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    • 7. 发明专利
    • PRODUCTION OF ALPHA-FLUOROACRYLIC ACID ESTER
    • JPS6078941A
    • 1985-05-04
    • JP18879683
    • 1983-10-07
    • DAIKIN IND LTD
    • OOMORI AKIRAKITAHARA TAKAHIRO
    • C07C69/653C07C67/327
    • PURPOSE:To produce the titled substance useful as a raw material of polymers having high softening temperature, etc. and excellent weather resistance, etc. and useful as a raw material of paint, etc., economically, by using alpha-fluoro-beta-hydroxypropionic acid ester as a raw material, and reacting the compound with a dehydration agent. CONSTITUTION:The objective compound can be produced by reacting alpha-fluoro-beta- hydroxypropionic acid ester with a dehydration agent in a solvent such as methanol at 30-150 deg.C, preferably 50-100 deg.C. The dehydration agent is a substance capable of removing the alpha-hydrogen and beta-hydroxyl group of the above starting compound, preferably sulfuric acid, phosphoric acid or phosphorus pentoxide, and its amount is usually preferably 0.1-2mol per 1mol of the starting compound. To prevent the undesirable reaction of the produced objective compound, e.g. polymerization, etc., it is preferable to add a polymerization inhibitor, e.g. hydroquinone, etc. to the reaction system in an amount of less than several % based on the objective compound.