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1. 发明专利

JPH10175945A PRODUCTION OR DITHIOETHER 失效
公开(公告)号：JPH10175945A
公开(公告)日：1998-06-30
申请号：JP35260896
申请日：1996-12-16
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU , NAKANISHI HIROSHI
IPC分类号： B01J27/122 , C07B61/00 , C07C319/14 , C07C321/30 , C07C323/20 , C07C323/21 , C07C323/22 , C07C323/65
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a dithioether useful as an organic additive usable for improvement of crystallinity and fluidity of various polymers, and a lubricant base oil in high yield by using an easily handleable disulfide compound instead of thiphenols. SOLUTION: The objective compound is produced by reacting a dihalo aromatic compound (preferably an m-dihalobenzene, especially m-dichlorobenzene) with a disulfide compound of the formula R-S-S-R [R is an aralkyl or a (substituted) aryl] and an alkali metal hydroxide in a polar solvent such as N-methyl-2-pyrroridone in the presence or absence of a copper catalyst such as cuprous chloride preferably at 200-260 deg.C for 4-15hr. Preferably, the molar ratio of the dihalo aromatic compound and the alkali metal hydroxide to the disulfide compound are 1-1.5 and 1.9-2.4, respectively.

2. 发明专利

JPH0762100A PRODUCTION OF HIGH-MOLECULAR WEIGHT POLYARYLENE SULFIDE 失效
公开(公告)号：JPH0762100A
公开(公告)日：1995-03-07
申请号：JP23544793
申请日：1993-08-27
申请人： TONEN SEKIYUKAGAKU KK
发明人： TSUDA TAKASHI , YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： C08G75/02 , C08G75/06
摘要： PURPOSE:To provide an economically excellent and simple method for producing a high-molecular weight polyarylene sulfide(PAS) without requiring an expensive polymerization assistant. CONSTITUTION:This method for producing a high-molecular weight polyarylen sulfide is to further react an active hydrogen-containing dihalogen aromatic compound with an alkali metallic sulfide and dihalo-aromatic compound in an organic amide-based solvent in a reactional vessel, cool the vapor phase part in the reactional vessel, thereby condense a part of the vapor phase in the reactional vessel and reflux the resultant condensate to the liquid phase in a method for reacting the alkali metallic sulfide with the dihalo-aromatic compound in the organic amide-based solvent and producing the polyarylene sulfide.

3. 发明专利

JPH0820644A HIGH MOLECULAR WEIGHT POLYARYLENE SULFIDE FOR BLOW-MOLDING 失效
公开(公告)号：JPH0820644A
公开(公告)日：1996-01-23
申请号：JP17620594
申请日：1994-07-06
申请人： TONEN SEKIYUKAGAKU KK
发明人： TSUDA TAKASHI , YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： B29C49/00 , B29L22/00 , C08G75/02 , C08G75/06
摘要： PURPOSE:To obtain the subject polymer reduced in the drawing-down of a parison on the blow-molding of the polymer, excellent in appearance and cost, and useful for medical care containers, etc., by adding a polyhalogenated aromatic compound, when an alkali metal sulfide is reacted with a dihalogenated aromatic compound. CONSTITUTION:This polymer is obtained by reacting (A) an alkali metal sulfide such as Li2S or Na2S with (B) a dihalogenated aromatic compound such as p-dichlorobenzene and (C) a polyhalogenated aromatic compound (e.g. 1,2,4- trichlorobenzene, 1,3,5-trichlorobenzene) in an amount of 0.2-1.0mol.% based on the component A in an organic amide solvent such as N-methylpyrrolidone or DMF, while the gaseous phase part of a reactor is cooled during the reaction to condense a part of the gaseous phase in the reactor and subsequently recycled to the liquid phase.

