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    • 1. 发明专利
    • Method for producing carbon fiber bundle and carbon fiber bundle obtained by the production method
    • 生产碳纤维布和生产方法获得的碳纤维布的方法
    • JP2014122439A
    • 2014-07-03
    • JP2012278056
    • 2012-12-20
    • Teijin Ltd帝人株式会社
    • ONO TSUBASANAITO TAKESHISAKURAI HIROSHI
    • D06M15/59C08K9/04C08L101/00D06M15/00
    • PROBLEM TO BE SOLVED: To provide a method for producing a reinforcing carbon fiber bundle, which has an improved impregnating property and handleability, and excellent workability, and which is most suitable for a composite.SOLUTION: Provided is a method for producing a reinforcing carbon fiber bundle comprising providing the fiber surface with a sizing agent, and drying by heating, wherein the sizing agent provided on the fiber surface contains fine particles having a 50% integration particle diameter Dof less than 0.25 μm and small particles having Dof 0.25 μm or more, and the temperature of drying by heating is higher than the melting point of the small particles. Further, it is preferable that a 90% integration particle diameter Dof the fine particles is less than 0.35 μm, that a 10% integration particle diameter Dof small particles is 0.05 μm or more, that the small particles comprises a thermoplastic resin, and that the fine particles comprise a thermoplastic resin. Further, it is preferable that the thermoplastic resin which forms the small particles and the fine particles is a polyamide resin, and it is preferable that the width of the carbon fiber bundle in the drying by heating step is 6 to 30 mm. Furthermore, it is preferable that the carbon fiber bundle is a continuous fiber and the carbon fiber bundle is a non-continuous fiber.
    • 要解决的问题:提供一种增强碳纤维束的制造方法,其具有改善的浸渍性和可操作性,并且具有优异的加工性,并且最适合于复合材料。解决方案:提供一种生产增强碳 纤维束,其包括提供纤维表面的上浆剂和通过加热干燥,其中在纤维表面上提供的施胶剂含有具有小于0.25μm的50%整合粒径Dof的微粒和0.25μm以上的Dof的小颗粒 ,通过加热干燥的温度高于小颗粒的熔点。 此外,优选的是,微粒的90%积分粒径D小于0.35μm,小颗粒的10%整合粒径D为0.05μm以上,小颗粒包含热塑性树脂,并且 细颗粒包含热塑性树脂。 此外,优选形成小颗粒的热塑性树脂和细颗粒是聚酰胺树脂,优选通过加热步骤干燥的碳纤维束的宽度为6至30mm。 此外,优选碳纤维束为连续纤维,碳纤维束为非连续纤维。
    • 3. 发明专利
    • Carbon fibers and method for producing the same
    • 碳纤维及其制造方法
    • JP2008285795A
    • 2008-11-27
    • JP2007133993
    • 2007-05-21
    • Teijin Ltd帝人株式会社
    • SAKURAI HIROSHIHARA HIROSHITAKAGI SHOICHI
    • D01F9/145
    • PROBLEM TO BE SOLVED: To provide carbon fibers which have at least a concentric structure at part of a cross-sectional structure, and have excellent mechanical characteristics, heat-radiating characteristics and a uniform crushing property.
      SOLUTION: The method for producing carbon fibers includes producing carbon fiber precursors from a mesophase pitch by a melt-blow method, wherein the melt viscosity and flow rate of the mesophase pitch in a capillary are 3 to 8 Pa s and 0.10 to 1.20 m/s, respectively, applying an infusibilizing treatment to the carbon fiber precursors, and then applying a calcination treatment to the treated products.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供在横截面结构的一部分具有至少同心结构的碳纤维,并且具有优异的机械特性,散热特性和均匀的破碎性能。 解决方案:碳纤维的制造方法包括通过熔喷法从中间相沥青制造碳纤维前体,其中毛细管中的中间相沥青的熔体粘度和流速为3〜8Pa·s,0.10〜 1.20m / s,对碳纤维前体进行渗透处理,然后对处理过的产品进行煅烧处理。 版权所有(C)2009,JPO&INPIT
    • 6. 发明专利
    • Carbon fiber and method for producing the same
    • 碳纤维及其制造方法
    • JP2005264346A
    • 2005-09-29
    • JP2004074012
    • 2004-03-16
    • Teijin Ltd帝人株式会社
    • BAN TETSUOSAKURAI HIROSHIHIRATA SHIGEKISAWAKI TORU
    • D01F6/96D01F8/18D01F9/145H01G11/22H01G11/24H01G11/32H01G11/34H01G11/40H01G11/44H01M4/88H01G9/058
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide an extremely fine carbon fiber without having a branched structure, having a high strength, high elasticity and 0.001-2 μm fiber diameter.
      SOLUTION: This carbon fiber is obtained through the processes comprising a step of forming a precursor fiber from a mixture consisting of pitch characterized by consisting of a composition of ≥60 wt. % pyridine soluble component, showing 180-330°C softening point and containing ≥90 % optical anisotropy with a thermoplastic resin, a step of forming a stabilized precursor fiber by subjecting the precursor fiber under a stabilizing treatment in a mixed gas atmosphere of iodine and oxygen, a step of removing the thermoplastic resin from the stabilized precursor fiber to form a fibrous carbon precursor and a step of carbonizing or graphitizing the fibrous carbon precursor.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供具有高强度,高弹性和0.001-2μm纤维直径的极细碳纤维,而不具有分支结构。 解决方案:该碳纤维通过以下方法获得,该方法包括以下步骤:从由沥青组成的混合物形成前体纤维,其特征在于由≥60wt。 %吡啶可溶成分,显示出180-330℃的软化点,并且含有≥90%的热塑性树脂的光学各向异性,通过在碘的混合气体气氛中对前体纤维进行稳定化处理来形成稳定的前体纤维的步骤,以及 氧气,从稳定化的前体纤维中除去热塑性树脂以形成纤维状碳前体的步骤和碳纤维状碳前体碳化或石墨化的步骤。 版权所有(C)2005,JPO&NCIPI