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1. 发明专利

JP2010192420A Fuel cell 审中-公开
标题翻译：燃料电池
公开(公告)号：JP2010192420A
公开(公告)日：2010-09-02
申请号：JP2009153778
申请日：2009-06-29
申请人： Toshiba Corp , 株式会社東芝
发明人： UDATSU MITSURU , SUGA HIROSHI , SATO ASAKO , FURUICHI MITSURU , MONMA JUN
IPC分类号： H01M4/86 , H01M8/10
CPC分类号： H01M4/8673 , H01M4/8605 , H01M8/1011 , Y02E60/523
摘要： PROBLEM TO BE SOLVED: To enhance an output of a fuel cell using a high-concentration fuel and improve durability and long-term stability. SOLUTION: The fuel cell is provided with an anode catalyst layer containing an anode catalyst and a proton-conductive electrolyte, a cathode catalyst layer containing a cathode catalyst and a proton-conductive electrolyte, a proton-conductive electrolyte membrane pinched between the anode catalyst layer and the cathode catalyst layer, and a mechanism for supplying fuel to the anode catalyst layer. A void ratio of the anode catalyst layer measured by a mercury intrusion porosimeter is 0-30%. It is desirable for such a fuel cell to have a metal specific surface area ratio (measured by a CO pulse adsorption method) before and after containing the anode catalyst by 0-20%. Furthermore, the anode catalyst layer contains preferably a reinforcing material. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：提高使用高浓度燃料的燃料电池的输出，提高耐久性和长期稳定性。解决方案：燃料电池设置有包含阳极催化剂和质子传导性电解质的阳极催化剂层，含有阴极催化剂和质子传导性电解质的阴极催化剂层，夹在第阳极催化剂层和阴极催化剂层，以及用于向阳极催化剂层供应燃料的机构。由水银侵入孔隙率计测定的阳极催化剂层的空隙率为0〜30％。这样的燃料电池在含有阳极催化剂前后的金属比表面积比（通过CO脉冲吸附法测定）优选为0〜20％是理想的。此外，阳极催化剂层优选含有增强材料。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2009295542A Fuel battery 审中-公开
标题翻译：燃油电池
公开(公告)号：JP2009295542A
公开(公告)日：2009-12-17
申请号：JP2008150628
申请日：2008-06-09
申请人： Toshiba Corp , Toshiba Electronic Engineering Corp , 東芝電子エンジニアリング株式会社 , 株式会社東芝
发明人： YAJIMA TORU , FURUICHI MITSURU , OMICHI GENTA , SATO ASAKO , MONMA JUN
IPC分类号： H01M4/86 , H01M4/88 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a fuel battery capable of increasing an amount of water supplied to an anode (a fuel electrode) and suppressing the deterioration of the diffusion of an oxidizing gas on a cathode catalyst layer and obtaining a high output. SOLUTION: The fuel battery 1 comprises an anode (a fuel electrode) 13, a cathode (an air electrode) 16, a fuel battery cell 10 having an electrolyte membrane 17 sandwiched by the anode and the cathode, a moisturizing layer 50 arranged by being laminated on the cathode (air electrode) 16, and a surface cover 60 arranged by being laminated on the moisturizing layer 50 and having an air inlet 61. The cathode catalyst layer 14 of the cathode (air electrode) 16 has a first catalyst layer 14a located so as to correspond to the air inlet 61 of the surface cover 60, and a second catalyst layer 14b forming a section excluding the first catalyst layer 14a. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够增加供给阳极（燃料电极）的水量并且抑制氧化气体在阴极催化剂层上的扩散劣化并获得高输出的燃料电池。解决方案：燃料电池1包括阳极（燃料电极）13，阴极（空气电极）16，具有由阳极和阴极夹持的电解质膜17的燃料电池单元10，保湿层50 通过层叠在阴极（空气电极）16上而布置的表面盖60以及层压在保湿层50上并具有空气入口61的表面盖60.阴极（空气电极）16的阴极催化剂层14具有第一位于与表面盖60的空气入口61对应的催化剂层14a以及形成不包括第一催化剂层14a的部分的第二催化剂层14b。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2008243800A Fuel cell 有权
标题翻译：燃料电池
公开(公告)号：JP2008243800A
公开(公告)日：2008-10-09
申请号：JP2008006449
申请日：2008-01-16
申请人： Toshiba Corp , Toshiba Electronic Engineering Corp , 東芝電子エンジニアリング株式会社 , 株式会社東芝
发明人： OZU HIDEYUKI , AKAMOTO YUKINORI , SATO YUICHI , OMICHI GENTA , SUGA HIROSHI , WATANABE DAISUKE , NEGISHI NOBUYASU , YOSHIDA YUICHI , SATO ASAKO
IPC分类号： H01M8/02 , H01M4/86 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/24
CPC分类号： H01M8/04156 , H01M8/04171 , H01M8/04186 , H01M8/04201 , H01M8/04291 , H01M8/0662 , H01M8/0668 , H01M8/1011 , H01M8/241 , H01M8/2455 , H01M2250/20 , Y02E60/523 , Y02T90/32
摘要： PROBLEM TO BE SOLVED: To provide a fuel cell which improves a capability of eliminating a gas component generated on the fuel electrode side of an MEA due to power generation reaction in order to improve the power generation efficiency and time-dependent stability of a fuel battery.
SOLUTION: The fuel battery 1 includes an electricity generating unit 2 having a membrane electrode assembly (MEA) 12, a fuel storage unit 4 storing a fuel therein, and a fuel supply mechanism 3 which supplies the fuel stored in the fuel storage unit 4 to a fuel electrode 7 of the membrane electrode assembly 12. The membrane electrode assembly 12 has a venting hole 17 which is formed to at least penetrate an electrolytic membrane 11 and allows a gas component generated on the side of the fuel electrode 7 to escape toward an air electrode 10.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种燃料电池，其提高消除由于发电反应而在MEA的燃料电极侧产生的气体成分的能力，以提高发电效率和时间依赖性的稳定性燃料电池解决方案：燃料电池1包括具有膜电极组件（MEA）12的发电单元2，在其中存储燃料的燃料存储单元4和供应储存在燃料储存器中的燃料的燃料供给机构3 单元4连接到膜电极组件12的燃料电极7.膜电极组件12具有通气孔17，其形成为至少穿透电解质膜11，并且允许在燃料电极7侧产生的气体成分逃避空气电极10.版权所有（C）2009，JPO＆INPIT

