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    • 4. 发明专利
    • Method for producing concentrated lithium hexafluorophosphate solution
    • 用于生产浓缩的四氢十六烷基磷酸盐溶液的方法
    • JP2013166680A
    • 2013-08-29
    • JP2012032368
    • 2012-02-17
    • Central Glass Co Ltdセントラル硝子株式会社
    • SATO KEIJIMITSUI TOSHINORIKAMITSURU YUKI
    • C01B25/455H01M10/0568
    • H01M10/0568C01D15/005H01M10/0525
    • PROBLEM TO BE SOLVED: To provide a method for more efficiently producing concentrated lithium hexafluorophosphate solustion with high purity without treating precipitate substances by-produced every synthesizing batch as waste materials.SOLUTION: A method for producing a concentrated lithium hexafluorophosphate solution by carrying out a reaction step (I) of reacting phosphorous trichloride, chlorine and lithium chloride and/or lithium fluoride with one another in a non-aqueous organic solvent, then carrying out a reaction step (II) of reacting a reaction product produced in the solvent in the reaction step (I) with hydrogen fluoride, then removing hydrogen chloride from the reaction solution by a degassing treatment, then filtrating the resultant solution, then degassing the resultant filtrate, and then concentrating the degassed product. The method is characterized in that the filtration was carried out in an inert atmosphere containing substantially no water and a filter cake that has been separated from the filtrate in the filtration and contains lithium fluoride solid content is used as a raw material of the reaction at least one step of the reaction steps (I), (II).
    • 要解决的问题:提供一种更高效地生产高纯度六氟磷酸锂六氟磷酸盐溶液的方法,而不用处理每个合成批次生产的沉淀物质作为废料。溶液:通过进行反应生产浓缩的六氟磷酸锂溶液的方法 在非水有机溶剂中使三氯化磷,氯和氯化锂和/或氟化锂反应的步骤(I),然后进行在反应中使溶剂中产生的反应产物反应的反应步骤(II) 步骤(I),然后通过脱气处理从反应溶液中除去氯化氢,然后过滤所得溶液,然后使所得滤液脱气,然后浓缩脱气产物。 该方法的特征在于,在基本上不含水的惰性气氛中进行过滤,并且在过滤中从滤液中分离出含有氟化锂固体含量的滤饼至少用作反应的原料 反应步骤(I),(II)的一步。
    • 5. 发明专利
    • Electrolyte for electrochemical device, electrolyte solution using this, and nonaqueous electrolyte battery
    • 电解电容器,电解液使用此电解液和非电解电解质电池
    • JP2010257616A
    • 2010-11-11
    • JP2009103515
    • 2009-04-22
    • Central Glass Co Ltdセントラル硝子株式会社
    • TSUJIOKA SHOICHIMITSUI TOSHINORIKONDO YUKIFUJIWARA AIICHIRO
    • H01M10/0568H01G11/06H01G11/54H01G11/62H01G11/64H01M10/052H01M10/0567H01M10/0569
    • H01M10/052H01M10/0567H01M10/0568H01M10/0569Y02E60/122
    • PROBLEM TO BE SOLVED: To find a new electrolyte having properties as an electrolyte for an electrochemical device, and to provide excellent electrolyte solution for a nonaqueous electrolyte battery and a nonaqueous electrolyte battery using this. SOLUTION: The electrolyte for an electrochemical device is expressed in a general formula (1). In the formula (1), M is an element of a thirteenth or fifteenth family of the periodic table, A + is an alkaline metal ion or onium ion, m is a number from 1 to 4 when M is an element of the thirteenth family, and 1 to 6 when M is an element of the fifteenth, n is a number from 0 to 3 when M is an element of the thirteenth, and 0 to 5 when M is an element of the fifteenth. R is a halogen, alkyl halide of C1-10, aryl of C6-20 or aryl halide of C6-20, of whose structures, the hydrogen may have mixed halogen, chained or cyclic alkyl group, aryl group, alkenyl group, alkoxy group, aryloxy group, sulfonyl group, amino group, cyano group, carbonyl group, acyl group, amide group or hydroxyl group, or the carbon may have nitrogen, sulfur and oxygen introduced. R may be of different kinds or the same. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:找到具有作为电化学装置的电解质的性质的新电解质,并且使用这种电解质电池和非水电解质电池提供优异的电解质溶液。 解决方案:用于电化学装置的电解质用通式(1)表示。 在式(1)中,M是周期表第十三或第十五族的元素,A + 是碱金属离子或鎓离子,当M为1时,m为1〜4的数 是第十三族的元素,当M为第十五族的元素时为1〜6,当M为第十三族的元素时,n为0〜3的数,当M为第十五族的元素时,为0〜5 。 R是卤素,C 1-10的烷基卤,C 6-20的芳基或C 6-20的芳基卤,其结构中,氢可以具有卤素,链状或环状的烷基,芳基,链烯基,烷氧基 芳氧基,磺酰基,氨基,氰基,羰基,酰基,酰胺基或羟基,或碳可以含有氮,硫和氧。 R可以是不同的或相同的。 版权所有(C)2011,JPO&INPIT
