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    • 3. 发明专利
    • Dye-sensitized photoelectric conversion element, its manufacturing method, electronic device, its manufacturing method and electronic apparatus
    • 透明光电转换元件及其制造方法,电子设备及其制造方法和电子设备
    • JP2006252986A
    • 2006-09-21
    • JP2005068671
    • 2005-03-11
    • Sony Corpソニー株式会社
    • MOROOKA MASAHIROOGURA REIKOSUZUKI YUSUKE
    • H01M14/00H01L31/04
    • H01G9/2059H01G9/2004H01G9/2031H01L51/0086H01M14/005Y02E10/542Y02E10/549Y02T10/7022
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized photoelectric conversion element capable of providing high photoelectric conversion efficiency when a dye using, as an adsorption radical, an acid functional group such as an carboxylic acid easy to form an aggregate is used as an sensitizing dye.
      SOLUTION: This dye-sensitized photoelectric conversion element has an electrolyte layer 4 between a semiconductor electrode 2 with the sensitizing dye adsorbed thereto and a counter electrode 3. In the dye-sensitized photoelectric conversion element, the sensitizing dye possessing, as molecules of the sensitizing dye, a plurality of acid functional groups to be adsorbed to the semiconductor electrode 2 is used; and a part of the acid functional groups are neutralized by an alkaline compound comprising an hydroxide of at least one kind of metal or compound selected from a group comprising Li, Na, K, tetramethyl ammonium, tetraethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium, an imidazolium compound and a pyridinium compound.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供一种能够提供高光电转换效率的染料敏化光电转换元件,当使用使用易于形成聚集体的羧酸等酸官能团作为吸附基团的染料时 作为敏化染料。 解决方案:该染料敏化光电转换元件在吸附有增感染料的半导体电极2和对电极3之间具有电解质层4.在染料敏化光电转换元件中,作为分子 的敏化染料,使用吸附在半导体电极2上的多个酸官能团; 并且一部分酸官能团被包含氢氧化物的碱性化合物中和,所述碱性化合物包含选自由Li,Na,K,四甲基铵,四乙基铵,四丙基铵,四丁基铵组成的组中的至少一种金属或化合物的化合物, 咪唑鎓化合物和吡啶鎓化合物。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Dye-sensitized photoelectric conversion element and its manufacturing method
    • 透明光电转换元件及其制造方法
    • JP2006134631A
    • 2006-05-25
    • JP2004320273
    • 2004-11-04
    • Sony Corpソニー株式会社
    • OGURA REIKOSUZUKI YUSUKEMOROOKA MASAHIRONODA KAZUHIRO
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized photoelectric conversion element preventing elusion of dye previously adsorbed in a semiconductor electrode while reverse electron migration is prevented and suppressing deterioration with time of photoelectric conversion efficiency, and to provide the manufacturing method of the dye-sensitized photoelectric conversion element. SOLUTION: Additives 10 are adsorbed on the surface of the semiconductor electrode 2 in a part of gaps between dye and dye by immersing the semiconductor electrode 2 on which dye is adsorbed in a solution 12 containing the additives. An electrolyte 5 containing no additive is sealed between the semiconductor electrode 2 on which the dye 9 and the additive 10 are adsorbed and a counter electrode 4, and a dye-sensitized solar cell is manufactured. COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决问题:提供一种染料敏化光电转换元件,其防止预先吸附在半导体电极中的染料,同时防止反向电子迁移并抑制光电转换效率随时间的劣化,并且提供制造方法 染料敏化光电转换元件。 解决方案:通过将含有染料的半导体电极2浸渍在含有添加剂的溶液12中,将添加剂10吸附在染料与染料间隙的一部分的半导体电极2的表面上。 不含添加剂的电解质5被密封在吸附有染料9和添加剂10的半导体电极2和对电极4之间,制造染料敏化太阳能电池。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Photoelectric converter and gelling agent
    • 光电转换器和胶凝剂
    • JP2007200796A
    • 2007-08-09
    • JP2006020306
    • 2006-01-30
    • Sony Corpソニー株式会社
    • MOROOKA MASAHIROSUZUKI YUSUKEOGURA REIKO
    • H01M14/00H01L31/04
