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    • 3. 发明专利
    • Radiation-sensitive resin composition
    • 辐射敏感性树脂组合物
    • JP2006133803A
    • 2006-05-25
    • JP2006005710
    • 2006-01-13
    • Jsr CorpJsr株式会社
    • IWAZAWA HARUOHAYASHI AKIHIROSHIMOKAWA TSUTOMU
    • G03F7/039C08K5/42C08L83/04G03F7/004G03F7/075H01L21/027
    • PROBLEM TO BE SOLVED: To provide a radiation-sensitive resin composition, containing a dissociable group-containing polysiloxane as a resin component and suitable for use as a chemically amplified resist, particularly superior in resolution. SOLUTION: The radiation-sensitive resin composition contains (A) the dissociable group-containing polysiloxane and (B) a radiation-sensitive acid generator, containing as essential components, a compound (B1) capable of generating an acid represented by Formula (I) and a compound (B2) capable of generating other sulfonic acid or a carboxylic acid. In the Formula (I), four symbols Rf each independently denote F or a trifluoromethyl group; Ra denotes a 3-20C cyclic monovalent hydrocarbon group or a 3-20C cyclic monovalent fluorinated hydrocarbon group, and the cyclic monovalent hydrocarbon group and the cyclic monovalent fluorinated hydrocarbon group may be substituted. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种含有可离解基团的聚硅氧烷作为树脂组分并且适合用作化学放大抗蚀剂的辐射敏感性树脂组合物,其分辨率特别优异。 解决方案:辐射敏感性树脂组合物含有(A)含离解基团的聚硅氧烷和(B)作为必需成分的辐射敏感性酸产生剂,能够产生由式 (I)和能够产生其它磺酸或羧酸的化合物(B2)。 在式(I)中,四个符号R f各自独立地表示F或三氟甲基; Ra表示3-20C环状一价烃基或3-20C环状一价氟化烃基,环状一价烃基和环状一价氟代烃基可以被取代。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Method of removing metal contained in alicyclic hydrocarbon polymer, and radiation-sensitive composition
    • 在ALICYCLIC HYDROCARBON聚合物中除去金属的方法和辐射敏感性组合物
    • JP2003342319A
    • 2003-12-03
    • JP2002153421
    • 2002-05-28
    • Jsr CorpJsr株式会社
    • SUWA YOSHINAKASE YOSHIHISAIWAZAWA HARUOSANO KIMIYASU
    • G03F7/039C08F6/08C08F32/04C08G67/02G03F7/26G03F7/38H01L21/027
    • PROBLEM TO BE SOLVED: To provide a purification process by which a metal contained in alicyclic hydrocarbon polymers as an impurity is removed and to provide a radiation-sensitive resin composition of a high performance photoresist which is composed of the purified polymer.
      SOLUTION: 1. The method of removing a metal contained in the alicyclic hydrocarbon polymer comprises the following processes: a process of coagulating the alicyclic hydrocarbon polymer by mixing an acid-added organic solvent solution of the polymer with its poor solvent, and a process of dissolving the coagulated polymer into a water-insoluble organic solvent, followed by bringing the solution into contact with an acidic hot water solution, extracting the metal contained therein. 2. The radiation-sensitive composition contains the alicyclic hydrocarbon polymer purified by the above-mentioned processes to remove the contained metal, and a radiation-sensitive acid generator.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供除去作为杂质的脂环烃聚合物中所含的金属的纯化方法,并提供由纯化的聚合物构成的高性能光致抗蚀剂的辐射敏感性树脂组合物。 解决方案:1.除去脂环烃聚合物中所含的金属的方法包括以下方法:通过将聚合物的加酸有机溶剂溶液与其不良溶剂混合而使脂环族烃聚合物凝结的方法,以及 将凝固的聚合物溶解在水不溶性有机溶剂中,然后使溶液与酸性热水溶液接触,萃取其中所含的金属的方法。 辐射敏感性组合物含有通过上述方法纯化的脂环烃聚合物以除去所含的金属和辐射敏感的酸产生剂。 版权所有(C)2004,JPO