4. 发明专利

JPH0971653A POLYARYLENE SULFIDE AND ITS PRODUCTION 失效
公开(公告)号：JPH0971653A
公开(公告)日：1997-03-18
申请号：JP18803096
申请日：1996-07-01
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU , MIYOSHI MASARU , ANAZAWA YOSHIKATA , MIKAWA NAOHIRO , ICHIKAWA KAZUHIRO
IPC分类号： C08G75/02 , C08G75/0295 , C08G75/06 , C08K3/00 , C08K3/34 , C08K3/36 , C08L81/02
摘要： PROBLEM TO BE SOLVED: To produce a new polyarylene sulfide, causing a remarkably small amount of tlashes in molding and providing a molding, having an ultrahigh whiteness degree and excellent in mechanical properties by setting a value of the pH of a polymer slurry in a post treating step within a specific range. SOLUTION: The amount of terminal SX groups (X is an alkali metal or H) based on the sum total of the terminal SX groups and SZn groups is

5. 发明专利

JPH0925346A FIBER-REINFORCED COMPOSITE MATERIAL 失效
公开(公告)号：JPH0925346A
公开(公告)日：1997-01-28
申请号：JP19411595
申请日：1995-07-07
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： C08J5/04 , B29C70/06 , B29K105/06
摘要： PROBLEM TO BE SOLVED: To obtain a fiber-reinforced composite material which gives a molding excellent in mechanical strengths such as bending and impact strengths by compositing a fibrous substrate and a polyarylene sulfide having a specified melt viscosity and elongation at break. SOLUTION: This material contains a polyarylene sulfide having a melt viscosity V6 of 3,000-20,000P and an elongation at break of 10% or higher and a fibrous substrate, can give a molding excellent in mechanical strengths such as bending and impact strengths, and is produced e.g. by forming the polyarylene sulfide into a sheet, alternately laying the resin sheets and the substrate sheets, and pressing the piled resin sheets and substrate sheets pref. at 300-350 deg.C for 3-20min under a pressure of 10-100kg/cm or by impregnating the substrate sheet with a powder, slurry, or soln. of the resin using a spray.

6. 发明专利

JPH08319348A POLYARYLENE SULFIDE AND ITS PRODUCTION 失效
公开(公告)号：JPH08319348A
公开(公告)日：1996-12-03
申请号：JP15116595
申请日：1995-05-26
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： C08G75/02 , C08G75/0231 , C08G75/06
摘要： PURPOSE: To obtan a polyarylene sulfide extremely reduced in the generation of burrs on its injection molding, high in the shear rate dependency of the melt viscosity and excellent in moldability by specifying the melt viscosity and the shear rate. CONSTITUTION: The polyarylene sulfide has a melt viscosity V6 of 300-4000 poises and a relation of the inequality between the melt viscosity V6 and the shear rate N. The method for producing the polyarylene sulfide comprises feeding (A) an alkali metal sulfide, (B) a dihalogenoaromtic compound and (C) an aromatic compound having three or more functional groups into a reaction system in a component A/B molar ratio of 0.97-1.02 and in a component C/A molar ratio of 0.002-0.015, reacting the fed compounds in a polar solvent, adding (D) a mol.wt.-controlling agent to the reaction system in an amount of 0.001-0.02 mole per mole of the fed component A, and further continuing the reaction. The component A, the component B, the component C and the component D are preferably sodium sulfide, p-dichlorobenzene, dichloroaniline, etc., and thiophenol, etc., respectively.

7. 发明专利

JPH04331268A SOLDER RESIST INK 失效
公开(公告)号：JPH04331268A
公开(公告)日：1992-11-19
申请号：JP2258691
申请日：1991-01-24
申请人： TONEN SEKIYUKAGAKU KK , NITTO CHEMICAL INDUSTRY CO LTD
发明人： TOMITA ISAO , YAMANAKA HIDENORI , KATO MASAYUKI , IKEDA TADAO , HOSODA JUN
IPC分类号： C09D11/00 , C09D11/033 , C09D11/10 , C09D11/102 , H05K3/28
摘要： PURPOSE:To prepare a solvent-based solder resist ink which is used for the cover coating of a circuit board, is excellent in flexibility, heat resistance, and adhesive properties, and gives a coating film free from curling by compounding a plurality of specific compds. as essential components into a solvent. CONSTITUTION:A solder resist ink based on a solvent (e.g. N-methylpyrrolidone) and used for the cover coating of a circuit board is prepd. by compounding polyparabanic acid (e.g. one obtd. from HCN and 4,4'-diphenylmethane diisocyanate), a phenoxy resin (e.g. Phenotohto YP 50, a product of Tohto Kasei Co., Ltd.), and an epoxy resin (e.g. Denacol EX 313, a product of Nagase Kasei Co., Ltd.) as essential components into the solvent.

