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1. 发明专利

JP2011051899A METHOD OF PRODUCING NORBORNANYL α-SUBSTITUTED ACRYLATE 有权
标题翻译：生产异丁烯醛取代的丙烯酸酯的方法
公开(公告)号：JP2011051899A
公开(公告)日：2011-03-17
申请号：JP2009195145
申请日：2009-08-26
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： MATSUURA MAKOTO , NADANO AKIRA , KOMATA TAKEO
IPC分类号： C07C67/04 , C07B61/00 , C07C69/54
CPC分类号： C07C67/04 , C07C2602/42 , C07C69/653
摘要： PROBLEM TO BE SOLVED: To provide a method of efficiently producing a norbornanyl α-substituted acrylate on an industrial scale while preventing the production of by-products resulting from an intramolecular cyclization reaction, an excessive addition reaction to acrylic acid, or the like.
SOLUTION: The method of producing a norbornanyl α-substituted acrylate includes causing an α-substituted acrylic acid to directly react with a substituted norbornene in the presence of at least one species of acid catalysts selected from methanesulfonic acid and camphorsulfonic acid. An α-substituted norbornanyl acrylate is useful as a resist monomer of a norbornene type. The production of by-products resulting from an intramolecular cyclization reaction, an excessive addition reaction of the acid to the reaction product, or the like, can be prevented.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种在工业规模上有效地制备降冰片烷基α-取代的丙烯酸酯的方法，同时防止由分子内环化反应产生的副产物，对丙烯酸的过量加成反应或喜欢。解决方案：制备降冰片烷基α-取代丙烯酸酯的方法包括使α-取代的丙烯酸在选自甲磺酸和樟脑磺酸的至少一种酸催化剂的存在下与取代的降冰片烯直接反应。 α-取代的降冰片烷基丙烯酸酯可用作降冰片烯型的抗蚀剂单体。可以防止由分子内环化反应产生的副产物，酸对反应产物的过度加成反应等的产生。版权所有（C）2011，JPO＆INPIT

2. 发明专利

JP2008050342A Method for producing n-(bicycro[2,2,1]hept-5-en-2-ylmethyl)-1,1,1-trifluoromethanesulfonamide 有权
标题翻译：生产N-（二氯[2,2,1] HEPT-5-EN-2-甲基乙基）-1,1,1-三氟甲磺酰胺的方法
公开(公告)号：JP2008050342A
公开(公告)日：2008-03-06
申请号：JP2007173216
申请日：2007-06-29
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： MATSUNAGA YOSHI , KOMATA TAKEO
IPC分类号： C07C303/38 , C07C311/12
CPC分类号： C07C303/38 , C07C2602/42 , C07C311/09
摘要： PROBLEM TO BE SOLVED: To provide a method for synthesizing N-(bicycro[2,2,1]hept-5-en-2-ylmethyl)-1,1,1-trifluoromethanesulfonamide, suitable for industrial production. SOLUTION: Trifluoromethanesulfonic acid anhydride is reacted with 1-bicycro[2,2,1]hept-5-en-2-ylmethanamine in the presence of a base and in a mixture solvent of water and an organic solvent to produce N-(bicycro[2,2,1]hept-5-en-2-ylmethyl)-1,1,1-trifluoromethanesulfonamide. The reaction is preferably performed in the presence of an inorganic base, at -10 to 50°C and in the coexistence of 0.2 to 100 g water-insoluble organic solvent per 1 g 1-bicycro[2,2,1]hept-5-en-2-ylmethanamine, Thereby, the objective sulfonamide can be obtained with high purity from a low price material at a high yield. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供适合于工业生产的N-（双环[2,2,1]庚-5-烯-2-基甲基）-1,1,1-三氟甲磺酰胺的合成方法。解决方案：三氟甲磺酸酐与1-双环[2,2,1]庚-5-烯-2-基甲胺在碱和水和有机溶剂的混合溶剂存在下反应，产生N - （bicycro [2,2,1]庚-5-烯-2-基甲基）-1,1,1-三氟甲磺酰胺。该反应优选在无机碱的存在下，在-10至50℃下进行，并且每1g 1g 1,2-双环[2,2,1]庚-5-醇中存在0.2-100g水不溶性有机溶剂烯-2-基甲胺，从而可以从低价格的材料以高产率从高纯度获得目标磺酰胺。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2007091634A METHOD FOR PRODUCING α-SUBSTITUTED NORBORNANYL ACRYLATE 有权
标题翻译：生产α-取代的异丁烯酸丙酯的方法
公开(公告)号：JP2007091634A
公开(公告)日：2007-04-12
申请号：JP2005283111
申请日：2005-09-28
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： KOMATA TAKEO , MATSUURA MAKOTO
IPC分类号： C07C303/40 , C07B61/00 , C07C303/44 , C07C311/04
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an α-substituted norbornanyl acrylate useful as a monomer adaptable to a photoresist for next generation on an industrial scale. SOLUTION: The method for producing an α-substituted acrylic acid norbornanyl ester comprises directly reacting an α-substituted acrylic acid with a substituted norbornene in the presence of trifluoromethanesulfonic acid. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于制造适用于工业规模下一代光刻胶的单体的α-取代的降冰片烷基丙烯酸酯的方法。解决方案：制备α-取代的丙烯酸降冰片烷酯的方法包括在三氟甲磺酸存在下使α-取代的丙烯酸与取代的降冰片烯直接反应。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2007045787A α-SUBSTITUTED ACRYLIC ACID NORBORNANYLS, METHOD FOR PRODUCING THE SAME AND COPOLYMER USING THE SAME 有权
标题翻译： α-取代的丙烯酸诺贝尔斯，其制备方法和使用它的共聚物
公开(公告)号：JP2007045787A
公开(公告)日：2007-02-22
申请号：JP2005234131
申请日：2005-08-12
申请人： Central Glass Co Ltd , Jsr Corp , Jsr株式会社 , セントラル硝子株式会社
发明人： KOMATA TAKEO , MATSUURA MAKOTO , MATSUNAGA YOSHI , KOBAYASHI SATORU , SHIMOKAWA TSUTOMU , KUSUMOTO SHIRO , HARA HIROMICHI , SUGIURA MAKOTO , KAWAKAMI MINEKI
IPC分类号： C07C311/09 , C07C303/40 , C08F20/38
摘要： PROBLEM TO BE SOLVED: To produce/provide objective specific α-substituted acrylic acid norbornanyls from a substituted norbornene by passing through a substituted norbornanyl alcohol in a high selectivity and yield, and a polymer containing the same as a monomer. SOLUTION: This substituted norbornanyl alcohol is expressed by general formula [4] [wherein, any one of R 2 , R 3 is RfSO 2 NHCH 2 - group (wherein, Rf is a 1-4C perfluoroalkyl) and rest is H]. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：通过以高选择性和收率的方式通过取代的降冰片烷醇，以及含有与单体相同的聚合物，从取代的降冰片烯生产/提供目标特异的α-取代的丙烯酸降冰片烷基。
解决方案：该取代的降冰片烷基醇由通式[4]表示[其中，R 2 SP 3，R 3 SP 3中的任一个为R f SO 2，（其中，Rf为1-4C全氟烷基），其余为H]。版权所有（C）2007，JPO＆INPIT

