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    • 2. 发明专利
    • Dye, photoelectric conversion element using the same, and photoelectrochemical cell
    • DYE,使用其的光电转换元件和光电化学电池
    • JP2010235908A
    • 2010-10-21
    • JP2009153051
    • 2009-06-26
    • Fujifilm Corp富士フイルム株式会社
    • USU TATSUYAKOBAYASHI KATSUKIMURA KEIZOSATO MUNEYOSHI
    • C09B57/00H01L31/04H01M14/00
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized cell having high conversion efficiency using an inexpensive organic dye. SOLUTION: A dye has a structure expressed by general formula (1) in a molecule, wherein A 1 is a six-membered or seven-membered nitrogen-containing heterocycle formed by connecting with a benzene ring, L 1 is an electron transfer connecting group containing at least one heterocycle selected from among a thiophene ring, a furan ring, a pyrrole ring, a selenophene ring and a heterocycle formed by the ring-fusing of these, R 1 and R 3 are independently a hydrogen atom or a substituent respectively, R 2 is a hydrogen atom or a substituent, B 1 is a methylene group substituted by a heterocyclic acid nucleus or an electron withdrawing group, B 1 has at least one acid group, and n1 is an integer of 1 to 12. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:使用便宜的有机染料提供具有高转化效率的染料敏化细胞。 解决方案:染料在分子中具有由通式(1)表示的结构,其中A 1是通过与苯连接形成的六元或七元含氮杂环 环,L 1 是含有至少一个选自噻吩环,呋喃环,吡咯环,硒吩环和通过环稠合形成的杂环的杂环的电子转移连接基团 这些R 1和R 3分别独立地表示氢原子或取代基,R 2是氢原子或取代基,B < SP> 1 是被杂环酸核或吸电子基取代的亚甲基,B 1具有至少一个酸基,n1是1〜12的整数。 P>版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Magnetic recording medium
    • 磁记录介质
    • JP2009054198A
    • 2009-03-12
    • JP2007217087
    • 2007-08-23
    • Fujifilm Corp富士フイルム株式会社
    • IMAKUNI AKIRASATO MUNEYOSHIHASHIMOTO HIROSHI
    • G11B5/738
    • PROBLEM TO BE SOLVED: To provide a magnetic recording medium which has excellent smoothness and electromagnetic transduction characteristics and suppresses cupping and sliding edge damage. SOLUTION: The magnetic recording medium is provided which has, on a non-magnetic support, a radiation cured layer formed by curing a layer containing a radiation curable compound and an inorganic powder by irradiation, wherein the radiation curable compound is a polycarbonate poly(meth)acrylate containing 50 to 100 wt.% monomer units having carbonate bonds in the whole monomer units and having a molecular weight of 1,000 to 10,000, the inorganic powder is surface treated by using a compound represented by formula (1) X k -Si-Y 4-k and having 5 to 50 nm average particle diameter and the inorganic powder content in the radiation cured layer is 25 to 65 vol.% of the whole volume of the radiation cured layer. In the formula (1), X denotes an alkyl group, an alkenyl group, aryl group or a (meth)acryloxy group, Y denotes a lower alkoxy group and k is an integer of 1 to 3. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有优异的平滑度和电磁转换特性的磁记录介质,并抑制拔罐和滑动边缘损坏。 解决方案:提供了在非磁性支撑件上具有通过照射固化含有可辐射固化化合物和无机粉末的层形成的辐射固化层的磁记录介质,其中可辐射固化化合物是聚碳酸酯 在整个单体单元中含有50-100重量%具有碳酸酯键且分子量为1,000至10,000的单体单元的聚(甲基)丙烯酸酯通过使用由式(1)表示的化合物进行表面处理, SB> k -Si-Y 4-k ,平均粒径为5〜50nm,辐射固化层中的无机粉末含量为整体的25〜65体积% 辐射固化层的体积。 在式(1)中,X表示烷基,烯基,芳基或(甲基)丙烯酰氧基,Y表示低级烷氧基,k表示1〜3的整数。 )2009,JPO&INPIT
    • 5. 发明专利
    • Magnetic recording medium
    • 磁记录介质
    • JP2009048684A
    • 2009-03-05
    • JP2007212021
    • 2007-08-16
    • Fujifilm Corp富士フイルム株式会社
    • SATO MUNEYOSHIHASHIMOTO HIROSHI
    • G11B5/738G11B5/70
    • PROBLEM TO BE SOLVED: To provide a magnetic recording medium having excellent coating film smoothness, electromagnetic transducing characteristics, a surface abnormality suppressing effect and a humidity expansion coefficient suppressing effect. SOLUTION: In the magnetic recording medium having a radiation cured layer formed by curing a layer containing a radiation curable compound and inorganic powder by irradiation with a radiation and a magnetic layer formed by dispersing ferromagnetic powder in a binder in this order on a non-magnetic supporting body, the inorganic powder has 5 to 50 nm average particle diameter, the surface of the inorganic powder is modified by using at least two or more kinds of silane coupling agents, at least one of the two or more kinds of silane coupling agents contains a (meth)acryloyl group and an inorganic powder content in the radiation cured layer is 30 to 60 vol%. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有优异的涂膜平滑度,电磁转换特性,表面异常抑制效果和湿度膨胀系数抑制效果的磁记录介质。 解决方案:在具有辐射固化层的磁记录介质中,所述辐射固化层通过用辐射固化包含辐射固化性化合物和无机粉末而形成,所述辐射和磁性层通过依次将铁磁性粉末分散在粘合剂中而形成 非磁性支撑体,无机粉末的平均粒径为5〜50nm,通过使用至少2种以上的硅烷偶联剂来改性无机粉体的表面,所述两种以上的硅烷 偶联剂含有(甲基)丙烯酰基,辐射固化层中的无机粉末含量为30〜60体积%。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Magnetic recording medium and manufacturing method thereof
