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1. 发明专利

JP2009114453A Acid-sensitive compound and resin composition for photoresist 有权
标题翻译：酸敏感化合物和树脂组合物
公开(公告)号：JP2009114453A
公开(公告)日：2009-05-28
申请号：JP2008320062
申请日：2008-12-16
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： NAKANO TATSUYA
IPC分类号： C08F220/12 , C07C69/00 , C07C69/54 , G03F7/004 , G03F7/039 , H01L21/027
CPC分类号： G03F7/039 , C07C69/54 , C07C2602/28 , C07C2603/68 , C07C2603/74 , G03F7/0045
摘要： PROBLEM TO BE SOLVED: To form a finer line pattern by using a photoresist resin composition which is high in etching resistance, and can be solubilized by irradiation. SOLUTION: The photoresist resin composition comprises a polymer containing an acid-responsive compound unit of following formula (1) or (2) (e.g. an adamantane skeleton) and a photoactive acid precursor. In formulas, R 1 represents an alkyl group or a cycloalkyl group, and R 2 represents a hydrogen atom, an alkyl group or a cycloalkyl group, R 3 represents a hydrogen atom or a methyl group, R 4 represents a hydrogen atom, a halogen atom, an alkyl group, an oxygen-containing group, an amino group or an N-substituted amino group, the Z ring represents an adamantane ring, n represents an integer of not less than 1. In formula (1), R 1 and R 2 can, jointly and together with the adjacent carbon atom, form an alicyclic hydrocarbon ring. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：通过使用耐蚀刻性高的光致抗蚀剂树脂组合物形成更细的线图案，并且可以通过照射而溶解。光致抗蚀剂树脂组合物包含含有下式（1）或（2）的酸响应性化合物单元（例如金刚烷骨架）和光活性酸前体的聚合物。在式中，R 1表示烷基或环烷基，R 2表示氢原子，烷基或环烷基，R 3， / SP>表示氢原子或甲基，R 4表示氢原子，卤素原子，烷基，含氧基团，氨基或N-取代氨基，Z环表示金刚烷环，n表示不小于1的整数。在式（1）中，R 1 和R 2 可以共同并与相邻的碳原子形成脂环烃环。版权所有（C）2009，JPO＆INPIT

2. 发明专利

JP2008179644A Method for producing epoxy compound 有权
标题翻译：生产环氧化合物的方法
公开(公告)号：JP2008179644A
公开(公告)日：2008-08-07
申请号：JP2008025080
申请日：2008-02-05
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： ISHII YASUTAKA , NAKANO TATSUYA
IPC分类号： C07D301/06 , B01J23/30 , B01J31/02 , B01J31/04 , B01J31/22 , C07B61/00 , C07D303/14
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To produce an epoxy compound from a corresponding compound comprising a non-aromatic ethylenic double bond at a high yield with a simple operation. SOLUTION: The epoxy compound is produced by causing a corresponding compound comprising a non-aromatic ethylenic double bond to contact with oxygen in the presence of an oxidation catalyst constituted of a N-hydroxyimide compound derived from a saturated or unsaturated aliphatic dicarboxylic acid anhydride, an alicyclic polycarboxylic acid anhydride or an aromatic polycarboxylic acid anhydride and a co-catalyst constituted of at least one species selected from the group consisting of an elemental metal, a boron compound, a metal hydroxide, a metal oxide, an organic acid salt, an inorganic acid salt, an acetylacetonate complex, a carbonyl complex, a cyclopentadienyl complex, a nitrosyl compound, a thiocyanate complex, an acetyl complex, a polyacid and a polyacid salt, without using tetraphenylporphyrinate-manganese(III)chloride and styrene and pyridine. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：以简单的操作以高产率从包含非芳族烯键双键的对应化合物制备环氧化合物。解决方案：环氧化合物是通过在由由饱和或不饱和脂族二羧酸衍生的N-羟基酰亚胺化合物构成的氧化催化剂存在下，使含有非芳族烯键式双键的相应化合物与氧接触而制备的酸酐，脂环族多元羧酸酐或芳族多元羧酸酐，以及由选自元素金属，硼化合物，金属氢氧化物，金属氧化物，有机酸盐中的至少一种的助催化剂构成的助催化剂，无机酸盐，乙酰丙酮络合物，羰基络合物，环戊二烯基络合物，亚硝酰基化合物，硫氰酸酯络合物，乙酰基配合物，多酸和多酸盐，不使用四苯基卟啉 - 氯化锰（III）和苯乙烯和吡啶。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2008179605A Method for producing lactam 审中-公开
标题翻译：生产乳酸菌的方法
公开(公告)号：JP2008179605A
公开(公告)日：2008-08-07
申请号：JP2007295092
申请日：2007-11-14
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： ISHII YASUTAKA , SHIBAMOTO AKIHIRO , IWAHAMA TAKAHIRO , NAKANO TATSUYA
IPC分类号： C07D223/10 , C07B61/00 , C07D225/02
CPC分类号： C07D201/04 , C07D201/10 , Y02P20/52 , Y02P20/55
摘要： PROBLEM TO BE SOLVED: To provide a method for commercially and efficiently manufacturing a lactam from a cycloalkane at a high yield using a catalyst being friendly to the environment. SOLUTION: The method for manufacturing a lactam comprising a process A of synthesizing a corresponding cycloalkanone oxime by causing a cycloalkane and a nitrous acid ester to react with each other in the presence of a nitrogen-atom-containing cyclic compound (a) comprising a skeleton represented by formula (i) [wherein X represents an oxygen atom or an -OR group (R represents a hydrogen atom or a protective group of a hydroxy group)] as a component constituting the ring thereof and a process B of converting the resulting cycloalkanone oxime obtained in the process A to form a corresponding lactam by virtue of the Beckmann rearrangement, and also comprises a process of removing the nitrogen-atom-containing cyclic compound (a) in the midst of the process A and/or after completing the process A. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供使用对环境友好的催化剂以高产率从环烷烃商业上有效地制造内酰胺的方法。解决方案：制备内酰胺的方法，其包括通过使环烷烃和亚硝酸酯在含氮原子的环状化合物（a）的存在下相互反应来合成相应的环烷酮肟的方法A，包含由式（i）表示的骨架[其中X表示氧原子或-OR基团（R表示氢原子或羟基的保护基）]作为构成环的组分和转化在方法A中获得的所得环烷酮肟由于Beckmann重排而形成相应的内酰胺，并且还包括在方法A和/或之后除去含氮原子的环状化合物（a）的方法完成过程A.版权所有（C）2008，JPO＆INPIT

