PURPOSE: To produce an electrical contact and sliding material having a surface part dispersed uniformly with borides and having excellent performance, by penetrating and dispersing B in a metallic material having the surface layer part consisting of a thin layer contg. gold, silver, etc. and Be, Mg, Al, etc.
      CONSTITUTION: ≥1 Kinds among Be, Mg, Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Ga, As, Zr, Nb, Mo, Pd, Cd, Ta, W and Pt are coated on the surface of gold, silver gold alloy, or silver alloy which is a base material by electroplating or the like; thereafter, the material is heat-treated to diffuse said element into the surface layer part, and metallic material of which the surface layer part from at least the surface down to 0.01W0.1mm depth contains 0.5W40atom% the above-mentioned elements as an alloy or fine particles and the balance is gold, silver gold alloy, or silver alloy is obtd. B is penetrated and diffused in such metallic material to form the fine particles consisting of the borides of the above-mentioned elements in the surface layer part of the metallic material, whereby the boride diffused alloy is produced and a metallic material suited for an electrical contact material, a sliding material, etc. is obtd.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:制造具有表面部分与硼化物均匀分散并具有优异性能的电接触和滑动材料,通过将B渗透并分散在具有由薄层的表面层组成的表面层部分的金属材料中。 Be,Mg,Al,Si,Ti,V,Cr,Mn,Fe,Co,Ni,Ga,As,Zr等1种, Nb,Mo,Pd,Cd,Ta,W和Pt通过电镀等涂覆在作为基材的金,银金合金或银合金的表面上; 此后,材料被热处理以将所述元件扩散到表面层部分中,并且其表面层部分至少从至少表面下降到0.01-0.1mm的金属材料。 深度含有0.5〜40原子%的上述元素作为合金或细颗粒,余量为金,银金合金或银合金。 B在这种金属材料中渗透并扩散以形成由金属材料的表面层部分中的上述元素的硼化物组成的细小颗粒,由此产生硼化物扩散合金和适合于电接触的金属材料 材料,滑动材料等。
    • 2. 发明专利
    • Ion-nitrifying method of aluminum material
    • 铝材料的离子化方法
    • JPS60211061A
    • 1985-10-23
    • JP6820884
    • 1984-04-05
    • Toyota Central Res & Dev Lab Inc
    • TACHIKAWA HIDEOSUZUKI TAKATOSHIFUJITA HIRONORIARAI TOORU
    • C23C8/36
    • C23C8/36
    • PURPOSE: To form a high-hardness film on the surface by placing Al or an Al alloy in a hermetic vessel, removing the remaining oxygen in the vessel, then heating the Al, activating the surface, introducing gaseous nitrogen, and generating glow discharge.
      CONSTITUTION: An anode plate 13 made of stainless steel is installed in a hermetic vessel 1, and an Al material or an Al alloy material 5 is placed on a base stand 2 as a cathode. The air in the hermetic vessel 1 is evacuated with a vacucum pump 3 to remove oxygen. Gaseous hydrogen is supplied while heating the inside of the furnace with 12, and then evacuated. Said process is repeated plural times to evacuate the remaining oxygen completely. A DC voltage is impressed between both electrodes 2 and 13 to generate electric discharge, and the Al 5 is heated by the impact of ions to a temp. at which Al is nitrified. Then the atmosphere in the hermetic vessel 1 is replaced with rare gases such as He, Ne, and Ar, and the electric discharge is generated to activate the surface of the Al 5. Subsequently, the inside of the hermetic vessel is replaced with NH
      3 or a gaseous mixture of N
      2 and H
      2 , and the low discharge is applied to form an AlN layer having high hardness and excellent abrasion resistance on the surface of the Al 5.
