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    • 2. 发明专利
    • Method for predicting oh- load of seawater by throwing in slag and method for preparing or selecting slag to be thrown in sea area
    • 用于通过在泥沙中倾斜预测海水的OH-负荷的方法和在海域中制备或选择泥浆的方法
    • JP2012077922A
    • 2012-04-19
    • JP2010220556
    • 2010-09-30
    • Jfe Steel CorpJfeスチール株式会社
    • INOUE YOTAROTAKAHASHI KATSUNORIMIYATA YASUTOWATANABE KEIJIYABUTA KAZUYA
    • F27D15/00C04B5/00
    • PROBLEM TO BE SOLVED: To exactly and conveniently predict an OHload that a slag A thrown in the sea area imposes on the sea water present between the sea surface and visible water depth.SOLUTION: A particle size distribution of the slag A is divided into a plurality of particle size ranges g. The specific surface area s of the slag and the settling time t of the slag from the sea surface to the visible water depth are calculated for each particle size range g. An optional particle size range gis selected from a plurality of particle size ranges g and an OHelution amount D is determined by the following procedure. (1) The rate vof OHconcentration increase of the sea water is determined based on the pH measured in an elution test of the slag of the particle size range g. (2) The rate of OHconcentration increase per the specific surface area of the slag A is determined based on the specific surface area sand the rate vof OHconcentration increase of the slag of the particle size range g, and based on the determined rate, the rate v of OHconcentration increase of the slag of each particle size range g other than the particle size range gis determined. (3) The OHelution amount d of the slag of each particle size range g is determined by the equation: OHelution amount d=[rate v of OHconcentration increase]×[settling time t from the sea surface to the visible water depth]×[proportion w in the slag A], and the OHelution amount D is determined by summing up each OHelution amount d.
    • 要解决的问题:为了准确和方便地预测在海域投掷的矿渣A对海面和可见的海水之间的海水造成的负荷 水深。 解决方案:将渣A的粒度分布分为多个粒度范围g。 对于每个粒度范围g,计算炉渣的比表面积s和炉渣从海面到可见水深度的沉降时间t。 从多个粒度范围g中选择任选的粒度范围g x ,并且确定洗脱量D 通过以下过程。 (1)基于在洗脱中测量的pH来确定海水的浓度增加率的比例v x 测试渣的粒度范围g x 。 (2)基于比表面积确定炉渣A的比表面积的OH - 浓度增加率s x < / SB>,并且颗粒尺寸范围的渣的浓度增加g - 的速率v x “POST”> x ,并且基于所确定的速率,除颗粒以外的每个粒度范围g的炉渣浓度增加的速率v 确定尺寸范围g x 。 (3)每个粒度范围g的炉渣的洗脱量d由下式确定:OH - 洗脱量d = [浓度增加]×[从海面到可见水深度的沉降时间t]×[渣A中的比例w] 通过将每个OH - / SP>洗脱量d相加来确定洗脱量D。 版权所有(C)2012,JPO&INPIT
    • 3. 发明专利
    • Method for reducing substance containing chromium oxide
    • 减少含有氧化铬的物质的方法
    • JP2013144292A
    • 2013-07-25
    • JP2012270732
    • 2012-12-11
    • Jfe Steel CorpJfeスチール株式会社
    • TOFUSA HIROYUKIMIYATA YASUTO
    • B09B3/00C02F11/00C04B5/00C21C7/00F27D15/00
    • Y02P10/212
    • PROBLEM TO BE SOLVED: To provide a method capable of suitably reducing hexavalent chromium even for a substance containing powdered chromium oxide which is small in grain size.SOLUTION: In the method, a substance containing reductive sulfur is mixed with a substance containing chromium oxide, and the mixture is treated with steam so that hexavalent chromium contained in the substance containing chromium oxide is reduced. The mixture is made to have a grain size in which the ratio of the grains of a diameter of 2.5 mm or less is not more than 40 mass%, and the mixture having the grain sizes is treated with steam. Since the mixture is adjusted in grain size to be a grain size distribution in which the mixture has a high ratio of coarse particles, steam goes into circulation over the entire mixture layer, which is capable of suitably reducing hexavalent chromium contained in the substance having chromium oxide.
