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    • 1. 发明专利
    • Collector member for fuel cell, cell stack and fuel cell
    • 燃料电池,电池堆和燃料电池的收集器组件
    • JP2007273358A
    • 2007-10-18
    • JP2006099288
    • 2006-03-31
    • Kyocera Corp京セラ株式会社
    • MIYAJI TATSUAZUMA MASAHIKOFUJIMOTO TETSURO
    • H01M8/02H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a collector member for a fuel cell capable of improving a Cr diffusion prevention effect, and of improving electrical connection reliability between cells of the fuel cell, to provide a cell stack, and to provide a fuel cell. SOLUTION: This cell stack is composed by electrically connecting a plurality of cells of a fuel cell to one another by interposing collector members 20. The collector member 20 is formed by sequentially coating a surface of a collector base material 201 containing Cr with a Cr diffusion prevention layer 202a containing Zn and a coating layer 202b containing a composite oxide of a perovskite structure containing at least a part of a constituent constituting an oxygen electrode layer of the cell of the fuel cell, and an oxide of zinc; and the coating layer 202b of the collector member 201 is jointed to the oxygen electrode layer of the cell of the fuel cell. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种能够提高Cr扩散防止效果的燃料电池用集电体构件,提高燃料电池单电池之间的电连接可靠性,提供电池组,并提供燃料 细胞。 解决方案:通过介电集电体20将燃料电池的多个电池彼此电连接而构成电池组。集电体20通过依次涂覆含有Cr的集电体基材201的表面, 含有Zn的Cr扩散防止层202a和含有包含构成燃料电池的电池的氧电极层的成分的至少一部分的钙钛矿结构的复合氧化物的涂层202b和锌的氧化物; 集电体201的涂层202b与燃料电池的电池的氧电极层接合。 版权所有(C)2008,JPO&INPIT
    • 2. 发明专利
    • Heat resistant conductive member, alloy member for fuel cell, current collecting member for fuel cell, cell stack and fuel cell
    • 耐热导电构件,燃料电池用合金构件,燃料电池,电池堆和燃料电池的电流收集构件
    • JP2007194025A
    • 2007-08-02
    • JP2006009863
    • 2006-01-18
    • Kyocera Corp京セラ株式会社
    • FUJIMOTO TETSUROAZUMA MASAHIKO
    • H01B5/02C22C19/05C22C38/00C22C38/18C23C30/00H01B1/02H01M8/02H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a heat resistant conductive member very small in a Cr diffusion amount; to provide an alloy member for a fuel cell; to provide a current collecting member for a fuel cell; to provide a cell stack; and to provide a fuel cell. SOLUTION: The heat resistant conductive member is composed by covering a surface of an alloy containing Cr with a surface layer 202 formed out of an oxide containing Zn and Mn, wherein the surface layer 202 is exposed, and the surface layer 202 is made of (Zn, Mn)Mn 2 O 4 . Such a heat resistant conductive member can be used as a current collecting member 20 for collecting current from a cell of a fuel cell, and can form this cell stack by arranging it between cells of fuel cells to electrically connect the cells of fuel cells to each other. This fuel cell is composed by storing such a cell stack in a storage vessel. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供非常小的Cr扩散量的耐热导电构件; 提供燃料电池用合金构件; 以提供用于燃料电池的集流部件; 提供电池堆; 并提供燃料电池。 解决方案:耐热导电部件通过将含有Cr的合金的表面覆盖在由含有Zn和Mn的氧化物形成的表面层202上而形成,其中表面层202暴露,表面层202为 由(Zn,Mn)Mn 2 4 制成。 这样的耐热导电部件可以用作集电部件20,用于从燃料电池的电池收集电流,并且可以通过将燃料电池单元布置在燃料电池单元之间来将燃料电池的单元电连接到每个 其他。 该燃料电池通过将这样的电池堆存储在储存容器中而构成。 版权所有(C)2007,JPO&INPIT
    • 3. 发明专利
    • Solid oxide fuel battery cell, fuel battery cell stack device, fuel battery module, and fuel battery device
    • 固体氧化物燃料电池单元,燃料电池单元堆叠装置,燃料电池模块和燃料电池装置
    • JP2010129267A
    • 2010-06-10
    • JP2008300755
    • 2008-11-26
    • Kyocera Corp京セラ株式会社
    • HORI YUICHIFUJIMOTO TETSURO
    • H01M8/02H01M8/04H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide: a solid oxide fuel battery cell restraining reduction deformation and with reliability improved; a fuel battery cell stack device with the use of the same; a fuel battery module; and a fuel battery device.