4. 发明专利

JP2007284415A Preparation of amide or lactam 审中-公开
标题翻译：生产酰胺或乳酸菌的方法
公开(公告)号：JP2007284415A
公开(公告)日：2007-11-01
申请号：JP2006244862
申请日：2006-09-08
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： ISHII YASUTAKA , NAKANO TATSUYA , IWAHAMA TAKAHIRO
IPC分类号： C07D201/04 , C07B61/00 , C07C231/10 , C07D223/10 , C07D225/02
CPC分类号： C07D201/04 , C07C231/10 , C07D223/10 , C07D225/02
摘要： PROBLEM TO BE SOLVED: To provide a process for producing an amide or a lactam by conducting rearrangement of an oxime compound to yield a corresponding amide or lactam, in which the amide or the lactam can be easily produced in a high yield without generating large amounts of by-products. SOLUTION: The production process for an amide or a lactam comprises conducting rearrangement of an oxime compound in the presence of a cyclic compound containing a structure represented by general formula (1) (wherein Z represents a halogen atom or an -OR group, and R represents an organic group) as a ring constituent, and a fluorinated alcohol to yield a corresponding amide or lactam. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供通过肟化合物的重排产生酰胺或内酰胺以产生相应的酰胺或内酰胺来生产酰胺或内酰胺的方法，其中酰胺或内酰胺可以以高产率容易地生产而没有产生大量的副产品。解决方案：酰胺或内酰胺的制备方法包括在含有通式（1）表示的结构的环状化合物的存在下进行肟化合物的重排（其中Z表示卤素原子或-OR基团，R表示有机基团）作为环成分，和氟化醇，得到相应的酰胺或内酰胺。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2007238562A Method for producing vinyl or allyl group-containing compound 有权
标题翻译：用于生产乙烯基或含全氟化合物的方法
公开(公告)号：JP2007238562A
公开(公告)日：2007-09-20
申请号：JP2006066531
申请日：2006-03-10
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： ISHII YASUTAKA , NAKANO TATSUYA , IWAHAMA TAKAHIRO
IPC分类号： C07F7/08 , B01J23/46 , C07B61/00 , C07C209/18 , C07C211/21 , C07C211/27 , C07C211/48 , C07F7/18
CPC分类号： C07C209/66 , C07F7/1836 , C07F7/1892 , C07C211/21 , C07C211/27 , C07C211/45
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a vinyl or allyl group-containing compound, by which the vinyl or allyl group-containing compound can simply be produced under mild conditions in a high yield. SOLUTION: This method for producing the vinyl or allyl group-containing compound comprises reacting a vinyl or allyl ester compound represented by formula (1) with a compound represented by formula (2): R 7 -Y-H in the presence of a transition element compound. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：提供一种制备含乙烯基或含烯丙基的化合物的方法，通过该方法，可以在温和的条件下以高产率制备含乙烯基或含烯丙基的化合物。解决方案：用于制备含乙烯基或含烯丙基的化合物的方法包括使由式（1）表示的乙烯基或烯丙基酯化合物与由式（2）表示的化合物反应：R -YH在过渡元素化合物的存在下。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2005255553A Method for producing n-containing ring compound 审中-公开
标题翻译：生产含氮环化合物的方法
公开(公告)号：JP2005255553A
公开(公告)日：2005-09-22
申请号：JP2004066198
申请日：2004-03-09
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： ISHII YASUTAKA , NAKANO TATSUYA , IWAHAMA TAKAHIRO
IPC分类号： C07D215/06 , C07B61/00 , C07D207/323 , C07D211/70 , C07D213/16 , C07D215/48 , C07D265/06
摘要： PROBLEM TO BE SOLVED: To provide a method for producing compounds bearing an N-containing heterocyclic rings, for example, quinoline ring, pyridine ring or the like starting from a carbonyl compound and an aminoalcohol under mild conditions.
SOLUTION: In the presence of a compound of a group 9 element and a base, a carbonyl compound of formula (1) (wherein R
1 , R
2 , Y are identical or different and shows each H or an organic group; at least two of R
1 , R
2 and Y may bond to each other and together with adjoining one or two carbon atoms to form a chain ring) and an aminoalcohol represented by formula (2) (wherein A is a divalent organic group, R
3 is H or an organic group, A and R
3 may link to each other to form a ring together with adjacent carbon atoms) are allowed to react with each other to produce a N-including ring compound.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种在温和条件下从羰基化合物和氨基醇开始制备带有含N杂环的化合物，例如喹啉环，吡啶环等。解决方案：在9族元素和碱的化合物存在下，式（1）的羰基化合物（其中R 1，R 2，R 2， Y相同或不同，表示每个H或有机基团; R 1 ，R 2 和Y中的至少两个可以彼此结合并与邻接的一个或两个碳原子形成链环）和由式（2）表示的氨基醇（其中A是二价有机基团，R 3 SP 3是H或有机基团，A和R 3 可以彼此连接形成环和相邻的碳原子）彼此反应以产生包含N的环化合物。版权所有（C）2005，JPO＆NCIPI

