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    • 1. 发明专利
    • Supported catalyst of platinum group metal, method of producing treated water removed of hydrogen peroxide by decomposing the same, method of producing treated water removed of dissolved oxygen, and method of washing electronic parts
    • 铂族金属的负载催化剂,通过分解其去除过氧化氢的处理水的方法,除去溶解氧的生产经处理的水的方法和洗涤电子部件的方法
    • JP2010214320A
    • 2010-09-30
    • JP2009065841
    • 2009-03-18
    • Japan Organo Co Ltdオルガノ株式会社
    • INOUE HIROSHITAKADA HITOSHITAKAHASHI KAZUSHIGESUGAWARA HIROSHI
    • B01J31/28C02F1/58C02F1/70C08J9/00
    • PROBLEM TO BE SOLVED: To provide a high performance catalyst capable of decomposing/removing hydrogen peroxide or of removing dissolved oxygen even if water is allowed to flow therethrough at such a high SV of higher than 2,000h -1 and even if the height of a packed bed of the catalyst is made low. SOLUTION: The supported catalyst of platinum group metal includes nanoparticles of platinum group metal of a mean diameter of 1 to 100 nm supported by a porous organic anion exchanger. The porous organic anion exchanger includes an open-cell structure comprising mutually communicating macropores and common openings (mesopores) of a mean diameter in a dry state of 1 to 1,000 μm each disposed in the walls of the macropores, has a total pore volume of 1 to 50 ml/g, comprises anion exchanging groups uniformly distributed therein, has an anion exchanging capacity of 0.5 to 5.0 mg equivalent/g of dry porous body, and includes the platinum group metal supported thereby in an amount in a dry state of 0.004 to 20 wt.%. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种能够分解/除去过氧化氢或除去溶解氧的高性能催化剂,即使允许水以高于2000h -1的高SV流过其中, / SP>,即使催化剂的填充床的高度变低。 解决方案:铂族金属的负载催化剂包括由多孔有机阴离子交换剂负载的平均直径为1至100nm的铂族金属的纳米颗粒。 所述多孔有机阴离子交换剂包括开放式电池结构,其包含相互连通的大孔和设置在大孔壁中的干燥状态为1〜1000μm的平均直径的共同孔(介孔),总孔体积为1 至50ml / g,包含均匀分布在其中的阴离子交换基团,具有0.5-5.0mg当量/ g干多孔体的阴离子交换容量,并且包括其中负载的铂族金属,其干燥状态为0.004至 20重量%。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Carbon-carbon bond-forming method and platinum group metal carrier catalyst for carbon-carbon bond-forming reaction
    • 碳碳偶合成型方法和碳组合金属载体催化剂用于碳碳偶合反应
    • JP2014015420A
    • 2014-01-30
    • JP2012154267
    • 2012-07-10
    • Japan Organo Co Ltdオルガノ株式会社
    • TAKADA HITOSHIINOUE HIROSHINAKAMURA AKIRASAJIKI HIRONAOKADOGUCHI HIROYASAWAMA YOSHINARIITO MAKOTO
    • C07C41/30C07B61/00C07C43/205C07C45/68C07C49/223C07C67/343C07C69/618C07C201/12C07C205/06C07C209/68C07C211/45
    • PROBLEM TO BE SOLVED: To provide a method of forming a carbon-carbon bond efficiently.SOLUTION: A carbon-carbon bond-forming method includes a reaction of an aromatic halide and an organoboron compound, a reaction of the aromatic halide and a compound having an alkynyl group at its terminal etc. in the presence of a platinum group metal carrier catalyst that is a platinum group metal carrier catalyst carrying nano particles of the platinum group metal having an average particle size of 1 to 100 nm on a non-particulate organic porous ion exchanger. The non-particulate organic porous ion exchanger contains a continuous skeleton phase and a continuous pore phase, and a thickness of the continuous skeleton is 1 to 100 μm, an average diameter of the continuous pore is 1 to 1000 μm, a total pore volume is 0.5 to 50 ml/g, an ion exchange capacity is 1 to 6 mg equivalent/g per a weight in dry conditions, and an ion exchange group is distributed in the organic porous ion exchanger uniformly, and an amount of the platinum group metal carried is 0.004 to 20 wt.% in dry conditions.
