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    • 1. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5774746A
    • 1982-05-11
    • JP15022580
    • 1980-10-28
    • Canon IncCopyer Co Ltd
    • KATAGIRI KAZUHARUISHIKAWA SHIYOUZOUWATANABE KATSUNORIKITAHARA MAKOTO
    • G03G5/06
    • G03G5/06
    • PURPOSE:To obtain a receptor with high sensitivity and low residual potential by adding a specified disazo compound to a receptor. CONSTITUTION:Disazo pigment represented by formula 1 (where A is an aromatic coupler, each of B1 and B2 is at least one of H, halogen, lower alkyl, OH and lower alkoxy, and B1 and B2 are identical with or different from each other) is dispersed in a charge transferring medium consisting of a charge transferring substance and an insulating binder, and a layer of the dispersion is formed on an electrically conductive layer. A charge generating layer contg. the disazo pigment and a charge transferring layer may be formed on the electrically conductive layer, and the disazo pigment may be added to a charge transfer complex. Thus, a receptor undergoing no reduction in the sensitivity and less increase in the residual charges even after repeated use is obtd.
    • 目的:通过向受体中加入特定的双偶氮化合物,获得具有高灵敏度和低残留潜能的受体。 构成:由式1表示的双偶氮颜料(其中A是芳族成色剂,B1和B2各自为H,卤素,低级烷基,OH和低级烷氧基中的至少一种,B1和B2彼此相同或不同) )分散在由电荷转移物质和绝缘粘合剂组成的电荷转移介质中,并且在导电层上形成分散体层。 电荷产生层 可以在导电层上形成双偶氮颜料和电荷转移层,并且可以将双偶氮颜料加入电荷转移络合物中。 因此,即使在重复使用后,也不会降低灵敏度的降低和残留电荷的增加。
    • 2. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5763540A
    • 1982-04-17
    • JP13871780
    • 1980-10-06
    • Canon IncCopyer Co Ltd
    • KATAGIRI KAZUHARUWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • G03G5/06
    • G03G5/06
    • PURPOSE:To obtain an electrophotographic receptor low in remaining potential and good in sensitivity, by using a specified disazo pigment as a charge generating material. CONSTITUTION:The disazo pigment to be used as a charge generating material has a 2, 5 diphenyl furan ring represented by the formulaIin which A is an aromatic coupler, such as the formula II in which X is a residue condensing with a benzene ring and forming a naphthalene or dibenzofuran ring or the like; Y is -CONR1R2; R1 being H, alkyl, or phenyl; and R2 being alkyl, phenyl, or naphthyl. Said disazo pigment, preferably having
    • 目的:通过使用指定的双偶氮颜料作为电荷产生材料,获得低电位且灵敏度好的电子照相受体。 构成:作为电荷产生材料使用的双偶氮颜料具有式A表示的二苯基呋喃环,其中A为芳香族成色剂,其中X为与苯环缩合的残基并形成 萘或二苯并呋喃环等; Y为-CONR1R2; R1是H,烷基或苯基; 并且R 2是烷基,苯基或萘基。 优选具有<= 5mu直径的所述双偶氮颜料分散在粘合剂溶液中,涂覆在铝板或类似导电层上以形成<=5μm厚的电荷产生层,并且在该层上具有5-30μm厚的电荷转移 形成含有电荷转移物质如吡唑啉的层,从而获得所需的电子照相受体。
    • 3. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5763539A
    • 1982-04-17
    • JP13871580
    • 1980-10-06
    • Canon IncCopyer Co Ltd
    • MABUCHI MINORUSAKAI KIYOSHIWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • C08K5/00C08K5/34C08K5/3412C08L33/00C08L33/02C08L67/00G03G5/06
    • G03G5/06
    • PURPOSE:To obtain an electrophotographic receptor low in remaining potential and good in sensitivity, by using a specified hydrazone compound as a charge transfer material. CONSTITUTION:The compound to be used as a charge transfer material is a hydrazone compound represented by the formula in which R1 is 1-5C alkyl or aralkyl and R2, R3 are each 1-5C alkyl, aralkyl, or aryl, but they are not both alkyl. A charge generating layer containing a charge generating material, such as selenium or disazo pigment is formed on a conductive substrate, such as an aluminum plate, and the above-mentioned hydrazone compound is coated on this layer together with a binder to form a 5-30mu thick charge transfer layer. The desired electrophotographic receptor is thus formed.
