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1. 发明专利

JP2014030820A Platinum group metal supported catalyst and reactor 有权
标题翻译：铂族金属负载催化剂和反应器
公开(公告)号：JP2014030820A
公开(公告)日：2014-02-20
申请号：JP2013144785
申请日：2013-07-10
申请人： Japan Organo Co Ltd , オルガノ株式会社
发明人： TAKADA HITOSHI , INOUE HIROSHI , NAKAMURA AKIRA , SAJIKI HIRONAO , KADOGUCHI HIROYA , SAWAMA YOSHINARI , ITO MAKOTO , HATTORI TOMOHIRO
IPC分类号： B01J31/08 , B01J35/10 , C07B61/00 , C07C1/22 , C07C5/08 , C07C15/18 , C07C15/24 , C07C41/30 , C07C43/20 , C07C45/68 , C07C49/796 , C07C67/303 , C07C67/343 , C07C69/616 , C07C69/618 , C07C201/12 , C07C205/06 , C07C227/04 , C07C229/60
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a platinum group metal supported catalyst having a higher reaction rate and higher catalytic activity.SOLUTION: A platinum group metal supported catalyst comprises a non-particulate organic porous cation exchanger supporting nanoparticles of platinum group metal of an average particle diameter 1-100 nm. The non-particulate organic porous cation exchanger includes a continuous skeleton phase and a continuous pore phase. A thickness of the continuous skeleton is 1-100 μm, an average diameter of the continuous pore is 1-1000 μm, and total pore volume is 0.5-50 ml/g. Cation exchange capacity per weight in a dry state is 1-6 mg equivalent/g. Cation exchange groups are uniformly dispersed in the organic porous cation exchanger. A content of the platinum group metal is 0.004-20 wt.% in a dry state.
摘要翻译：要解决的问题：提供具有较高反应速率和较高催化活性的铂族金属负载型催化剂。解决方案：铂族金属负载催化剂包含一种非颗粒状有机多孔阳离子交换剂，其负载平均颗粒中铂族金属纳米颗粒直径1-100nm。非颗粒有机多孔阳离子交换剂包括连续的骨架相和连续的孔相。连续骨架的厚度为1-100μm，连续孔的平均直径为1-1000μm，总孔体积为0.5-50ml / g。干燥状态下每重量的阳离子交换容量为1-6mg当量/ g。阳离子交换基团均匀分散在有机多孔阳离子交换剂中。在干燥状态下，铂族金属的含量为0.004〜20重量％。

2. 发明专利

JP2014015420A Carbon-carbon bond-forming method and platinum group metal carrier catalyst for carbon-carbon bond-forming reaction 有权
标题翻译：碳碳偶合成型方法和碳组合金属载体催化剂用于碳碳偶合反应
公开(公告)号：JP2014015420A
公开(公告)日：2014-01-30
申请号：JP2012154267
申请日：2012-07-10
申请人： Japan Organo Co Ltd , オルガノ株式会社
发明人： TAKADA HITOSHI , INOUE HIROSHI , NAKAMURA AKIRA , SAJIKI HIRONAO , KADOGUCHI HIROYA , SAWAMA YOSHINARI , ITO MAKOTO
IPC分类号： C07C41/30 , C07B61/00 , C07C43/205 , C07C45/68 , C07C49/223 , C07C67/343 , C07C69/618 , C07C201/12 , C07C205/06 , C07C209/68 , C07C211/45
摘要： PROBLEM TO BE SOLVED: To provide a method of forming a carbon-carbon bond efficiently.SOLUTION: A carbon-carbon bond-forming method includes a reaction of an aromatic halide and an organoboron compound, a reaction of the aromatic halide and a compound having an alkynyl group at its terminal etc. in the presence of a platinum group metal carrier catalyst that is a platinum group metal carrier catalyst carrying nano particles of the platinum group metal having an average particle size of 1 to 100 nm on a non-particulate organic porous ion exchanger. The non-particulate organic porous ion exchanger contains a continuous skeleton phase and a continuous pore phase, and a thickness of the continuous skeleton is 1 to 100 μm, an average diameter of the continuous pore is 1 to 1000 μm, a total pore volume is 0.5 to 50 ml/g, an ion exchange capacity is 1 to 6 mg equivalent/g per a weight in dry conditions, and an ion exchange group is distributed in the organic porous ion exchanger uniformly, and an amount of the platinum group metal carried is 0.004 to 20 wt.% in dry conditions.
摘要翻译：要解决的问题：提供一种有效形成碳 - 碳键的方法。解决方案：碳 - 碳键形成方法包括芳族卤化物与有机硼化合物的反应，芳族卤化物与具有在铂族金属载体催化剂存在下，在其末端具有炔基，该铂族金属载体催化剂是在非微粒有机物上载有平均粒度为1〜100nm的铂族金属的纳米颗粒的铂族金属载体催化剂多孔离子交换器。非颗粒状有机多孔质离子交换体含有连续的骨架相和连续的孔相，连续骨架的厚度为1〜100μm，连续孔的平均直径为1〜1000μm，总孔体积为 0.5〜50ml / g，干燥条件下的离子交换容量为1〜6mg当量/ g，有机多孔质离子交换器中分离出离子交换基团，并且携带有铂族金属的量在干燥条件下为0.004至20重量％。

3. 发明专利

JP2014030821A Platinum group metal supported contact dehydrogenation catalyst and contact dehydrogenation method 有权
标题翻译：铂族金属支持接触脱氢催化剂和接触脱氢方法
公开(公告)号：JP2014030821A
公开(公告)日：2014-02-20
申请号：JP2013144786
申请日：2013-07-10
申请人： Japan Organo Co Ltd , オルガノ株式会社
发明人： TAKADA HITOSHI , INOUE HIROSHI , NAKAMURA AKIRA , SAJIKI HIRONAO , KADOGUCHI HIROYA , SAWAMA YOSHINARI , ITO MAKOTO , HATTORI TOMOHIRO
IPC分类号： B01J31/28 , C07B61/00 , C08J9/24
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a contact dehydrogenation catalyst and a contact dehydrogenation method having excellent reaction efficiency.SOLUTION: A platinum group metal supported contact dehydrogenation catalyst comprises a non-particulate organic porous ion exchanger supporting nanoparticles of platinum group metal of an average particle diameter 1-100 nm. The non-particulate organic porous ion exchanger includes a continuous skeleton phase and a continuous pore phase. Thickness of the continuous skeleton is 1-100 μm, an average diameter of the continuous pore is 1-1000 μm, and total pore volume is 0.5-50 ml/g. Ion exchange capacity per weight in a dry state is 1-6 mg equivalent/g. Ion exchange groups are uniformly dispersed in the organic porous cation exchanger. A content of the platinum group metal is 0.004-20 wt.% in a dry state.
摘要翻译：要解决的问题：提供一种接触脱氢催化剂和具有优异反应效率的接触脱氢方法。解决方案：铂族金属负载型接触脱氢催化剂包括一种非颗粒状有机多孔离子交换剂，其支持平均粒子的铂族金属纳米颗粒直径1-100nm。非颗粒状有机多孔离子交换器包括连续的骨架相和连续的孔相。连续骨架的厚度为1-100μm，连续孔的平均直径为1-1000μm，总孔体积为0.5-50ml / g。在干燥状态下每重量的离子交换容量为1-6mg当量/ g。离子交换基团均匀分散在有机多孔阳离子交换剂中。在干燥状态下，铂族金属的含量为0.004〜20重量％。

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