    • H01G9/2009H01G9/2031Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a photoelectric converter capable of applying as a dye-sensitized photoelectric converter having a gel-like electrolyte, in which there is no possibility of electrolyte leakage and drop in fill factor caused by gelling of the electrolyte is small. SOLUTION: The dye-sensitized photoelectric converter 10 is mainly composed of a transparent substrate 1 such as glass; a transparent electrode (a negative electrode) 2 comprising a transparent conductive layer such as FTO [fluorine-doped tin oxide (IV) SnO 2 ] or the like; a semiconductor layer 3 holding photosensitized dye; a gel-like electrolyte layer 4; a counter electrode (a positive electrode) 5; a counter substrate 6; and a sealing agent, or the like. The electrolyte layer 4 is made of an organic electrolyte containing an oxidation reduction species (a redox pair) such as I - /I 3 - , and gelled with a titanium oxide system fibrous matrix material having large specific surface area and high performance holding the electrolyte. As the semiconductor layer 3, a porous layer formed by sintering fine particles of titanium oxide TiO 2 is used, and the counter electrode 5 made of a platinum layer 5b or the like is formed on the counter substrate 6. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种光电转换器,其能够应用于具有凝胶状电解质的染料敏化光电转换器,其中不存在电解质泄漏和由电解胶凝胶引起的填充因子下降的可能性 是小。 染料敏化光电转换器10主要由玻璃等透明基板1构成。 包含透明导电层的透明电极(负极)2,例如FTO [氟掺杂氧化锡(IV)SnO 2 SB] 2等等; 保持光敏染料的半导体层3; 凝胶状电解质层4; 对电极(正电极)5; 对置基板6; 和密封剂等。 电解质层4由含有氧化还原物质(氧化还原对)的有机电解质构成,例如I / 并用具有大的比表面积和高性能的氧化钛体系纤维基质材料胶凝,保持电解质。 作为半导体层3,使用通过烧结氧化钛TiO 2 SB <2>的微粒形成的多孔层,在对置基板6上形成由铂层5b等构成的对电极5 。版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • Dye-sensitized photoelectric conversion element, photoelectric conversion element module, electronic apparatus, moving body, and power generation system
    • 感光度光电转换元件,光电转换元件模块,电子设备,移动体和发电系统
    • JP2007095370A
    • 2007-04-12
    • JP2005280374
    • 2005-09-27
    • Sony Corpソニー株式会社
    • OGURA REIKOSUZUKI YUSUKEMOROOKA MASAHIRO
    • H01M14/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized simple and cheap photoelectric conversion element such as a dye-sensitized solar cell of which breakage of a sealing material under heat is prevented for improved durability, with no coolant circulation facility required. SOLUTION: An infrared reflection film 6 is provided on one main surface of a transparent conductive substrate 1, while a dye carrying semiconductor micro particle layer 2 is provided on the other main surface. The infrared reflection film 6 is preferred to employ a heat mirror of three-layer structure of TiO 2 /TiN/TiO 2 . The dye carrying semiconductor micro particle layer 2 is made to face a conductive substrate 3 at least whose surface constitutes a counter electrode, and their peripheries are sealed with a sealing material 4. An electrolyte layer 5 is sealed up in the space between the dye carrying semiconductor micro particle layer 2 and the conductive substrate 3, constituting the dye-sensitized photoelectric conversion element. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供染料敏化的简单廉价的光电转换元件,例如染料敏化太阳能电池,其中防止密封材料在加热下破裂以提高耐久性,而不需要冷却剂循环设备。 解决方案:在透明导电基板1的一个主表面上设置红外反射膜6,而在另一个主表面上设置载有半导体微粒子层2的染料。 红外线反射膜6优选使用TiO 2 / TiO 2 / TiO 2 / SB 2的三层结构的热镜。 携带有载体的半导体微粒子层2的表面至少形成为表面构成对电极的导电性基材3,并且其周围用密封材料4密封。电解质层5被密封在携带 半导体微粒子层2和导电性基板3构成染料敏化型光电转换元件。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Method for manufacturing dye-sensitized photoelectric conversion device
    • 制造感光度光电转换装置的方法
    • JP2011243580A
    • 2011-12-01
    • JP2011157493
    • 2011-07-19
    • Sony Corpソニー株式会社
    • OGURA REIKO
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a dye-sensitized photoelectric conversion device, capable of holding a sensitizing dye in a porous body layer composed of a semiconductor material easily in a short time at low costs.SOLUTION: A porous body layer 11 composed of a titanium oxide is formed on a transparent substrate 2 having a transparent conductive film 3. The sensitizing dye is held by dripping solution 13 including the sensitizing dye to cover the porous body layer 11 and by penetrating the solution 13 into the porous body layer 11. By heating the porous body layer 11 and/or the solution 13 beforehand according to the necessity, the solution 13 is dripped in the heated state. The temperature of heating is set to be lower than the boiling point of the solvent in the solution 13.
