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    • 4. 发明专利
    • METHOD FOR ADJUSTING MOLTEN STEEL COMPONENT IN LADLE REFINING
    • JPH0273913A
    • 1990-03-13
    • JP22433888
    • 1988-09-07
    • NIPPON KOKAN KK
    • ISHIKAWA HIROAKIHASEGAWA TERUYUKIMIYAHARA HIROAKI
    • C21C7/00
    • PURPOSE:To quickly execute adjustment of Mn content in molten steel by obtaining shortage content of Mn in the molten steel with a Mn sensor providing an element coating oxide containing Mn on solid electrolyte having oxygen ion conductivity. CONSTITUTION:The sensor part 30 of a probe 14 is dipped into the molten steel in a ladle under treatment to obtain Mn activity in the molten steel. The probe 14 is composed of the sensor part 30 and a protecting tube 31 and the element 35 composing of the solid electrolyte 37 of ZrO2 coating Mn3O4 layer 38 on the surface, is provided in the sensor part 30 and in the inner part thereof, reference material 36 composing of mixed material of Cr and Cr2O3 is enclosed and a measuring electrode 40 is inserted. By the sensor part 30 having this constitution, electromotive force of Mn in the molten steel is detected to obtain the Mn activity, and by using this Mn activity, the shortage content of Mn is obtd. and Mn containing material quantity corresponding to the shortage content, is added. By this method, the treating time of molten steel is drastically shortened and the treating cost is reduced.
    • 6. 发明专利
    • METHOD FOR BLOWING MOLTEN METAL BY BOTTOM BLOWING NOZZLE
    • JPS63100117A
    • 1988-05-02
    • JP24458886
    • 1986-10-15
    • NIPPON KOKAN KK
    • TABATA YOSHIAKIHASEGAWA TERUYUKIHIRANO MINORUTOYODA KOJI
    • C21C5/34C21C5/48
    • PURPOSE:To simplify exchange of a nozzle and repairing work of refractory by inserting a pipe in a penetrated hole formed on bottom part of a vessel at a position apart from the bottom blowing nozzle in case of wear of the refractory near the nozzle and blowing gas into molten metal through only this pipe. CONSTITUTION:When furnace body temp. of converter after tapping molten steel is fallen down to the temp. to be possible to work, a flange 26 is fixed by welding to a suitable position in the iron shell 12 of furnace bottom apart from the above condition nozzle 14. And, after boring the iron shell 12 and the refractory 10 by inserting an edge tip of drill in the center hole of flange 26, the pipe for nozzle 28 is inserted in the penetrated hole obtd. Next, the tip part of pipe 28 is pushed by using a stopper jig from the inside of furnace, to prevent the projection of the pipe 28 to the inside of furnace by the pouring pressure of press-fitting agent. Further, gelling alumina cement is pressed to fit between the pipe 28 and the refractory 10 through a hose screwing the tip thereof into the hole 27 of flange 26. And, after forming the new nozzle 24, the piping 20 of existing nozzle 14 is taken out and the refractory is filled up in the passage 15 and a plug is driven into the opening at the outside of passage 15 to clog the passage 15.