    • 要解决的问题:提供一种能够适当地减少六价铬的方法,即使对于粒径小的粉末状氧化铬的物质也是如此。解决方案:在该方法中,将含有还原硫的物质与含有氧化铬的物质混合, 并且用蒸汽处理混合物,使得包含在含有氧化铬的物质中的六价铬被还原。 使混合物具有其直径为2.5mm以下的颗粒的比例不大于40质量%的粒径,并且用蒸汽处理具有晶粒尺寸的混合物。 由于将混合物的粒径调节为混合物的粗颗粒比例高的粒度分布,所以在整个混合层上蒸汽进行循环,其能适当地还原含有铬的物质中所含的六价铬 氧化物。
    • 5. 发明专利
    • Method for resource recovery from steelmaking slag, and raw material for phosphate fertilizer
    • 钢铁渣回收利用方法,磷酸盐肥料原料
    • JP2012007190A
    • 2012-01-12
    • JP2010141137
    • 2010-06-22
    • Jfe Steel CorpJfeスチール株式会社
    • MATSUI AKITOSHIKIKUCHI NAOKIKISHIMOTO YASUOTOFUSA HIROYUKITAKAHASHI KATSUNORIMIYATA YASUTOYAO YASUKO
    • C21C5/28B09B3/00C04B5/00C21B13/08C21C1/02F27D15/00
    • Y02P10/212
    • PROBLEM TO BE SOLVED: To inexpensively recover metal iron from decarburization refining slag and preliminary dephosphorized slag which are produced in a steelmaking process and utilize the steelmaking slag as a civil engineering and construction material or an environmental improvement material, which do not cause volume expansion and clouding phenomenon of seawater, and further as raw materials for phosphate fertilizers.SOLUTION: In the method for resource recovery from steelmaking slag, decarburization refining slag produced in decarburization refining of molten iron in a converter and preliminary dephosphorized slag produced in preliminary dephosphorization treatment of molten iron are mixed such that a basicity (mass% of CaO/mass% of SiO) of the mixture after the mixing of the slag is 1.5-2.8, reduction treatment for the reduction of an iron oxide in the slag is subjected to the mixture using a reducing agent containing one or more selected from carbon, silicon and aluminum, and the slag after the reduction treatment is used as one or more of a civil engineering and construction material, an environmental improvement material and raw materials for phosphate fertilizers, while metal iron obtained through the reduction treatment is used as an iron source.
    • 要解决的问题:从炼钢过程中生产的脱碳精炼渣和预脱磷炉中廉价回收金属铁,并利用炼钢渣作为土木工程和建筑材料或环境改善材料,不会造成 体积膨胀和海水混浊现象,进一步成为磷肥的原料。 解决方案:在炼钢渣资源回收方法中,将转炉中铁水脱碳精炼产生的脱碳精炼渣和在铁水预脱磷处理中产生的预脱磷渣混合,使碱度(质量% 炉渣混合后混合物的CaO / CaO /质量%SiO 2 )为1.5〜2.8,对炉渣中的氧化铁还原处理进行了 使用含有选自碳,硅和铝中的一种或多种的还原剂的混合物,还原处理后的渣用作土木工程和建筑材料,环境改善材料和磷酸盐肥料的原料中的一种或多种,​​而 使用通过还原处理得到的金属铁作为铁源。 版权所有(C)2012,JPO&INPIT
    • 6. 发明专利
    • スラグ塊状物及びその製造方法
    • JP2017114736A
    • 2017-06-29
    • JP2015253393
    • 2015-12-25
    • Jfeスチール株式会社Jfe Steel Corp
    • MIYATA YASUTO
    • C04B5/00C21C5/28F27D15/02
    • 【課題】スラグの種類を問わず原料として使用できるとともに、凝固収縮孔が生じたり、内部歪みによる破壊が生じたりすることがないスラグ塊状物を、特別な専用設備を要することなく、少ない手間と時間で低コストに製造する。【解決手段】粒子間の空隙率が30vol%以上となるような粒度を有する粒状スラグを層状に敷き詰めてスラグ層を形成し、このスラグ層に溶融スラグを流し込んで粒子間隙に溶融スラグを流入させ、溶融スラグを凝固させることにより、この凝固したスラグと前記粒状スラグとからなるスラグ塊状物を得る。このスラグ塊状物は、粒状スラグが溶融スラグを小さく分断する役割を果たすため、凝固時の収縮による収縮孔が個々の空隙内に分散して生成し、収縮歪みも同様に分散し、さらには、CaO・SiO2鉱物のγ変態に伴い発生する応力も分散される。このため、大きな凝固収縮孔が生じにくく、また、塊状物を破壊に至らしめるような大きな内部歪みが生じにくい。【選択図】図1
    • 7. 发明专利
    • Method for modifying bottom sediment
    • 修改底层沉积物的方法
    • JP2013039524A
    • 2013-02-28
    • JP2011177611
    • 2011-08-15
    • Jfe Steel CorpJfeスチール株式会社
    • MIYATA YASUTOYABUTA KAZUYA
    • C02F11/00E02B3/00
    • PROBLEM TO BE SOLVED: To provide a method for modifying bottom sediment containing much sulfide and nitrogen in a field of modifying costal sea area environment using slag, especially using steelmaking slag, without generating ammonia odor so as to prevent malodor from sludge, such as hydrogen sulfide odor, and elution of the sulfide stably over a long period of time.SOLUTION: The steelmaking slag is put into the sediment containing sulfide and mixed to become a mixture of the sediment and the steelmaking slag. The mixture is in a range of at least 20 cm deep from the surface of the sludge and has a pH value of 8.3 to 9.3.
