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1. 发明专利

JP2004027179A Polymerization catalyst 有权
公开(公告)号：JP2004027179A
公开(公告)日：2004-01-29
申请号：JP2003024347
申请日：2003-01-31
申请人： Inst Of Physical & Chemical Res , 理化学研究所
发明人： AIDA SHOJIRO , KOU SHIYOUMIN , WAKATSUKI YASUO , DOI YOSHIHARU
IPC分类号： C08F4/52 , C08F4/54 , C08F4/60 , C08F4/603 , C08F36/00 , C08F36/04 , C08F136/08 , C08F212/00
CPC分类号： C08F36/04 , Y10S526/943 , C08F4/52 , C08F136/06 , C08F4/545
摘要： PROBLEM TO BE SOLVED: To provide a catalyst capable of effecting the polymerization of a conjugated diene or the copolymerization of a conjugated diene and an aromatic vinyl compound efficiently and at a low cost.
SOLUTION: The catalyst which polymerizes a conjugated diene and the like is composed of a metallocene type cationic complex of a gadlinium compound, e.g., a metallocene type cationic complex of a trivalent gadlinium compound to be represented by formula (I): R
a GdX
b (wherein Gd is gadlinium; R is a cyclopentadienyl group, a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a fluorenyl group or a substituted fluorenyl group; X is an anion; a is an integer of 1 or 2; and b is an integer of 1 or 2).
COPYRIGHT: (C)2004,JPO

2. 发明专利

JP2004027103A Catalyst composition 审中-公开
公开(公告)号：JP2004027103A
公开(公告)日：2004-01-29
申请号：JP2002187957
申请日：2002-06-27
申请人： Inst Of Physical & Chemical Res , 理化学研究所
发明人： AIDA SHOJIRO , KOU SHIYOUMIN , WAKATSUKI YASUO , DOI YOSHIHARU
IPC分类号： C08F4/54 , C08F4/60 , C08F4/6192 , C08F36/04 , C08F136/04 , C08F136/06
CPC分类号： C08F136/04 , C08F136/06 , C08F4/52 , C08F4/545
摘要： PROBLEM TO BE SOLVED: To provide a polymerization catalyst for efficiently producing a polymer which has a high content of a cis 1,4-structure in the microsturcture, a moderate molecular weight easy to mold, and simultaneously a narrow molecular distribution.
SOLUTION: The catalyst composition for the polymerization of a conjugated diene comprises (A) a metallocene type complex of a rare earth metal compound, (B) an aluminoxane, and (C) a combination of two or more organometallic compounds of groups I to III elements in the periodic table.
COPYRIGHT: (C)2004,JPO

3. 发明专利

JP2003292513A Catalyst composition 审中-公开
标题翻译：催化剂组合物
公开(公告)号：JP2003292513A
公开(公告)日：2003-10-15
申请号：JP2002094681
申请日：2002-03-29
申请人： Inst Of Physical & Chemical Res , 理化学研究所
发明人： AIDA SHOJIRO , KOU SHIYOUMIN , WAKATSUKI YASUO
IPC分类号： C08F4/54 , C08F4/60 , C08F36/00 , C08F136/04 , C08L9/00
CPC分类号： C08F136/04 , C08L9/00 , Y10S526/943 , C08F4/54 , C08F4/52
摘要： PROBLEM TO BE SOLVED: To provide a catalyst composition as a polymerization catalyst for producing polymers with high cis-1,4-structure content of the microstructure and narrow molecular weight distribution.
SOLUTION: The catalyst composition for polymerizing a conjugated diene comprises (A) a metallocene-type complex of general formula (I): (C
5 R
1 R
2 R
3 R
4 R
5 )
a MX
b .L
c [wherein, M is a rare earth metal atom; C
5 R
1 R
2 R
3 R
4 R
5 is a substituted cyclopentadienyl group; R
1 to R
5 are each a hydrocarbon group (except the case that R
1 , R
2 , R
3 , R
4 and R
5 are each methyl); X is H, a halogen atom, alkoxido group, thiolato group, amido group or 1-20C hydrocarbon group; L is a Lewis base compound; (a) is an integer of 1, 2 or 3; b is an integer of 0, 1 or 2; and c is an integer of 0, 1 or 2] and (B) an ionic compound composed of a non-coordinating anion and cation and/or aluminoxane.
COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供催化剂组合物作为聚合催化剂，用于生产具有显微组织的高顺式-1,4-结构含量和窄分子量分布的聚合物。解决方案：用于聚合共轭二烯的催化剂组合物包含（A）通式（I）的茂金属型络合物：（C 5 1 SP> 2 R 3 R 4 R 5 SB> .L [其中，M是稀土金属原子; 5 R＆lt; SP＆gt; 1＆lt; / SP＆gt; R＆lt; SP＆gt; 2＆lt; / SP＆gt; 是取代的环戊二烯基; R 1 至R 5 各为烃基（除了R 1 ，R 2 ，R 3 ，R 4 和R 5 各为甲基）; X是H，卤原子，烷氧基，硫醇基，酰氨基或1-20C烃基; L是路易斯碱化合物; （a）为1,2或3的整数; b是0,1或2的整数; 和c是0,1或2的整数]和（B）由非配位阴离子和阳离子和/或铝氧烷组成的离子化合物。版权所有（C）2004，JPO

