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    • 3. 发明专利
    • CELLULAR SINTERED BODY COMPOSED OF POLYARYLENE SULFIDE
    • JPH02298527A
    • 1990-12-10
    • JP11858589
    • 1989-05-15
    • KUREHA CHEMICAL IND CO LTD
    • ENOKI TOMOOSAKAGUCHI YASUO
    • C08J9/24C08L81/02
    • PURPOSE:To obtain a cellular sintered body, having preferred voids and excellent in dimensional stability, heat, chemical resistance, etc., with a low molding shrinkage factor by heat-treating powder of a polyarylene sulfide under specific temperature conditions, then heating and sintering the resultant heat-treated powder. CONSTITUTION:A cellular sintered body obtained by heat-treating (A) powder of a substantially linear polyarylene sulfide having 500 to 5X10 P, preferably 10 to 10 P melt viscosity (at 310 deg.C and 1200/sec shearing rate), preferably a block copolymer, etc., composed of 50-95mol% recurring units expressed by formula I and 5-50mol% blocks expressed by formula II at a temperature above the melting crystallization temperature and below the melting point for 0.5-600min and having 2X10 to 10 P, preferably 3X10 to 7X10 P, heating and sintering the resultant heat-treated powder (B) at a temperature above the softening temperature and below the decomposition temperature and preferably further heat-setting the sintered body at a temperature below the melting point.
    • 10. 发明专利
    • MANUFACTURE OF SODIUM DITHIONITE
    • JPS5687682A
    • 1981-07-16
    • JP16529879
    • 1979-12-19
    • KUREHA CHEMICAL IND CO LTD
    • MORITA TOMIJIROUENOKI TOMOOYOSHIMORI MINORU
    • C25B1/14
    • PURPOSE:To manufacture Na2S2O4 of high purity at an improved current efficiency, by circulating hydrochloric acid soln. through an anodic chamber separated by a cation exchange membrane while feeding hydrochloric acid to the anodic chamber, and by electrolyzing aqueous sodium hydrogensulfite soln. made by supplying SO2 to the sodium sulfite soln. in the cathodic chamber. CONSTITUTION:Aqueous hydrochloric acid soln. is circulated through the anodic chamber of an electrolytic cell having the anodic chamber separated from the cathodic chamber with a cation exchange membrane while charging hydrochloric acid soln. to the anodic chamber. On the other hand, sulfurous acid gas is supplied to the soln. contg. sodium sulfite in the cathodic chamber to form aqueous sodium hydrogensulfite which is electrolyzed thereby manufacturing catholyte contg. Na2S2O4. Na2S2 O4.2H2O is crystallized by addition of sodium sulfite to the catholyte. To the soln. separated from the Na2S2O4.H2O is added sulfurous acid gas to form sodium hydrogensulfite, which is led to the cathodic chamber and is used for manufacturing Na2S2O4. This method allows to manufacture Na2S2O4 of high purity at about 95% current efficiency.