    • 解决的问题:提供一种染料敏化光电转换装置的制造方法,其能够以低成本在短时间内容易地在半导体材料构成的多孔体层中保持敏化染料。 解决方案:在具有透明导电膜3的透明基板2上形成由氧化钛构成的多孔体层11.感光染料由包含增感染料的滴加溶液13保持以覆盖多孔体层11和 通过将溶液13穿透到多孔体层11中。根据需要预先加热多孔体层11和/或溶液13,将溶液13滴加到加热状态。 加热温度设定为低于溶液13中溶剂的沸点。版权所有:(C)2012,JPO&INPIT
    • 9. 发明专利
    • Photoelectric converter
    • 光电转换器
    • JP2007200559A
    • 2007-08-09
    • JP2006013965
    • 2006-01-23
    • Sony Corpソニー株式会社
    • MOROOKA MASAHIROSUZUKI YUSUKEOGURA REIKO
    • H01M14/00H01L31/04
    • Y02E10/542Y02P70/521
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized photoelectric converter inexpensive and excellent in photoelectric conversion performance. SOLUTION: The dye-sensitized photoelectric converter 10 is comprised of mainly a transparent substrate 1 such as glass; a semiconductor layer 3 held with photo-sensitized dye; a current conductive layer (a negative electrode) 12; an electrolyte layer 4; a counter electrode (a positive electrode) 5; a counter substrate 6; and a sealing material (not shown in a figure). A porous layer obtained by sintering fine particles of titanium oxide TiO 2 is used as the semiconductor layer 3, an organic electrolyte containing an oxidation reduction species such as I - /I 3 - is used as the electrolyte layer 4, and the counter electrode 5 laminated with a platinum layer or the like is installed on the counter substrate 6. A current collector layer 12 is arranged so as to come in contact with the semiconductor layer 3 on the side far from a light incident side. Therefore, shading of incident light to the semiconductor layer 3 by the current collecting layer 12 is prevented. An opening part (a cut-out part) 13 for making an electrolyte of the electrolyte layer 4 permeate to the semiconductor layer 3 is installed in the current collector layer 12. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供廉价且光电转换性能优异的染料敏化光电转换器。 染料敏化光电转换器10主要由玻璃等透明基板1构成, 用光敏染料保持的半导体层3; 电流导电层(负极)12; 电解质层4; 对电极(正电极)5; 对置基板6; 和密封材料(图中未示出)。 作为半导体层3,使用通过烧结氧化钛TiO 2 SB <2>的细颗粒而获得的多孔层,含有氧化还原物质的有机电解质, 使用SB> 3 - 作为电解质层4,并且在对置基板6上安装层叠有铂层等的对电极5.集电层12 被布置成在远离光入射侧的一侧与半导体层3接触。 因此,防止了由集电层12向半导体层3的入射光的阴影。 用于使电解质层4的电解质渗透到半导体层3的开口部(切口部)13安装在集电层12中。(C)2007,JPO&INPIT
    • 10. 发明专利
    • Photoelectric conversion element and its manufacturing method, photoelectric conversion element module, electronic equipment, movable body, power generation system, display, and its manufacturing method
    • 光电转换元件及其制造方法,光电转换元件模块,电子设备,可移动体,发电系统,显示器及其制造方法
    • JP2007073273A
    • 2007-03-22
    • JP2005257235
    • 2005-09-06
    • Sony Corpソニー株式会社
    • SUZUKI YUSUKEMOROOKA MASAHIROOGURA REIKO
    • H01M14/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a photoelectric conversion element such as a dye-sensitized solar cell, capable of obtaining stable photoelectric conversion characteristics for a long time and high process compatibility, and to provide the manufacturing method of the photoelectric conversion element. SOLUTION: A transparent electrode 2 and a semiconductor fine particle joint body layer 3 which is a semiconductor electrode are formed on a transparent substrate 1. An electrode 5 and a counter electrode 6 are formed on a substrate 4. A first component and a second component of a non-mixture type two-component adhesive are applied to the peripheral part of the transparent electrode 2 and the peripheral part of the counter electrode 6, the transparent substrate1 and the substrate 4 are stuck together so that the first component and the second component contact each other. An electrolyte is poured in a space between the semiconductor fine particle joint body layer 3 and the counter electrode 6 to form an electrolyte layer 8, and the dye-sensitized solar cell is manufactured. COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:为了提供能够长期获得稳定的光电转换特性和高的工艺相容性的染料敏化太阳能电池的光电转换元件,并且提供光电转换元件的制造方法 。 解决方案:在透明基板1上形成作为半导体电极的透明电极2和半导体微粒接合体层3.电极5和对电极6形成在基板4上。第一部件和 将非混合型双组分粘合剂的第二组分施加到透明电极2的周边部分,并且对电极6的周边部分,透明基板1和基板4粘合在一起,使得第一部件和 第二个组件彼此接触。 在半导体微粒子接合体层3和对电极6之间的空间中注入电解质,形成电解质层8,制造染料敏化太阳能电池。 版权所有(C)2007,JPO&INPIT