      SOLUTION: The solid oxide fuel battery cell 1 is configured by: laminating a fuel electrode layer 3, a solid electrolyte layer 4 and an air electrode layer 6 on one of a pair of flat surfaces "n" of an electroconductive support 1 having a pair of flat surfaces "n" set in parallel with each other and a fuel gas flow channel 2 for flowing fuel gas inside, and containing Ni; and laminating an inter-connector 8 containing Mg through an adhesive layer 7 on the other flat surface "n". Since the molal quantity of Mg in the adhesive layer 7 is 50% or less of that in the inter-connector 8, reduction deformation can be effectively restrained, and reliability can be improved. Additionally, the fuel battery cell stack device 11 with reliability improved, the fuel battery module 18 and the fuel battery device 23 can be provided.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供:固体氧化物燃料电池电池抑制还原变形和可靠性提高; 具有使用该燃料电池单元堆叠装置的燃料电池单元堆叠装置; 燃料电池模块; 和燃料电池装置。 解决方案:固体氧化物燃料电池单元1通过以下方式构成:将导电支撑体1的一对平坦表面“n”中的燃料电极层3,固体电解质层4和空气电极层6层压 具有彼此平行设置的一对平面“n”和用于使燃料气体内部流动并包含Ni的燃料气体流路2; 并且在另一个平坦表面“n”上通过粘合剂层7层压含有Mg的连接器8。 由于粘合剂层7中的Mg的摩尔量为连接器8中的Mg的摩尔量的50%以下,因此可以有效地抑制还原变形,可以提高可靠性。 此外,可以提供可靠性提高的燃料电池单元堆叠装置11,燃料电池模块18和燃料电池装置23。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Heat resistant conductive member, alloy member for fuel cell, power collecting member for fuel cell, cell stack and fuel cell
    • 耐热导电构件,燃料电池用合金构件,燃料电池,电池堆和燃料电池的电力收集构件
    • JP2007220655A
    • 2007-08-30
    • JP2006292869
    • 2006-10-27
    • Kyocera Corp京セラ株式会社
    • AZUMA MASAHIKOFUJIMOTO TETSURO
    • H01B5/02H01M8/02H01M8/12
    • Y02E60/525
    • PROBLEM TO BE SOLVED: To provide a heat resistant conductive member having almost no diffusion to external of Cr; to provide an alloy member for a fuel cell; to provide a power collecting member for a fuel cell; to provide a cell stack; and to provide a fuel cell. SOLUTION: This alloy member for a fuel cell is characterized in that surfaces of an alloy containing Cr are covered with intermediate layers 203 containing Zn and Mn, and coating layers 202 containing Zn. The coating layer 202 is formed out of ZnO. Such an alloy member for a fuel cell can be used as a power collecting member 20 for collecting power from a fuel cell 1. Such a power collecting member is interposed between the fuel cells 1, whereby this cell stack is composed, and the cell stack is housed in a housing vessel, whereby this fuel cell is composed. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供几乎没有扩散到Cr外部的耐热导电构件; 提供燃料电池用合金构件; 以提供用于燃料电池的集电构件; 提供电池堆; 并提供燃料电池。 解决方案:用于燃料电池的该合金构件的特征在于,含有Cr的合金的表面被包含Zn和Mn的中间层203以及含有Zn的涂层202覆盖。 涂层202由ZnO形成。 这种用于燃料电池的合金构件可以用作用于从燃料电池1收集电力的集电构件20.这种集电构件插入在燃料电池1之间,由此构成电池组,并且电池堆 被容纳在容纳容器中,由此构成该燃料电池。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Fuel cell, support element therefor, and fuel cell unit
    • 燃油电池,其辅助元件和燃料电池单元
    • JP2005190737A
    • 2005-07-14
    • JP2003428082
    • 2003-12-24
    • Kyocera Corp京セラ株式会社
    • FUJIMOTO TETSUROYAMASHITA SHOJI
    • H01M8/02H01M8/12H01M8/24