7. 发明专利

JP2005254085A Surface-modified titanium oxide photocatalyst and method of oxidizing organic compound using it 审中-公开
标题翻译：表面修饰的氧化钛光催化剂和使用其氧化有机化合物的方法
公开(公告)号：JP2005254085A
公开(公告)日：2005-09-22
申请号：JP2004066916
申请日：2004-03-10
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： YOKONO TERUHISA , NAKANO TATSUYA
IPC分类号： A61L9/00 , A61L9/01 , A61L9/20 , B01D53/86 , B01J19/12 , B01J31/38 , B01J33/00 , B01J35/02
摘要： PROBLEM TO BE SOLVED: To provide a surface-modified titanium oxide photocatalyst showing high photocatalytic activity and a method of oxidizing organic compounds using the catalyst. SOLUTION: The photocatalyst consists of a surface-modified titanium oxide coated with a porous ceramic film. The photocatalyst is preferably surface-modified with lipophilic groups, a metal compound or molecular-recognition groups. Preferably, the lipophilic group contains a 1-30C hydrocarbon group, the metal compound contains a metal complex, and the molecule-recognizing group corresponds to one or more of crown ethers, cyclodextrin and calixarene. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供显示高光催化活性的表面改性氧化钛光催化剂和使用该催化剂氧化有机化合物的方法。解决方案：光催化剂由涂覆有多孔陶瓷膜的表面改性氧化钛组成。光催化剂优选用亲脂基团，金属化合物或分子识别基团进行表面改性。优选地，亲油基团含有1-30C烃基，金属化合物含有金属络合物，分子识别基团相当于冠醚，环糊精和杯芳烃中的一种或多种。版权所有（C）2005，JPO＆NCIPI