    • 要解决的问题:提供一种有效形成碳 - 碳键的方法。解决方案:碳 - 碳键形成方法包括芳族卤化物与有机硼化合物的反应,芳族卤化物与具有 在铂族金属载体催化剂存在下,在其末端具有炔基,该铂族金属载体催化剂是在非微粒有机物上载有平均粒度为1〜100nm的铂族金属的纳米颗粒的铂族金属载体催化剂 多孔离子交换器。 非颗粒状有机多孔质离子交换体含有连续的骨架相和连续的孔相,连续骨架的厚度为1〜100μm,连续孔的平均直径为1〜1000μm,总孔体积为 0.5〜50ml / g,干燥条件下的离子交换容量为1〜6mg当量/ g,有机多孔质离子交换器中分离出离子交换基团,并且携带有铂族金属的量 在干燥条件下为0.004至20重量%。
    • 4. 发明专利
    • Platinum group metal-deposited catalyst, method for producing water treated with the catalyst to decompose hydrogen peroxide, method for producing water treated with the catalyst to remove dissolved oxygen, and method for cleaning electronic component
    • 铂族金属沉积催化剂,用于生产用催化剂处理过氧化氢的方法,用于生产用催化剂处理的水以除去溶解的氧气的方法,以及用于清洁电子组件的方法
    • JP2011036807A
    • 2011-02-24
    • JP2009186432
    • 2009-08-11
    • Japan Organo Co Ltdオルガノ株式会社
    • INOUE HIROSHITAKADA HITOSHITAKAHASHI KAZUSHIGESUGAWARA HIROSHI
    • B01J31/28C02F1/58
    • PROBLEM TO BE SOLVED: To provide a high-performance catalyst which can decompose/remove hydrogen peroxide or remove dissolved oxygen even when the water, which is to be treated and contains hydrogen peroxide or dissolved oxygen, is made to pass through the catalyst at the SV (space velocity) exceeding 2,000 h -1 and further the height of a catalyst-packed layer is made thin. SOLUTION: The platinum group metal-deposited catalyst is obtained by depositing a platinum group metal nanoparticle having 1-100 nm average particle size on an organic porous anion exchanger. The organic porous anion exchanger is a continuous macroporous structure which is characterized in that bubble-like macropores are superposed on one another and superposed portions become openings having 20-300 μm in water-wet states, the skeleton part of which has a top layer part of a porous structure. The organic porous anion exchanger has ≥0.4 mg-equivalent/ml anion exchange capacity per volume in a water-wet state. An anion exchange group is distributed uniformly in the organic porous anion exchanger. The amount of the platinum group metal to be deposited is 0.004-20 wt.% in a dry state. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供一种能够分解/除去过氧化氢或除去溶解氧的高性能催化剂,即使被处理并含有过氧化氢或溶解氧的水被制成通过 SV(空速)超过2000h -1的催化剂,进一步使催化剂填充层的高度变薄。 解决方案:铂族金属沉积催化剂通过在有机多孔阴离子交换剂上沉积具有1-100nm平均粒度的铂族金属纳米颗粒而获得。 有机多孔阴离子交换剂是连续的大孔结构,其特征在于,气泡状大孔彼此重叠并且叠置部分成为水湿状态的具有20-300μm的开口,其骨架部分具有顶层部分 的多孔结构。 有机多孔阴离子交换剂在水湿状态下的体积为≥0.4mg当量/ ml阴离子交换容量。 阴离子交换基团均匀分布在有机多孔阴离子交换剂中。 待沉积的铂族金属的量在干燥状态下为0.004-20重量%。 版权所有(C)2011,JPO&INPIT
    • 5. 发明专利
    • Platinum-group metal supported catalyst, method of producing treated water with hydrogen peroxide composed, method of producing treated with dissolved oxygen removed and method of cleaning electronic part
    • 铂族金属负载催化剂,用过氧化氢生产处理水的方法,用去除的氧化物生产处理的方法和清洁电子部件的方法
    • JP2010259989A
    • 2010-11-18
    • JP2009111758
    • 2009-05-01
    • Japan Organo Co Ltdオルガノ株式会社
    • INOUE HIROSHITAKADA HITOSHITAKAHASHI KAZUSHIGESUGAWARA HIROSHI
    • B01J31/28B01J35/02B01J35/10B08B3/04C02F1/58C02F1/70
    • PROBLEM TO BE SOLVED: To provide a high-performance catalyst allowing decomposition removal of hydrogen peroxide and removal of dissolved oxygen even when water is passed at a high SV higher than 2,000 h -1 and the height of the packed bed of the catalyst is reduced. SOLUTION: A platinum-group metal supported catalyst includes nano-particles of a platinum-group metal supported in an organic porous anion exchange material, and the organic porous anion exchange material is a composite structure of an organic porous material which includes a continuous backbone phase and a continuous pore phase and a large number of grains of diameters of 4-40 μm adhered to the surface of the backbone of the organic porous material or a large number of protrusions of sizes of 4-40 μm formed on the surface of the backbone of the organic porous material and has an average diameter of pores of 10-150 μm, a total volume of pores of 0.5-5 ml/g and an anion exchange capacity per volume of at least 0.2 mg equiv./ml in a water-wetted state. Anion exchange groups are distributed uniformly in the composite structure. The nano-particles of the platinum-group metal of an average particle size of 1-100 nm are supported in a wt.