    • 目的:通过使用指定的腙化合物作为电荷转移材料,获得低电位且灵敏度好的电子照相受体。 构成:用作电荷转移材料的化合物是由下式表示的腙化合物,其中R 1是1-5C烷基或芳烷基,R 2,R 3各自是1-5C烷基,芳烷基或芳基,但它们不是 两个烷基。 在诸如铝板的导电基材上形成含有电荷产生材料如硒或双偶氮颜料的电荷产生层,并且将上述腙化合物与粘合剂一起涂覆在该层上,形成5- 30μm厚的电荷转移层。 因此形成所需的电子照相受体。
    • 4. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5758157A
    • 1982-04-07
    • JP13296980
    • 1980-09-26
    • Canon IncCopyer Co Ltd
    • SAKAI KIYOSHIMABUCHI MINORUWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • G03G5/05C09B26/02G03G5/06
    • G03G5/06
    • PURPOSE:To obtain a receptor having high sensitivity, low residual potential and superior durability and causing less deterioration in the characteristics even after repeated use by adding a phenothiazine-hydrazone compound as a charge transferring material to photosensitive layer. CONSTITUTION:A hydrazone compound represented by formula 1 (where R1 is lower alkyl, and each of R2 and R3 is optionally substituted alkyl, aralkyl aryl, yet both of them are not alkyl) as a charge transferring material is added to a photosensitive layer. Especially, on an electrically conductive support a charge transferring layer contg. said charge transferring material and a charge generating layer are formed to manufacture a receptor composed of 3 layers. The coated film of the photosensitive layer is easy to form and has high flexibility, and a receptor with high sensitivity, superior durability, etc. is obtd.
    • 目的:为了获得具有高灵敏度,低残留电位和优异耐久性的受体,即使在通过将吩噻嗪 - 腙化合物作为电荷转移材料添加到感光层中而重复使用之后也不会导致特性劣化。 构成:作为电荷转移材料的由式1表示的腙化合物(其中R 1是低级烷基,并且R 2和R 3各自是任选取代的烷基,芳烷基芳基,但它们都不是烷基)。 特别地,在导电支撑件上,电荷转移层 形成电荷转移材料和电荷产生层以制造由3层构成的受体。 感光层的涂膜易于形成并具有高柔性,并且可以看到具有高灵敏度,优异的耐久性等的受体。
    • 5. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5778542A
    • 1982-05-17
    • JP15381480
    • 1980-11-04
    • Canon IncCopyer Co Ltd
    • KATAGIRI KAZUHARUISHIKAWA SHIYOUZOUWATANABE KATSUNORIKITAHARA MAKOTO
    • G03G5/06
    • G03G5/06
    • PURPOSE:To obtain a photoreceptor superior in sensitive by adding a specified novel disazo pigment. CONSTITUTION:A photoreceptor contains a disazo pigment represented by the general formala (1) and A is preferably represented by the general formulae (2), (3), and (4), and it is preferably constituted as follows: (P) A layer formed by dispersing the pigment into a medium composed of a charge transfer substance and an insulating binder is formed on a conductive layer; (Q) a charge generating layer containing the pigment is formed on a conductive layer, and a charge transfer layer, for example a resin layer containing 2,5-bis(p-diethylaminophenyl)-1,3,4-oxadizole is laminated on the charge generating layer; (R) the pigment is dispersed into a charge transfer complex. Especially selection of the (Q) type photoreceptor permits sensitivity to be improved, remaining potential to be lowered, and deterioration of sensitivity in repeated uses to be low.
    • 目的:通过加入特定的新型双偶氮颜料,获得敏感性优异的感光体。 构成:感光体含有由通式(1)表示的双偶氮颜料,A优选由通式(2),(3)和(4)表示,优选构成如下:(P)A 在导电层上形成通过将颜料分散到由电荷转移物质和绝缘粘合剂构成的介质中形成的层; (Q)在导电层上形成含有颜料的电荷产生层,电荷转移层例如含有2,5-双(对二乙基氨基苯基)-1,3,4-恶唑的树脂层层压在 电荷产生层; 颜料分散到电荷转移络合物中。 特别是(Q)型感光体的选择使得灵敏度得到提高,剩余电位降低,反复使用的灵敏度劣化降低。
    • 6. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5763538A
    • 1982-04-17
    • JP13826680
    • 1980-10-04
    • Canon IncCopyer Co Ltd
    • KATAGIRI KAZUHARUWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • C08K5/00C08K5/45C08K5/47C08L67/00G03G5/06
    • G03G5/06
    • PURPOSE:To enhance sensitivity of an electrophotographic receptor and to prevent deterioration of the sensitivity, rise of remaining potential, etc. in repeated uses, by adding a disazo pigment having a benzothiazole ring to the photosensitive layer of the receptor. CONSTITUTION:The desired electrophotographic receptor is prepared by adding to the photosensitive layer of the receptor for use in an electrophotographic copying machine, etc., such as the charge generating layer of the photoreceptor consisting of a conductive layer, this charge generating layer, and a charge transfer layer, a disazo pigment having a benzothiazole ring represented by the formulaIin which A is an aromatic coupler, as a charge generating material. The disazo pigment of the fornulaIcan be produced by tetrazotizing diamine represented by the formula II, and coupling it with the aromatic coupler represented by the formula III or IV or the like in which R3 is optionally substituted alkyl or phenyl, in presence of alkali.