8. 发明专利

JP2005213123A Carbon-doped titanium oxide and its producing method, photocatalyst, and method of oxidizing organic compound by using the catalyst 有权
标题翻译：碳化钛氧化物及其制备方法，光催化剂和使用催化剂氧化有机化合物的方法
公开(公告)号：JP2005213123A
公开(公告)日：2005-08-11
申请号：JP2004024726
申请日：2004-01-30
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： YOKONO TERUHISA , NAKANO TATSUYA
IPC分类号： C01G23/047 , B01J27/20 , B01J35/02 , C07B33/00 , C07B61/00 , C07C29/50 , C07C35/37 , C07C45/28 , C07C49/453
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a titanium oxide doped with another element showing a high catalytic activity even in a visible light at a long wavelength side and its producing method and a photocatalyst with a high activity. SOLUTION: The carbon-doped titanium oxide is a titanium oxide doped with carbon. Preferably, the carbon atom is doped as a carbon ion. The carbon-doped titanium oxide is produced by calcining a mixture of a titanium compound having oxygen atoms and a carbon source. In the presence of a photocatalyst composed of the carbon-doped titanium oxide, an organic compound having a part to be oxidized is oxidized with a molecular oxygen or a peroxide under an irradiation of light. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：即使在长波长一侧的可见光下也能够提供掺杂有另一种显示出高催化活性的元素的氧化钛及其制备方法和具有高活性的光催化剂。解决方案：碳掺杂的氧化钛是掺杂有碳的氧化钛。优选地，碳原子被掺杂为碳离子。通过煅烧具有氧原子的钛化合物和碳源的混合物来制造碳掺杂的氧化钛。在由碳掺杂的氧化钛组成的光催化剂的存在下，在光照射下，用分子氧或过氧化物氧化具有待氧化部分的有机化合物。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2009298706A Method for producing amide or lactam 审中-公开
标题翻译：生产酰胺或乳酸菌的方法
公开(公告)号：JP2009298706A
公开(公告)日：2009-12-24
申请号：JP2008152424
申请日：2008-06-11
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： IWAHAMA TAKAHIRO , NAKANO TATSUYA , ISHII YASUTAKA
IPC分类号： C07D201/04 , C07B61/00 , C07D223/10
CPC分类号： C07D201/04 , C07D223/10 , Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for easily producing an amide or a lactam at a high yield by causing the rearrangement reaction of an oxime compound to proceed, without generating a large amount of byproducts such as ammonium sulfate. SOLUTION: The method for producing an amide or a lactam comprises subjecting an oxime compound to a rearrangement reaction in the presence of a compound comprising a structure represented by the following formula (1)-Z-X (1) (in the formula, Z represents a P atom, an N atom, an S atom, a B atom or an Si atom, and X represents a leaving group, provided that Z is bound to one or two or more atom(s) or group(s) in addition to X) to form a corresponding amide or a corresponding lactam. In the production method, X may be a halogen atom. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供通过使肟化合物的重排反应进行而容易地以高产率制备酰胺或内酰胺的方法，而不产生大量的副产物如硫酸铵。解决方案：制备酰胺或内酰胺的方法包括在包含由下式（1）-ZX（1）表示的结构的化合物的存在下使肟化合物进行重排反应（式中， Z表示P原子，N原子，S原子，B原子或Si原子，X表示离去基团，条件是Z与一个或两个以上的原子或基团结合，除了X之外）以形成相应的酰胺或相应的内酰胺。在制造方法中，X可以是卤素原子。版权所有（C）2010，JPO＆INPIT

10. 发明专利

JP2009256306A Adamantane derivative having polymerizable unsaturated group, and method for producing the same 审中-公开
标题翻译：具有聚合性不饱和基团的亚胺衍生物及其制造方法
公开(公告)号：JP2009256306A
公开(公告)日：2009-11-05
申请号：JP2008227840
申请日：2008-09-05
申请人： Daicel Chem Ind Ltd , ダイセル化学工業株式会社
发明人： IWAHAMA TAKAHIRO , NAKANO TATSUYA , HEIYU TAKAHIRO , SON SHUKI , IGUCHI YUKI
IPC分类号： C07C69/54 , C07C31/27 , C07C35/37 , C07C67/14
摘要： PROBLEM TO BE SOLVED: To provide an adamantane derivative having a polymerizable unsaturated group, on making it a polymer, imparting high flexibility and excellent organic solvent solubility, and also imparting useful properties to a resin for photoresist, such as etching resistance, crosslinking reactivity, etc.
SOLUTION: This adamantane derivative having a polymerizable unsaturated group is expressed by formula (1) [wherein, R
1 is H or a 1-6C alkyl; (q), (n) are each an integer of ≥1; (m), (p) are each 0 or an integer of ≥1; (p+m) is ≥1; and when the (m) is ≥2, m(n)s are the same or different, provided that when (q)=1 and also (p)=0, (m) is an integer of ≥2, or (n) is an integer of ≥2].
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：为了提供具有可聚合不饱和基团的金刚烷衍生物，使其成为聚合物，赋予高柔性和优异的有机溶剂溶解性，并且还赋予光致抗蚀剂树脂（例如耐蚀刻性）有用的性质，交联反应性等。解决方案：具有可聚合不饱和基团的金刚烷衍生物由式（1）表示[其中，R SP = H或1-6C烷基; （q），（n）各自为≥1的整数; （m），（p）各自为0或≥1的整数; （p + m）≥1; 当（m）≥2时，m（n）s相同或不同，条件是当（q）= 1且（p）= 0时，（m）为≥2的整数，或（n ）是≥2的整数。版权所有（C）2010，JPO＆INPIT

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