5. 发明专利

JP2006193437A Method for producing 1,1,3,3,3-pentafluoropropene 审中-公开
标题翻译：生产1,1,3,3,3-二氟丙烯的方法
公开(公告)号：JP2006193437A
公开(公告)日：2006-07-27
申请号：JP2005004229
申请日：2005-01-11
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： KOMATA TAKEO , HIROTSU YOSHITERU , HAMANO YUSUKE
IPC分类号： C07C17/25 , C07B61/00 , C07C17/383 , C07C21/18
摘要： PROBLEM TO BE SOLVED: To provide a method for synthesizing 1,1,3,3,3-pentafluoropropene suitable for its production in an industrial scale.
SOLUTION: This method for producing the 1,1,3,3,3-pentafluoropropene comprises bringing 3-chloro-1,1,1,3,3-pentafluoropropane into contact with activated carbon in a gas phase to perform a dehydrochlorination reaction. Thus, the objective 1,1,3,3,3-pentafluoropropene can efficiently be obtained. The dehydrochlorination reaction can ordinarily be performed at a reaction temperature of 200 to 350°C in an activated carbon-contacting time of 1 to 300 seconds, especially preferably at a reaction temperature of 220 to 320°C in an activated carbon-contacting time of 20 to 150 seconds. The reaction approximately selectively proceeds, and the objective compound having a purity of ≥99.5% can be obtained in easy operations in a high yield.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种适合其工业规模生产的1,1,3,3,3-五氟丙烯的方法。解决方案：用于制备1,1,3,3,3-五氟丙烯的方法包括使3-氯-1,1,1,3,3-五氟丙烷与气相中的活性炭接触以进行脱氯化氢反应。因此，可以有效地获得目标1,1,3,3,3-五氟丙烯。脱氯化氢反应通常可以在200-350℃的反应温度下进行，活性炭接触时间为1至300秒，特别优选在220至320℃的反应温度下，在活性炭接触时间 20到150秒。大致选择性地进行反应，可以在高产率的容易操作中获得纯度≥99.5％的目标化合物。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2005232037A Acrylic acid-based ester of 1,1-bis(trifluoromethyl)-1,3-diol and method for producing the same 有权
标题翻译： 1,1-双（三氟甲基）-1,3-二醇的丙烯酸酯及其制备方法
公开(公告)号：JP2005232037A
公开(公告)日：2005-09-02
申请号：JP2004040302
申请日：2004-02-17
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： KOMATA TAKEO , MATSUNAGA YOSHI , HIROTSU YOSHITERU , AKIBA SHINYA
IPC分类号： C07C69/653 , C07C67/14
摘要： PROBLEM TO BE SOLVED: To obtain an acrylic acid-based ester of a 1,1-bis(trifluoromethyl)-1,3-diol being a new fluorine-containing polymerizable monomer and to provide a method for producing the same.
SOLUTION: The acrylic acid-based ester of a 1,1-bis(trifluoromethyl)-1,3-diol being a new fluorine-containing polymerizable monomer has a high fluorine content and a polar group in the same molecule. A polymer comprising the fluorine-containing polymerizable monomer as a constituent element is expected to have a wide application around the field of an advanced material from properties such as water repellency, oil repellency, low water absorption properties, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric, etc., the field of coating by making the best use of transparent behavior especially in each wavelength, an antireflection film by applying low refractive index and visible light transparency, an optical device by applying transparency in a high waveband (optical communication waveband) and the field of an interlayer insulating film by making the best use of low water absorption properties, low dielectric, etc.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：为了获得作为新的含氟可聚合单体的1,1-双（三氟甲基）-1,3-二醇的丙烯酸酯，并提供其制备方法。解决方案：作为新的含氟可聚合单体的1,1-双（三氟甲基）-1,3-二醇的丙烯酸酯具有相同分子中的高氟含量和极性基团。包含含氟可聚合单体作为构成元素的聚合物预期在诸如防水性，拒斥性，低吸水性，耐热性，耐候性，耐腐蚀性等性能的范围内广泛应用于先进材料领域透明度，光敏性，低折射率，低电介质等，通过最好地利用透明行为特别是在每个波长，通过施加低折射率和可见光透明度的抗反射膜，通过应用的光学装置通过最好地利用低吸水性，低电介质等，高波段（光通信波段）的透明度和层间绝缘膜的场。（C）2005，JPO＆NCIPI