4. 发明专利

JP2008016390A Fuel cell 审中-公开
标题翻译：燃料电池
公开(公告)号：JP2008016390A
公开(公告)日：2008-01-24
申请号：JP2006188434
申请日：2006-07-07
申请人： Toshiba Corp , 株式会社東芝
发明人： SATO ASAKO , YAJIMA TORU , MONMA JUN , HASHIMOTO MINORU , TAKIZAWA YUMIKO
IPC分类号： H01M8/02 , H01M4/86 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a fuel cell in which an output characteristics is improved. SOLUTION: This is the fuel cell which is provided with a polymer material composed of at least one out of polyethylene glycol and polyethylene oxide, an anode catalyst layer 4 containing an anode catalyst and a binder, a cathode catalyst layer 1, an electrolyte membrane 7 arranged between the anode catalyst layer 4 and the cathode catalyst layer 1, and a vapor-liquid separation layer 12 in order to supply a vaporized fuel to the anode catalyst layer 4. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种改善输出特性的燃料电池。解决方案：这是一种燃料电池，其设置有由聚乙二醇和聚环氧乙烷中的至少一种组成的聚合物材料，包含阳极催化剂和粘合剂的阳极催化剂层4，阴极催化剂层1，布置在阳极催化剂层4和阴极催化剂层1之间的电解质膜7和气 - 液分离层12，以便向阳极催化剂层4供应蒸发的燃料。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2007123208A Fuel cell system, and method of improving output power of fuel cell 审中-公开
标题翻译：燃料电池系统及其提高燃料电池输出功率的方法
公开(公告)号：JP2007123208A
公开(公告)日：2007-05-17
申请号：JP2005317668
申请日：2005-10-31
申请人： Toshiba Corp , 株式会社東芝
发明人： SUGA HIROSHI , SUZUKI HIDENORI , SATO ASAKO , YAJIMA TORU
IPC分类号： H01M8/04 , H01M8/10
CPC分类号： H01M8/04649 , H01M8/04186 , H01M8/04238 , H01M8/045 , H01M8/04828 , H01M8/1011 , H01M2250/30 , Y02B90/18 , Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a fuel cell system and a method of improving output power of fuel cell capable of improving output power.
SOLUTION: Alternating current component is superposed on direct current component output from a DMFC 102 composed of a cathode catalyst layer, an anode catalyst layer, a proton conductive film arranged between the cathode catalyst layer and the anode catalyst layer, and a means for supplying fuel to the anode catalyst layer, by an alternating current component superposing means 108.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：提供一种能够提高输出功率的燃料电池系统和提高燃料电池的输出功率的方法。解决方案：将交流分量重叠在由阴极催化剂层，阳极催化剂层，布置在阴极催化剂层和阳极催化剂层之间的质子传导膜组成的DMFC102输出的直流分量上，用于通过交流分量叠加装置108向阳极催化剂层供应燃料。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2005259381A Nonaqueous electrolyte secondary battery 有权
标题翻译：非电解电解质二次电池
公开(公告)号：JP2005259381A
公开(公告)日：2005-09-22
申请号：JP2004066114
申请日：2004-03-09
申请人： Toshiba Corp , 株式会社東芝
发明人： SATO ASAKO , SEKINO MASAHIRO , YAJIMA TORU , MATSUMOTO KOICHI
IPC分类号： H01M4/587 , H01M10/05 , H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/40 , H01M4/02 , H01M4/58
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery which has small swelling in a charging storage and which has a long charge and discharge life cycle.
SOLUTION: This nonaqueous electrolyte secondary battery is provided with a positive electrode 3 containing positive electrode active materials, a negative electrode 4, and a nonaqueous electrolyte containing vinylene carbonate (VC) and 2, 4-difluoroanisole (DFA), and the content of VC in the nonaqueous electrolyte at the initiation of usage is 0.6 wt% or less, and the amount of DFA in the positive electrode active material per surface area of 1 m
2 is in the range of 1-50 mg. The negative electrode 4 contains a graphite material in which face intervals d