      COPYRIGHT: (C)1985,JPO&Japio
    • 目的:为了通过将Al或Al合金置于密封容器中,在表面上形成高硬度的膜,除去容器中剩余的氧,然后加热Al,激活表面,引入气态氮并产生辉光放电。 构成:将由不锈钢制成的阳极板13安装在密封容器1中,并将Al材料或Al合金材料5放置在作为阴极的底座2上。 密封容器1中的空气用真空泵3抽真空以除去氧气。 供应气态氢气,同时用12加热炉内,然后抽真空。 所述方法重复多次以完全排出剩余的氧气。 在两个电极2和13之间施加直流电压以产生放电,并且通过离子的冲击将Al 5加热至温度。 其中Al被硝化。 然后密封容器1中的气氛用诸如He,Ne和Ar的稀有气体代替,并且产生放电以活化Al 5的表面。随后,密封容器的内部被NH 3或 N2和H2的气体混合物,并且施加低放电以在Al 5的表面上形成具有高硬度和优异耐磨性的AlN层。
    • 3. 发明专利
    • Method for hardening surface of iron alloy material
    • 钢铁合金材料表面硬化方法
    • JPS59190355A
    • 1984-10-29
    • JP6279683
    • 1983-04-08
    • Toyota Central Res & Dev Lab Inc
    • ARAI TOORUENDOU JIYUNJISUGIMOTO YOSHIHIKO
    • C23C10/02C23C12/00C23C28/00
    • C23C10/02C23C12/00C23C28/00
    • PURPOSE: To form a surface layer of carbonitride of a Va group element and an inner layer of an iron alloy contg. solubilized N on the surface of an iron alloy material contg. a specified amount or more of C by nitriding the surface of the material and subjecting it to thermal diffusion treatment with a treating agent contg. said Va group element.
      CONSTITUTION: The surface of an iron alloy material contg. ≥0.2wt% C is nitrided, and it is subjected to thermal diffusion treatment with a treating agent contg. a Va group element to form a surface layer of the carbonitride of the Va group element and an inner layer of an iron alloy contg. solubilized N on the surface of the iron alloy material. The thermal diffusion treatment it carried out in a molten salt bath contg. said Va group element and borate as a treating agent, or the iron alloy material is immersed in a molten salt bath contg. the Va group element.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:形成Va组元素和铁合金内层的碳氮化物表面层。 在铁合金材料表面上溶解N。 指定量以上的C,通过氮化该材料的表面并对其进行热处理。 Va组元素说 构成:铁合金材料表面 > = 0.2wt%C被氮化,并用处理剂进行热扩散处理。 Va族元素,形成Va族元素的碳氮化物的表面层和铁合金的内层。 溶解的N在铁合金材料的表面上。 在熔盐浴中进行的热扩散处理 所述Va族元素和硼酸盐作为处理剂,或将铁合金材料浸入熔融盐浴中。 Va组元素。
    • 4. 发明专利
    • Method for coating iron alloy with carbide
    • 用碳化硅涂覆钢铁合金的方法
    • JPS5770270A
    • 1982-04-30
    • JP14798580
    • 1980-10-21
    • Toyota Central Res & Dev Lab Inc
    • ARAI TOORUENDOU JIYUNJI
    • C23C10/36C23C10/40C23C10/52C23C10/54
    • C23C10/36C23C10/40C23C10/52
    • PURPOSE:To enable to treat an iron alloy without using an activator and eliminate incovenience such as solidification of a treating agent powder, burining thereof to a material to be treated or the like, in a surface treatment of the iron alloy with a powder, by forming a using treating agent from a mixture of a specific metal and a metal oxide. CONSTITUTION:A treating agaent is constituted from a mixed powder comprising at least one or more of a metal such as Cr, V, Nb, Ta, Ti or a prwder of an alloy containing said metal and at least one or more of an oxide powder of the aforementioned elements. In said treating agent, an iron alloy material containing 0.2% or more C is coexisted as a material to be treated and heated to 700-1,200 deg.C. Thereby, a carbide layer comprising one or more of a carbide of Cr, V, Bb, Ta, Ti can be formed on a surface of the iron alloy material.
    • 目的:为了能够在不使用活化剂的情况下处理铁合金,并且在粉末状的铁合金的表面处理中,通过将粉末固化,处理剂粉末的固化,发泡等处理等来消除不合格 从特定金属和金属氧化物的混合物形成使用处理剂。 构成:处理剂由包含Cr,V,Nb,Ta,Ti中的至少一种或多种的混合粉末构成,或者含有所述金属和至少一种或多种氧化物粉末的合金 的上述要素。 在所述处理剂中,含有0.2%以上C的铁合金材料作为待处理材料并存,加热至700〜1200℃。 由此,可以在铁合金材料的表面上形成包含Cr,V,Bb,Ta,Ti的碳化物中的一种或多种的碳化物层。