% of 0.004-20 in a dry state. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供高性能的催化剂,即使当水以高于2000h -1的高SV通过时,也能够分解除去过氧化氢和除去溶解氧,并且 催化剂填充床的高度降低。 解决方案:铂族金属负载催化剂包括负载在有机多孔阴离子交换材料中的铂族金属的纳米颗粒,有机多孔阴离子交换材料是有机多孔材料的复合结构,其包括 连续主链相和连续孔相和大量直径为4-40μm的颗粒粘附到有机多孔材料的骨架的表面上或在表面上形成大量4-40μm的突起 的有机多孔材料的主链,并且具有10-150μm的孔的平均直径,0.5-5ml / g的孔的总体积和每体积的阴离子交换容量至少为0.2mg当量/ ml 水润状态。 阴离子交换基团在复合结构中均匀分布。 平均粒度为1-100nm的铂族金属的纳米颗粒在干燥状态下以0.004-20重量%的量负载。 版权所有(C)2011,JPO&INPIT
    • 7. 发明专利
    • Monolith organic porous body, monolith organic porous ion exchanger, method for producing those and chemical filter
    • MONOLITH有机多孔体,MONOLITH有机多孔离子交换器,生产这些和化学过滤器的方法
    • JP2009062512A
    • 2009-03-26
    • JP2008081731
    • 2008-03-26
    • Japan Organo Co Ltdオルガノ株式会社
    • INOUE HIROSHINAKAMURA AKIRATAKADA HITOSHIKONDO SATOSHIYAMANAKA KOJINISHIMURA HIROYUKI
    • C08F257/02B01J20/26B01J39/20B01J41/14C08J7/12
    • PROBLEM TO BE SOLVED: To provide a monolith organic porous body being chemically stable, having high mechanical strength and low pressure loss when a fluid passes through the porous body and capable of being used as an absorbent having large adsorption capacity or an ion exchanger having large ion exchange volume per volume and a monolith ion exchanger and to provide a method for producing the ion exchanger and to provide a chemical filter. SOLUTION: The monolith organic porous body is characterized in that the porous body has a continuous macropore structure having ≥1 mm thickness and 0.5-5 ml/g whole pore volume in which foam-shaped macropores overlaps each other and the overlap part becomes an opening having a 20-200 μm average diameter and a skeleton section area which appears in cross section is 25-50% in a photographic region in SEM photograph of a cut surface of the continuous macropore structure. The monolith ion exchanger is obtained by introducing an ion exchange group into the monolith organic porous body. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种化学稳定的整体有机多孔体,当流体通过多孔体并能够用作具有大吸附能力的吸收剂或离子的吸收剂时具有高机械强度和低压力损失 交换器,具有大的离子交换体积/单体离子交换器,并提供一种生产离子交换器的方法并提供一种化学过滤器。 整体有机多孔体的特征在于,多孔体具有连续的大孔结构,其具有≥1mm厚度和0.5-5ml / g全孔体积,其中泡沫形大孔彼此重叠,并且重叠部分 在连续大孔结构的切割面的SEM照片中,成为具有20-200μm平均直径的开口和在照相区域中截面为25-50%的骨架截面积。 单体离子交换剂是通过将离子交换基团引入整体有机多孔体而获得的。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Apparatus and method for treatment of drain water
    • 排水水处理设备及方法
    • JP2014166607A
    • 2014-09-11
    • JP2013038991
    • 2013-02-28
    • Japan Organo Co Ltdオルガノ株式会社
    • FUKUMIZU KEIICHIROINOUE HIROSHITAKADA HITOSHI
    • C02F9/00C02F1/32C02F1/42C02F1/58C02F1/72C02F1/78
    • PROBLEM TO BE SOLVED: To provide a treatment apparatus for drain water which reduces the amount of organic matter in drain water by a simple method, removes hydrogen peroxide, a by-product produced in the apparatus, and is capable of recovering drain water as high-purity water.SOLUTION: A treatment apparatus for drain water includes a reductor 10 which carries out a reduction treatment of drain water containing peroxide and organic matter, an ion ingredient remover 12 which removes ion ingredients contained in the reduction treatment water treated by the reductor 10, an organic matter oxidation unit 14 which oxidizes organic matter contained in the ion ingredient removed water treated by the ion ingredient remover 12 and a hydrogen peroxide remover 16 which removes hydrogen peroxide produced in the organic matter oxidation unit 14.
    • 要解决的问题:为了提供通过简单的方法减少排水中的有机物的量的排水的处理装置,除去在装置中产生的副产物的过氧化氢,并且能够回收排水高 用于排水的处理装置包括:对含有过氧化物和有机物质的排水进行还原处理的还原剂10;离子成分去除剂12,其除去由还原剂处理的还原处理水中所含的离子成分 10表示有机物质氧化装置14,该有机物质氧化装置14对由离子成分去除剂12除去的水除去的有机物进行氧化,除去在有机物氧化装置14中产生的过氧化氢的过氧化氢去除剂16。