002 of (002) faces by powder X-ray diffraction measurements are 0.336 nm or less and a diffraction angle 2θ has a peak in 42.8-44.0° and 45.5-46.6° in the diffraction measurements.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种在充电存储器中具有小的膨胀并且具有长的充放电寿命周期的非水电解质二次电池。解决方案：该非水电解质二次电池设置有含有正极活性物质的正极3，负极4和含有碳酸亚乙烯酯（VC）和2,4-二氟苯甲醚（DFA）的非水电解质，开始使用时，非水电解液中的VC含量为0.6重量％以下，每1面积SP 2的表面积的正极活性物质中的DFA的含量为1 -50毫克。负极4含有通过粉末X射线衍射测定的（002）面的面间隔d 002 的石墨材料为0.336nm以下，衍射角2θ为42.8〜44.0的峰值 °和45.5-46.6°。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2005108513A Electrode, nonaqueous electrolyte secondary battery, and manufacturing method of nonaqueous electrolyte secondary battery 有权
标题翻译：电极，非电解电解质二次电池及非电解二次电池的制造方法
公开(公告)号：JP2005108513A
公开(公告)日：2005-04-21
申请号：JP2003337700
申请日：2003-09-29
申请人： Toshiba Corp , Toshiba Electronic Engineering Corp , 東芝電子エンジニアリング株式会社 , 株式会社東芝
发明人： KAMIBAYASHI SHINICHI , SATO ASAKO
IPC分类号： H01M2/12 , H01M4/131 , H01M4/1391 , H01M4/525 , H01M4/62 , H01M10/05 , H01M10/052 , H01M4/02 , H01M4/04 , H01M4/58 , H01M10/40
CPC分类号： Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide an electrode capable of reducing explosion and ignition when a nonaqueous electrolyte secondary battery is overcharged.
SOLUTION: The nonaqueous electrolyte secondary battery has a safety valve mechanism actuated by internal pressure rise, and a positive electrode containing lithium-nickel complex oxide and lithium carbonate, fulfilling a formula (1); 0.02≤(P
2 -P
1 ) 2 is Ni/C peak ratio at the surface of the electrode, and P
1 is Ni/C peak ratio in the inside of the electrode, measured by an X-ray electron spectrometry (XPS).
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种当非水电解质二次电池过充电时能够减少爆炸和点火的电极。解决方案：非水电解质二次电池具有通过内部压力升高致动的安全阀机构和满足式（1）的含锂镍复合氧化物和碳酸锂的正极; 0.02≤（P 2 -P 1 ）<0.8，其中P 2 是电极表面的Ni / C峰值比， P 1 是通过X射线电子光谱法（XPS）测量的电极内部的Ni / C峰值比。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2004172113A Nonaqueous electrolyte secondary battery 有权
公开(公告)号：JP2004172113A
公开(公告)日：2004-06-17
申请号：JP2003377349
申请日：2003-11-06
申请人： Toshiba Corp , 株式会社東芝
发明人： SHIMURA NAO , TANAKA HIROMASA , SEKINO MASAHIRO , SATO ASAKO , INADA SHUSUKE , YAJIMA TORU , OGUCHI MASAYUKI
IPC分类号： H01M4/02 , H01M4/36 , H01M4/525 , H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/40 , H01M4/58
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery restrained from swelling when stored in a charged state and in a high-temperature environment. SOLUTION: This nonaqueous electrolyte secondary battery is equipped with: a positive electrode 3 containing a positive electrode active material; a negative electrode 4; and a nonaqueous electrolyte. The nonaqueous electrolyte secondary battery is characterized by that the positive electrode active material contains lithium composite oxide powder wherein the particle diameter (D10) at a volume cumulative frequency of 10% is below 4.5 μm, the ratio (I 003 /I 104 ) of the peak intensity I 003 of the (003) surface to the peak intensity I 104 of the (104) surface in a powder X-ray diffraction is larger than 5, and the mol ratio (X Li /X Co ) of Li to Co is above 1.02; and the nonaqueous electrolyte contains a sultone compound having at least one double bond in each ring. COPYRIGHT: (C)2004,JPO