8. 发明专利

JPH1180356A PRODUCTION OF FUNCTIONAL GROUP-CONTAINING POLYARYLENE SULFIDE RESIN 失效
公开(公告)号：JPH1180356A
公开(公告)日：1999-03-26
申请号：JP25269197
申请日：1997-09-03
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： C08G75/02 , C08G75/029
摘要： PROBLEM TO BE SOLVED: To obtain the subject resin capable of simply introducing a specific functional group in an arbitrary amount by carrying out heat oxidation crosslinking reaction of a polyarylene sulfide polymer in the presence of a specific compound. SOLUTION: When (A) a polyarylene sulfide polymer (hereinafter referred to as raw material PAS) is subjected to heat oxidation crosslinking under oxygen-containing atmosphere, the heat oxidation crosslinking reaction is carried out in the presence of (B) one or more organic compounds having at least one active hydrogen containing group (preferably SH, OH, NH2 , COOH, CHO or SO3 H) to provide the objective resin. For example, a compound of the formula [X and Y are each SH, OH, NH2 , COOH, CHO or SO3 H; R is independently H, a halogen, a lower alkyl or the like; (p) is 0-4; (q) is 1-5; (p+q)=5] is exemplified as the component B. Furthermore, the component B is preferably used in an amount of 0.05-10 pts.wt. based on 100 pts.wt. component A.

9. 发明专利

JPH1060278A POLYARYLENE SULFIDE RESIN COMPOSITION 失效
公开(公告)号：JPH1060278A
公开(公告)日：1998-03-03
申请号：JP23865696
申请日：1996-08-22
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： C08K5/00 , C08L81/02
摘要： PROBLEM TO BE SOLVED: To obtain a polyarylene sulfide resin composition having antimicrobial and antifungal activities by blending a polyarylene sulfide with an antimicrobial substance provided with a chelation site having a metallic ion such as copper, silver or zinc as a complex salt and a specific functional group in the same molecule. SOLUTION: This polyarylene sulfide resin composition is obtained by blending (A) 100 pts.wt. polyarylene sulfide (e.g. polyphenylene sulfide) with (B) 0.1-3.0 pts.wt. antimicrobial substance comprising a compound represented by formulae I to IV, etc., and provided with a chelation site having a metallic ion selected from the group consisting of copper, silver and zinc as a complex salt and at least one functional group selected from the group consisting of epoxy group, an alkoxysilyl group, amino group and vinyl group in the same molecule and further (C) 0-200 pts.wt. inorganic filler (e.g. a glass fiber), mixing the prepared blend in a Henschel mixer and then melt kneading the obtained mixture with a twin-screw extruder, etc. The resultant polyarylene sulfide resin composition has excellent antimicrobial and antifungal activities and is capable of sustaining the properties for a long period.

10. 发明专利

JPH07224165A HIGH MOLECULAR-WEIGHT POLYARYLENE SULFIDE FOR TURBULAR EXTRUSION MOLDING 失效
公开(公告)号：JPH07224165A
公开(公告)日：1995-08-22
申请号：JP3321094
申请日：1994-02-07
申请人： TONEN SEKIYUKAGAKU KK
发明人： YAMANAKA HIDENORI , KOMIYAMA OSAMU
IPC分类号： B29C47/00 , B29K81/00 , C08G75/02 , C08G75/0231 , C08G75/0254 , C08G75/06
摘要： PURPOSE:To obtain the subject polyarylene sulfide useful for a piping, etc., having excellent impact resistance, etc., by adding a specific amount of a polyhalo aromatic compound to an organic amide-based solvent and reacting the polyhalo aromatic compound with an alkali metal sulfide and a dihalo aromatic compound. CONSTITUTION:(A) An alkali metal sulfide (specific sodium sulfide) is reacted with (B) a dihalo aromatic compound (preferably p-dichlorobenzene) and (C) 0.2-1.0mol%, preferably 0.3-0.6mol% (based on the fed alkali metal sulfide) of a polyhalo aromatic compound (preferably 1,2,4-trichlorobenzene or 1,3 5- trichlorobenzene) in an organic amide solvent. A vapor phase part in a reactor is cooled during the reaction, and a part of the vapor phase is condensed in the reactor and is refluxed to a liquid phase to give the objective polyarylene sulfide (PAS). The PAS has preferably 20,000-50,00 poise melt viscosity and -20 to +20% thickening ratio during melting.

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