    • 8. 发明专利
    • Method for processing wastewater containing fluorophosphate compounds
    • 用于处理含有氟磷酸盐化合物的废水的方法
    • JP2013085972A
    • 2013-05-13
    • JP2011225424
    • 2011-10-13
    • Central Glass Co Ltdセントラル硝子株式会社
    • MITSUI TOSHINORIKAWAMOTO HIROMIKAMIYA JUNPEI
    • C02F1/58C02F3/12
    • C02F1/583C02F1/001C02F1/38C02F1/66C02F1/76C02F5/06C02F2101/105C02F2101/14C02F2209/02
    • PROBLEM TO BE SOLVED: To reduce the phosphorus concentration and fluorine concentration in wastewater occurring to a level such that it is possible to discharge into the sea or the like with little dilution, performing the reduction by means of an easy process and with little energy loss, when producing lithium hexafluorophosphate or an electrolyte resulting from dissolving lithium hexafluorophosphate in an organic solvent.SOLUTION: This method for processing wastewater containing fluorophosphate compound is characterized by having: a decomposition step decomposing fluorophosphate compounds by causing the inclusion of hydrogen chloride in the wastewater containing fluorophosphate compounds in a manner so that the concentration of hydrogen chloride becomes 11-25 mass%, and then heating the wastewater to 50°C or higher and lower than 80°C; an immobilizing step of immobilizing phosphorus and fluorine in the wastewater by adding a calcium compound to the wastewater after the decomposition step, causing the pH of the wastewater to be at least 6; and a solid-liquid separation step of obtaining wastewater with reduced concentration of fluorine and phosphorus by eliminating the solid material immobilized in the immobilizing step.
    • 要解决的问题:为了将废水中的磷浓度和氟浓度降低到能够以少量稀释物排放到海中等的水平,通过简单的方法进行还原,并且 当生产六氟磷酸锂或由六氟磷酸锂溶解在有机溶剂中而产生的电解质时,能量损失小。 解决方案:用于处理含氟磷酸盐化合物废水的方法的特征在于:通过使含氟磷酸盐化合物的废水中含有氯化氢以分解氟磷酸盐化合物的方式使氯化氢浓度变为11- 25质量%,然后将废水加热至50℃以上且低于80℃; 通过在分解步骤之后向废水中加入钙化合物将磷和氟固定在废水中的固定步骤,使废水的pH至少为6; 以及通过除去在固定化步骤中固定的固体材料来获得具有降低的氟和磷浓度的废水的固液分离步骤。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Electrolyte for nonaqueous electrolyte battery, and nonaqueous electrolyte battery
    • 非电解电解电池电解质和非电解电解质电池
    • JP2007165125A
    • 2007-06-28
    • JP2005359995
    • 2005-12-14
    • Central Glass Co Ltdセントラル硝子株式会社
    • TSUJIOKA SHOICHIMITSUI TOSHINORITAROURA SATORU
    • H01M10/05H01M10/052H01M10/0567H01M10/0568
    • Y02E60/122Y02T10/7011
    • PROBLEM TO BE SOLVED: To provide an electrolyte for a nonaqueous electrolyte battery for providing excellent durability to the nonaqueous electrolyte battery; and to provide a nonaqueous electrolyte battery using it.
      SOLUTION: This electrolyte for a nonaqueous electrolyte battery comprising a nonaqueous organic solvent and a solute contains: at least one compound selected, as an additive, from a first compound group comprising, bis(oxalate)borate salt, difluoro(oxalate)borate salt, tris(oxalate)phosphoric salt, difluoro(bisoxalate) phosphoric salt, and tetrafluoro(oxalate)phosphoric salt; and at least one compound selected from a second compound group comprising monofluorophosphoric salt and difluorophosphoric salt. This nonaqueous electrolyte battery uses the electrolyte.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种用于非水电解质电池的电解质,以提供对非水电解质电池的优异的耐久性; 并提供使用它的非水电解质电池。 解决方案:包含非水有机溶剂和溶质的非水电解质电池用电解液包含:至少一种化合物,其选自第二化合物组合物作为添加剂,所述第一化合物组包含双(草酸)硼酸盐,二氟(草酸盐) 硼酸盐,三(草酸盐)磷酸盐,二氟(二草酸盐)磷酸盐和四氟(草酸盐)磷酸盐; 和选自包含单氟磷酸盐和二氟磷酸盐的第二化合物基团中的至少一种化合物。 该非水电解质电池使用电解质。 版权所有(C)2007,JPO&INPIT