9. 发明专利

JP2004095538A Nonaqueous electrolyte secondary battery 审中-公开
标题翻译：非电解电解质二次电池
公开(公告)号：JP2004095538A
公开(公告)日：2004-03-25
申请号：JP2003204904
申请日：2003-07-31
申请人： Toshiba Corp , 株式会社東芝
发明人： OSAKI TAKAHISA , TAKAMI NORIO , HASEBE HIROYUKI , KANDA MOTOI , SATO ASAKO , KUBOKI TAKASHI , YAMADA SHUJI
IPC分类号： H01M2/16 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/485 , H01M4/50 , H01M4/525 , H01M4/587 , H01M4/62 , H01M10/05 , H01M10/052 , H01M10/0566 , H01M10/058 , H01M10/40 , H01M4/02 , H01M4/58
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte secondary battery, in which nonaqueous electrolyte is impregnated in a group of electrodes in a solution state, for reducing a thickness, and improving capacity and large current characteristics and cycle performance.
SOLUTION: The nonaqueous electrolyte secondary battery is provided with a positive electrode containing a positive active substance, a conductive material, and a first binder, a negative electrode containing a negative active substance, a carbonacenous material for storing or discharging a lithium ion, and a second binder, a separator arranged between the positive electrode and negative electrode, and the nonaqueous electrolyte. A total concentration gradient of the first and second binders is minimized in a center part of the separator and is gradually increased as close to an interface of the positive and negative electrodes, and has a continuous curve of a binder concentration which becomes maximum in a center part of the positive and negative electrodes.
COPYRIGHT: (C)2004,JPO
摘要翻译：解决方案：提供一种非水电解质二次电池，其中非水电解质浸渍在溶液状态的一组电极中，用于减小厚度，并且提高容量和大的电流特性和循环性能。解决方案：非水电解质二次电池设置有包含正极活性物质，导电材料和第一粘合剂的正极，含有负极活性物质的负极，用于储存或放出锂离子的碳酸盐材料，第二粘合剂，配置在正极和负极之间的隔膜和非水电解质。第一和第二粘合剂的总浓度梯度在分离器的中心部分被最小化，并且随着正极和负极的界面的接近而逐渐增加，并且具有在中心变得最大的粘合剂浓度的连续曲线正极和负极的一部分。版权所有（C）2004，JPO

10. 发明专利

JP2002329529A NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
公开(公告)号：JP2002329529A
公开(公告)日：2002-11-15
申请号：JP2001269299
申请日：2001-09-05
申请人： TOSHIBA CORP
发明人： SATO ASAKO , FUJIWARA MASAFUMI , KOIWA KAORU , SEKINO MASAHIRO , SHIMURA NAO , HASEBE HIROYUKI , OGUCHI MASAYUKI , KONUMA MASATAKA
IPC分类号： H01M2/02 , H01M4/133 , H01M4/36 , H01M4/587 , H01M10/05 , H01M10/0525 , H01M10/0565 , H01M10/0566 , H01M10/0569 , H01M10/40 , H01M4/02 , H01M4/58
摘要： PROBLEM TO BE SOLVED: To improve a self-discharge characteristic of a nonaqueous electrolyte secondary battery provided with a nonaqueous electrolyte containing γ- butyrolactone. SOLUTION: This secondary battery is provided with an armoring material 1 having a thickness of

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