4. 发明专利

JP2009057425A Method for producing cyclic olefin-based addition polymer 审中-公开
标题翻译：生产循环烯烃添加聚合物的方法
公开(公告)号：JP2009057425A
公开(公告)日：2009-03-19
申请号：JP2007224180
申请日：2007-08-30
申请人： Institute Of Physical & Chemical Research , Jsr Corp , Jsr株式会社 , Univ Nihon , 学校法人日本大学 , 独立行政法人理化学研究所
发明人： WAKATSUKI YASUO , AIDA SHOJIRO , TARDIF OLIVIER , MARUYAMA YOICHIRO
IPC分类号： C08F32/00 , C08F4/70
摘要： PROBLEM TO BE SOLVED: To provide a method for efficiently producing a cyclic olefin-based addition polymer excellent in physical and chemical heat resistances as well as in properties such as adhesion, tackiness, additive dispersiveness and solubility in a solvent.
SOLUTION: The method for producing the cyclic olefin-based addition polymer includes addition-polymerizing a specific cyclic olefin-based compound having a polar group in the presence of a catalyst component (A) which is a complex in which a cyclopentadienyl-based ligand coordinates with a transition metal selected from groups 8-10 elements of a periodic table, and a compound (B) which is at least one compound selected from the group consisting of an organic aluminum compound (a), a specific ionic compound (b), and a compound (c) which accelerates dissociation of the ligand in the catalyst component (A).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种有效地制备物理和化学耐热性优异的环状烯烃类加成聚合物以及粘合性，粘合性，添加剂分散性和溶剂中的溶解性等的方法。解决方案：制备环状烯烃系加成聚合物的方法包括在催化剂组分（A）的存在下加成聚合具有极性基团的特定的环状烯烃类化合物，该催化剂组分（A）是其中环戊二烯基 - 与选自元素周期表第8-10族元素的过渡金属配位的配位体和选自有机铝化合物（a），特定离子化合物（a）的至少一种化合物的化合物（B） b）和加速催化剂组分（A）中配体解离的化合物（c）。版权所有（C）2009，JPO＆INPIT

5. 发明专利

JP2005247901A 4-silyl-1-butene-3-yne polymer, copolymer with conjugated diene, and methods for producing them 审中-公开
标题翻译： 4-SILYL-1-BOTENE-3-YNE聚合物，具有共轭二烯的共聚物及其生产方法
公开(公告)号：JP2005247901A
公开(公告)日：2005-09-15
申请号：JP2004056521
申请日：2004-03-01
申请人： Denki Kagaku Kogyo Kk , Institute Of Physical & Chemical Research , 独立行政法人理化学研究所 , 電気化学工業株式会社
发明人： AIDA SHOJIRO , WAKATSUKI YASUO , DOI YOSHIHARU , OTSU TOSHIAKI
IPC分类号： C08F4/54 , C08F4/60 , C08F236/04 , C08F238/00
摘要： PROBLEM TO BE SOLVED: To obtain a novel polymer and a novel copolymer each comprising 4-silyl-1-butene-3-yne structural units.
SOLUTION: The 4-silyl-1-butene-3-yne polymer comprises structural units represented by formula (I) and structural units represented by formula (II). The copolymer comprises 4-silyl-1-butene-3-yne structural units and conjugated diene structural units. The method for producing the polymer or the copolymer comprises using a polymerization catalyst containing a rare earth metallocene complex.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了获得包含4-甲硅烷基-1-丁烯-3-基结构单元的新型聚合物和新型共聚物。解决方案：4-甲硅烷基-1-丁烯-3-炔聚合物包括由式（I）表示的结构单元和由式（II）表示的结构单元。该共聚物包括4-甲硅烷基-1-丁烯-3-元结构单元和共轭二烯结构单元。制造聚合物或共聚物的方法包括使用含有稀土金属茂络合物的聚合催化剂。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2004323743A Method for producing block copolymer 审中-公开
公开(公告)号：JP2004323743A
公开(公告)日：2004-11-18
申请号：JP2003122245
申请日：2003-04-25
申请人： Institute Of Physical & Chemical Research , 独立行政法人理化学研究所
发明人： AIDA SHOJIRO , WAKATSUKI YASUO , DOI YOSHIHARU
IPC分类号： C08F297/06
CPC分类号： C08F297/06
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a block copolymer of a conjugated diene and a polar monomer.
SOLUTION: This method for producing the block copolymer of the conjugated diene and the polar monomer comprises the homopolymerization of the conjugated diene in the presence of a catalyst composition containing (A) a metallocene complex of a rare earth metal compound and (B) an ionic compound composed of a non-coordinating anion and cation and/or an aluminoxane and the addition of the polar monomer to the homopolymerization product.
COPYRIGHT: (C)2005,JPO&NCIPI

7. 发明专利

JP2004238637A Polymerization catalyst 审中-公开
公开(公告)号：JP2004238637A
公开(公告)日：2004-08-26
申请号：JP2004158940
申请日：2004-05-28
申请人： Institute Of Physical & Chemical Research , 独立行政法人理化学研究所
发明人： AIDA SHOJIRO , KOU SHIYOUMIN , WAKATSUKI YASUO , DOI YOSHIHARU
IPC分类号： C08F4/54 , C08F4/606 , C08F36/04
摘要： PROBLEM TO BE SOLVED: To provide a catalyst capable of efficiently and economically performing polymerization of a conjugated diene and copolymerization of a conjugated diene with an aromatic vinyl compound. SOLUTION: The catalyst for polymerization of the conjugated diene and the like comprises a metallocene type cationic complex of a gadolinium compound, e.g., a trivalent gadolinium compound represented by the general formula: R a GdX b [wherein, Gd is gadolinium; R is (substituted) cyclopentadienyl, (substituted) indenyl or (substituted) fluorenyl; X is an anion; (a) is an integer of 1 or 2; and b is an integer of 1 or 2]. COPYRIGHT: (C)2004,JPO&NCIPI

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