    • 目的:通过在受体的感光层中加入具有苯并噻唑环的双偶氮颜料,提高电子摄影受体的敏感性,防止重复使用时的敏感性降低,剩余电位上升等。 构成:通过向用于电子照相复印机等的受体的感光层中添加所需的电子照相受体,例如由导电层构成的感光体的电荷产生层,该电荷产生层和 电荷转移层,具有由式I表示的苯并噻唑环的双偶氮颜料作为电荷产生材料。 可以通过将由式II表示的二胺进行四唑化,并将其与式III或IV表示的芳族成色剂或其中R 3为任选取代的烷基或苯基的芳族成色剂在碱存在下偶联来制备。
    • 7. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5760338A
    • 1982-04-12
    • JP13524580
    • 1980-09-30
    • Canon IncCopyer Co Ltd
    • SAKAI KIYOSHIMABUCHI MINORUWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • C08K5/00C08K5/34C08K5/3442C08L33/00C08L33/02C08L67/00G03G5/06G03G5/08
    • G03G5/0672G03G5/0631G03G5/067
    • PURPOSE:To improve the sensitivity, durability, etc, of an electrophotographic receptor used for electrophotographic copiers and the like by containing an org. photoconductive material consisting of pyrazoline compounds in the photosensitive layer of said photoreceptor. CONSTITUTION:The pyrazoline compound (e.g.; formula III) expressed by the formula II synthesized by causing the ketone expressed by the formulaI(Y is phenyl, benzyl that may have substituents) to react with the hydrazine expressed by the formula X-NH-NH2 (X is pyridyl, quinolyl that may have substituents such as methyl, methoxyl, and the like). The compound of the formula II is contained as an electric charge transport material in the electric charge transport layer of an electrophotographic receptor constituted of a conductive layer, an electric charge generating layer, an electric charge transfer layer, etc. Thereby, the degradiation in the surface potential and sensitivity in the repetitive use of the photoreceptor is decreased, the rise in residual potential is made negligible and durability is improved.
    • 目的:提高用于电子照相复印机等的电子照相受体的灵敏度,耐久性等。 在所述感光体的感光层中由吡唑啉化合物组成的光电导材料。 构成:通过使由式I表示的酮(Y是苯基,可具有取代基的苄基)与由式X-NH-NH 2表示的肼反应合成的由式II表示的吡唑啉化合物(例如式III) (X为吡啶基,可具有取代基的甲酰基,例如甲基,甲氧基等)。 在由导电层,电荷产生层,电荷转移层等构成的电子照相受体的电荷输送层中含有式II化合物作为电荷输送材料。因此, 在重复使用感光体时的表面电位和灵敏度降低,残留电位的上升被忽略,耐久性提高。
    • 8. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5766438A
    • 1982-04-22
    • JP14250580
    • 1980-10-14
    • Canon IncCopyer Co Ltd
    • KATAGIRI KAZUHARUISHIKAWA SHIYOUZOUWATANABE KATSUNORIKITAHARA MAKOTO
    • C08K5/00C08K5/35C08L67/00G03G5/06
    • G03G5/06
    • PURPOSE:To raise sensitivity of a photoreceptor, to lower its remaining potential, and to render it durable against repeated uses, by using a diazo pigment having an oxazole ring for its photosensitive layer. CONSTITUTION:A diazo pigment represented by the formulaIin which A is an aromatic coupler, and B is at least one selected from H, halogen, lower alkyl, lower alkoy, hydroxy, and acylamino is used. Preferable photoreceptors are embodied as follows: (1) A photoreceptor prepared by forming on a conductive layer a layer containing a pigment dispersed into a charge transfer medium consisting of a charge transfer material and an insulating binder (the binder itself may be a charge transfer material), (2) A photoreceptor consisting of a conductive layer, a charge generating layer containing an organic pigment, and a charge transfer layer, (3) A photoreceptor containing an organic pigment added to a charge transfer complex.