    • 磁记录介质及其制造方法
    • JP2009181682A
    • 2009-08-13
    • JP2008022283
    • 2008-02-01
    • Fujifilm Corp富士フイルム株式会社
    • SATO MUNEYOSHIHASHIMOTO HIROSHI
    • G11B5/738G11B5/842
    • PROBLEM TO BE SOLVED: To provide a magnetic recording medium having excellent electromagnetic conversion characteristics and durability. SOLUTION: The magnetic recording medium has an intermediate layer formed by irradiating a composition including a radiation curable compound with a radiation and a magnetic layer including ferromagnetic powder and a binder in this order on a non-magnetic supporting body. The intermediate layer includes silica particles originating from silica sol modified by an organic compound, and the organic compound has a 6-36C saturated or unsaturated hydrocarbon group and at least one group selected from the group consisting of a phosphoric acid group, a sulfonic acid group, carboxylic acid group, phosphonic acid group, a phosphate group, an alkoxy group, an aryloxy group and an amino group. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有优异的电磁转换特性和耐久性的磁记录介质。 解决方案:磁记录介质具有通过在非磁性支撑体上依次将包含辐射固化性化合物的组合物和包含铁磁性粉末和粘合剂的磁性层照射的组合物形成的中间层。 中间层包括源自由有机化合物改性的二氧化硅溶胶的二氧化硅颗粒,有机化合物具有6-36℃的饱和或不饱和烃基和至少一个选自磷酸基,磺酸基 羧酸基,膦酸基,磷酸基,烷氧基,芳氧基和氨基。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Photoelectric conversion element, photoelectrochemical cell, and pigment
    • 光电转换元件,光电化学电池和颜料
    • JP2012084503A
    • 2012-04-26
    • JP2011059913
    • 2011-03-17
    • Fujifilm Corp富士フイルム株式会社
    • USU TATSUYASATO MUNEYOSHIKOBAYASHI KATSUKIMURA KEIZO
    • H01M14/00C09B23/00H01L31/04
    • H01G9/2059C09B57/007C09B57/10H01G9/2009H01G9/2031H01L51/0064H01M14/005Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a photoelectric conversion element and a photoelectrochemical cell capable of acquiring a high conversion efficiency even in a wavelength region exceeding 800 nm, and a pigment.SOLUTION: A photoelectric conversion element provided with a photoreceptor layer having the pigment composed of the chemical compounds represented in a general formula (1) and a semiconductor fine particle. [In the general formula (1), Q represents a tetravalent aromatic group. X, Xrepresent each independently a sulfur atom and an oxygen atom or C(R)R. R, Rrepresent each independently the heterocyclic groups linked by a hydrogen atom, an aliphatic group, an aromatic group, and a carbon atom. R, R' represent independently the heterocyclic groups linked by the aliphatic group, aromatic group, and carbon atom. P, Prepresent each independently non-metallic atom groups of specific structures. Pand Prepresent different structures. Wrepresents a counter ion required to neutralize an electric charge.]
    • 要解决的问题:提供即使在超过800nm的波长区域中也能获得高转换效率的光电转换元件和光电化学电池以及颜料。 解决方案:提供具有由通式(1)表示的化合物和半导体微粒组成的颜料的感光体层的光电转换元件。 [通式(1)中,Q表示四价芳香族基。 X 1 ,X 2 各自独立地表示硫原子和氧原子或C(R 1 )R 2 。 R 1 ,R 2 各自独立地表示由氢原子,脂族基团,芳族基团和 碳原子。 R,R'分别独立地表示由脂族基团,芳族基团和碳原子连接的杂环基。 P 1 ,P 2 表示各自独立的特定结构的非金属原子团。 P 1 ,P 2 表示不同的结构。 W 1 表示中和电荷所需的抗衡离子。]

      版权所有(C)2012,JPO&INPIT

    • 10. 发明专利
    • Photoelectric conversion element and photo-electrochemical cell
    • 光电转换元件和光电化学电池
    • JP2011119205A
    • 2011-06-16
    • JP2010048748
    • 2010-03-05
    • Fujifilm Corp富士フイルム株式会社
    • KOBAYASHI KATSUOMORI KOSHIKIMURA KEIZOSATO MUNEYOSHIUSU TATSUYA
    • H01M14/00C09B23/00C09B57/00H01L31/04
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide an inexpensive photoelectric conversion element having high conversion efficiency and excellent durability; and to provide a photo-electrochemical cell. SOLUTION: The photoelectric conversion element contains dye having structure represented by general formula (1). In general formula (1), X represents a non-metallic atom group necessary for forming a nitrogen-containing heterocyclic ring of a six-membered ring or a seven-membered ring by coupling with a benzene ring; Y represents a dye residue; n represents an integer of 1 or above; Z represents a substituent; m represents 0 or a positive integer; when m is 2 or above, Z may be the same or different; and R 1 represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic ring group binding with a carbon atom. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供具有高转换效率和优异耐久性的廉价的光电转换元件; 并提供光电池。 光电转换元件含有具有由通式(1)表示的结构的染料。 在通式(1)中,X表示通过与苯环的偶合形成六元环或七元环的含氮杂环所必需的非金属原子团; Y代表染料残留物; n表示1以上的整数, Z表示取代基; m表示0或正整数; 当m为2或更高时,Z可以相同或不同; R SP 1表示与碳原子结合的氢原子,脂肪族基团,芳香族基团或杂环基团。 版权所有(C)2011,JPO&INPIT