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a support element suppressing an expansion through a reduction-oxidation cycle, and further to provide a fuel cell and a fuel cell unit, which suppress cracks and peelings of the solid electrolyte caused by the reduction and oxidation cycle, without having effect on making a control so as to tune the thermal expansion coefficient of the support element to a solid electrolyte. SOLUTION: A support element 31 for a fuel cell is configured to contain iron group metals and/or oxides of the iron group metal, Y 2 O 3 , and Mn compounds, and has a gas permeability and conductivity. The thermal expansion coefficient of the support element is brought close to the thermal expansion coefficient of a solid electrolyte 33 or a fuel electrode layer 32, and the production of cracks and peelings due to the differences of thermal expansions is suppressed effectively. At the same time, expansions at the support element for fuel cell caused by the reduction and oxidation cycle are also suppressed by an appropriate amount of Mn. As a result, even if starting and stopping are performed repeatedly, cracks and peelings at the fuel electrode and the solid electrolyte are effectively suppressed. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供通过还原 - 氧化循环抑制膨胀的支撑元件,并且还提供一种抑制由所述还原反应引起的固体电解质的裂纹和剥离的燃料电池和燃料电池单元,以及 氧化循环,而不影响进行控制,以将支撑元件的热膨胀系数调整到固体电解质。 解决方案:用于燃料电池的支撑元件31被配置为容纳铁族金属和/或铁族金属Y 2 SB 3 O 3 / SB的铁族金属和/或氧化物,以及 Mn化合物,具有透气性和导电性。 使支撑体的热膨胀系数接近于固体电解质33或燃料电极层32的热膨胀系数,并且有效地抑制了由于热膨胀差异引起的裂纹和剥离的产生。 同时,由还原和氧化循环引起的燃料电池用载体的膨胀也被适当量的Mn抑制。 结果,即使重复进行起动停止,也能够有效地抑制燃料电极和固体电解质的裂纹和剥离。 版权所有(C)2005,JPO&NCIPI
    • 8. 发明专利
    • Analytical method and analytical device of electron diffraction pattern
    • JP2004264260A
    • 2004-09-24
    • JP2003057576
    • 2003-03-04
    • Kyocera Corp京セラ株式会社
    • FUJIMOTO TETSURO
    • G01N23/20
    • PROBLEM TO BE SOLVED: To perform material identification quantitatively and accurately based on coordinate information of a diffraction point acquired from an electron diffraction pattern. SOLUTION: Coincidence between a calculated pattern and a measured pattern is calculated quantitatively (step S19) by using at least one factor among (1) the number of diffraction points as a crystallographic pattern, (2) a face interval ratio as a geometric condition, (3) an angle between faces, (4) a camera constant, and (5) an average error of an angle between photographs. In this case, the factor (1) which is a factor for showing coincidence of this electron diffraction pattern becomes the maximum value when basic reflection points agree completely, and becomes the minimum value when all the basic reflection points disagree. The factors (2)-(5) are for showing respectively coincidence of the face interval ratio, coincidence of the angle between faces, coincidence of the camera constant, and coincidence of the angle, and become respectively the maximum values in the case of complete agreement, and become the minimum values when the difference exceeds a measurement error. COPYRIGHT: (C)2004,JPO&NCIPI