    • 目的:通过使用具有恶唑环的重氮颜料作为其感光层,提高感光体的敏感度,降低其剩余电位,并使其耐反复使用。 构成:使用由式Ⅰ表示的重氮颜料,其中A为芳族成色剂,B为选自H,卤素,低级烷基,低级烷基,羟基和酰氨基中的至少一种。 优选的感光体的实施方式如下:(1)通过在导电层上形成分散在由电荷转移材料和绝缘粘合剂构成的电荷转移介质中的颜料的层而制备的感光体(粘合剂本身可以是电荷转移材料 ),(2)由导电层,含有有机颜料的电荷产生层和电荷转移层组成的感光体,(3)含有添加到电荷转移络合物中的有机颜料的感光体。
    • 9. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5763549A
    • 1982-04-17
    • JP13826480
    • 1980-10-04
    • Canon IncCopyer Co Ltd
    • KATAGIRI KAZUHARUWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • G03G5/06
    • G03G5/06
    • PURPOSE:To obtain an electrophotographic receptor improved in sensitivity and reduced in remaining potential, by forming a photosensitive layer containing a specified disazo pigment on the receptor. CONSTITUTION:A photoreceptor has a photosensitive layer containing a disazo pigment represented by the formulaIin which A is an aromatic coupler; B is methyl or Cl; and D is H, lower alkyl, halogen, OH, lower alkoxy, or acylamino. In the formulaI, A is preferably selected from couplers represented by the formula II, III, and IV in which V is a residue condensing with a benzene ring and forming a naphthalene or anthracene ring, or the like; Y is CONR1 R2, where R1 is H, alkyl, or phenyl, and R2 is alkyl, phenyl, or naphthyl; and R3 is alkyl or phenyl. When the photoreceptor consists of at least 3 layers: a conductive layer, the charge generating layer containing the disazo pigment represented by the formulaI, and a charge transfer layer, deterioration of sensitivity and rise of remaining potential can be suppressed to a negligible degree.
    • 目的:通过在受体上形成含有特定双偶氮颜料的感光层,获得敏感性提高并降低剩余电位的电子照相受体。 构成:感光体具有感光层,其含有由式Ⅰ表示的双偶氮颜料,其中A为芳族偶合剂; B是甲基或Cl; 和D是H,低级烷基,卤素,OH,低级烷氧基或酰氨基。 在式I中,A优选选自由式II,III和IV表示的成色剂,其中V是与苯环缩合并形成萘或蒽环的残基; Y是CONR1R2,其中R1是H,烷基或苯基,R2是烷基,苯基或萘基; 并且R 3是烷基或苯基。 当感光体由至少3层构成时:导电层,含有由式I表示的双偶氮颜料的电荷产生层和电荷转移层,可以将灵敏度的劣化和剩余电位的上升抑制在可忽略的程度。
    • 10. 发明专利
    • Electrophotographic receptor
    • 电子摄影受体
    • JPS5758158A
    • 1982-04-07
    • JP13297080
    • 1980-09-26
    • Canon IncCopyer Co Ltd
    • MABUCHI MINORUSAKAI KIYOSHIWATANABE KATSUNORIISHIKAWA SHIYOUZOUKITAHARA MAKOTO
    • C08K5/00C08K5/35C08L67/00G03G5/06G03G5/08
    • G03G5/0631G03G5/0674
    • PURPOSE:To obtain a receptor having high sensitivity, low residual potential and superior durability and causing less deterioration in the characteristids even after repeated use by adding a specified oxadiazole compound to a photosensitive layer, especiallly to a charge transferring layer. CONSTITUTION:An oxadiazole compound represented by formulaI(where each of R1 and R2 is alkyl, aralkyl or a residue forming a ring together with N, and R1 and R2 are identical with or different from each other) is added to a photosensitive layer. Esoecially, an electrographic receptor composed of 3 layer is manufactured using an electrically conductive layer, a charge transferring layer contg. said compound as a charge transferring material and a charge generating layer. The photosensitive layer is easy to form and has high flexibility, and a receptor with high sensitivity, low residual potential and superior durability is obtd.
    • 目的:为了获得具有高灵敏度,低残留电位和优异的耐久性的受体,即使在通过向感光层中加入特定的恶二唑化合物,特别是电荷转移层而重复使用后,特性也不会发生劣化。 构成:将由式I表示的恶二唑化合物(其中R 1和R 2各自为烷基,芳烷基或与N一起形成环的残基,并且R 1和R 2彼此相同或不同)加入感光层。 特别地,使用导电层,电荷转移层约束制造由3层组成的电摄影受体。 所述化合物作为电荷转移材料和电荷产生层。 感光层容易形成并具有高柔韧性,并且具有高灵敏度,低残留电位和优异的耐久性的受体。