    • 要解决的问题:提供一种在使用炉渣,特别是使用炼钢炉渣改性海底环境环境中改善含有大量硫化物和氮的底部沉积物的方法,而不产生氨气味,以防止恶臭的污泥, 例如硫化氢气味,长时间稳定地洗脱硫化氢。

      解决方案:将炼钢渣放入含硫化物的沉淀物中,混合成为沉淀物和炼钢渣的混合物。 该混合物在距污泥表面至少20厘米的范围内,pH值为8.3至9.3。 版权所有(C)2013,JPO&INPIT

    • 8. 发明专利
    • Raw material for blast furnace, and method for manufacturing the same
    • 用于高炉的原材料及其制造方法
    • JP2012072473A
    • 2012-04-12
    • JP2010219770
    • 2010-09-29
    • Jfe Steel CorpJfeスチール株式会社
    • TOFUSA HIROYUKIMIYATA YASUTO
    • C21B5/00C21B3/04C21C1/02C22B1/243
    • Y02W30/542
    • PROBLEM TO BE SOLVED: To provide a raw material for a blast furnace manufactured using molten iron desulfurization slag as a main raw material, and capable of being used without deteriorating permeability of the inside of the blast furnace, and a method for manufacturing the same.SOLUTION: The raw material for the blast furnace is composed of molten iron desulfurization slag, and crushed matter of hydration hardened object obtained by hydration-hardening a kneaded material of fine powder of granulated blast furnace slag. In the method for manufacturing the raw material, kneading is carried out by adding fine powder of the granulated blast furnace slag and water to the molten iron desulfurization slag, and the massive raw material for blast furnaces is obtained by a crushing process and a classifying process after hydration hardening of the kneaded material. Since the raw material for blast furnaces using molten iron desulfurization slag as a main raw material is massive and sufficiently strong, it can be used without deteriorating permeability of the inside of the blast furnace.
    • 要解决的问题:提供一种使用铁水脱硫渣作为主要原料制造的高炉的原料,并且能够在不使高炉内部的渗透性恶化的情况下使用,以及制造方法 一样。

      解决方案:高炉原料由铁水脱硫渣和水化硬化物质粉碎物质组成,水化硬化物质通过水化硬化粒状高炉矿渣细粉末的混炼物而得到。 在原料的制造方法中,通过向铁水脱硫渣中加入粒状高炉渣和水的细粉而进行混炼,通过破碎法和分级法获得大量的高炉原料 在捏合材料水化硬化后。 由于使用铁水脱硫渣作为主要原料的高炉原料大而且足够强,所以可以使用而不会使高炉内部的渗透性降低。 版权所有(C)2012,JPO&INPIT

    • 9. 发明专利
    • Method for treating slag containing sulfur and calcium
    • 用于处理含有硫和硫酸钙的方法
    • JP2011093761A
    • 2011-05-12
    • JP2009251157
    • 2009-10-30
    • Jfe Steel CorpJfeスチール株式会社
    • MIYATA YASUTOWATANABE KEIJITAKAHASHI KATSUNORIYABUTA KAZUYA
    • C04B5/00C01F11/18C21B3/04C21C1/02F27D15/00
    • C04B5/00
    • PROBLEM TO BE SOLVED: To provide a treatment method whereby sulfur content and water-soluble Ca content can be effectively reduced in slag containing sulfur and Ca.
      SOLUTION: The treatment method comprises steps of: soaking the slag containing sulfur and Ca in a solvent, blowing carbon dioxide into the solvent and adjusting pH of the solvent to 4-10, thereby extracting a sulfur component and a Ca component contained in the slag into the solvent and reacting the extracted Ca component with the carbon dioxide so as to produce calcium carbonate; and recovering the calcium carbonate together with the treated slag. The treatment method enables efficient extraction of the sulfur component and the Ca component contained in the slag into the solvent and fixation of the Ca component as calcium carbonate, thereby effectively reducing the sulfur content and the Ca content in the slag containing sulfur and Ca.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种处理方法,其中可以在含硫和Ca的炉渣中有效降低硫含量和水溶性Ca含量。 解决方案:处理方法包括以下步骤:将含硫和Ca的渣浸泡在溶剂中,将二氧化碳吹入溶剂中,并将溶剂的pH调节至4-10,从而提取含硫成分和Ca成分 在炉渣中加入溶剂中,使提取的Ca成分与二氧化碳反应,生成碳酸钙; 并与处理的炉渣一起回收碳酸钙。 该处理方法能够有效地提取炉渣中所含的硫成分和Ca成分进入溶剂,并将Ca成分固定为碳酸钙,从而有效降低含硫和Ca含量的硫含量和Ca含量。 版权所有(C)2011,JPO&INPIT