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    • 3. 发明专利
    • ELECTRODE FOR DETECTION OF HALOGEN ION
    • JPS57211055A
    • 1982-12-24
    • JP9688181
    • 1981-06-22
    • FUJI PHOTO FILM CO LTD
    • SESHIMOTO OSAMUSAKAGUCHI SHINJITAKAYAMA TAKESHISATOU AKIRA
    • G01N27/40G01N27/333
    • PURPOSE:To measure the concentration of a halogen ion or the activity of halogen electrically in a solution to be inspected, by providing a coating layer consisting of a copolymer copolymerized a specific hydrophobic monomer and specific hydrophylic monomer. CONSTITUTION:Metallic silver is vapor-deposited on a PET film and a silver/ silver chloride electrode is formed by immersing the surface of said silver layer in a treating solution of potassium dichromate and concentrated hydrochloric acid. A covering layer permeating a halogen ion is formed on the surface of the silver chloride electrode. This coating layer consists of a copolymer copolymerized at least one kind of hydrophobic monomer expressed by general formula (I) and at least one kind of hydrophilic monomer expressed by general formula (II). R is hydrogen atom, an alkyl radical or a halogen atom and R is an alkyl radical, a substituted alkyl radical, an alkoxicarbonyl radical or substituted alkoxicarbonyl radical, etc., in the formula (I). R is hydrogen atom or an alkyl radical and R is a 2-pyridyl radical or a hydroxy carbonyl radical, etc., in the formula (II).