7. 发明专利

JP2004161703A Method for producing 2-fluoro-4-(trifluoromethyl) benzonitrile 审中-公开
标题翻译： 2-氟-4-（三氟甲基）苯并噻唑的制备方法
公开(公告)号：JP2004161703A
公开(公告)日：2004-06-10
申请号：JP2002331214
申请日：2002-11-14
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： KOMATA TAKEO , HIROTSU YOSHITERU , FUJIMOTO MASATAKA
IPC分类号： C07C253/00 , C07B61/00 , C07C253/30 , C07C255/50
摘要： PROBLEM TO BE SOLVED: To provide a method for producing 2-fluoro-4-(trifluoromethyl)benzonitrile useful as pharmaceutical/agrochemical intermediate in an industrial scale.
SOLUTION: The method for producing the 2-fluoro-4-(trifluoromethyl)benzonitrile comprises hydrolyzing 2-chloro-4-(trifluoromethyl)benzal chloride to provide 2-chloro-4-(trifluoromethyl)benzaldehyde, reacting the 2-chloro-4-(trifluoromethyl)benzaldehyde with hydroxylamine, dehydrating the reaction product and then fluorinating the dehydrated product with a metal fluoride or fluorinating the 2-chloro-4-(trifluoromethyl)benzaldehyde with the metal fluoride, reacting the fluorinated compound with hydroxylamine and then dehydrating the reaction product.
COPYRIGHT: (C)2004,JPO
摘要翻译：待解决的问题：提供可用作工业规模的药物/农药中间体的2-氟-4-（三氟甲基）苄腈的方法。解决方案：2-氟-4-（三氟甲基）苄腈的制备方法包括水解2-氯-4-（三氟甲基）亚苄基氯，得到2-氯-4-（三氟甲基）苯甲醛，使2- （三氟甲基）苯甲醛与羟胺脱水，然后使金属氟化物氟化脱水产物，或用金属氟化物氟化2-氯-4-（三氟甲基）苯甲醛，氟化化合物与羟胺反应，和然后使反应产物脱水。版权所有（C）2004，JPO

8. 发明专利

JP2003055289A Method for producing 1,3-difluoroacetone 审中-公开
标题翻译： 1,3-二氟乙酸生产方法
公开(公告)号：JP2003055289A
公开(公告)日：2003-02-26
申请号：JP2001244221
申请日：2001-08-10
申请人： Central Glass Co Ltd , セントラル硝子株式会社
发明人： KOMATA TAKEO , IMURA HIDEAKI , HIROTSU YOSHITERU
IPC分类号： C07C45/29 , C07C45/82 , C07C49/167
摘要： PROBLEM TO BE SOLVED: To produce highly pure 1,3-difluoroacetone reagent useful as an intermediate for medicines, agrochemicals and the like in a high yield.
SOLUTION: 1,3-Difluoro-2-propanol is oxidized with an oxidizing agent such as sodium dichromate in an aqueous solution to obtain the crude product containing the 1,3-difluoroacetone. The crude product is distilled under a reduced pressure of 3,000 to 70,000 Pa. The obtained distillation fraction is dried with a drying agent and again distilled to distil out the 1,3-difluoroacetone.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：以高产率制备用作药物，农药等的中间体的高纯度1,3-二氟丙酮试剂。解决方案：1,3-二氟-2-丙醇用氧化剂如重铬酸钠在水溶液中氧化，得到含有1,3-二氟丙酮的粗产物。将粗产物在3,000〜7000Pa的减压下蒸馏，将得到的蒸馏馏分用干燥剂干燥，再蒸馏除去1,3-二氟丙酮。

9. 发明专利

JP2001261594A METHOD FOR PRODUCING 1-CHLOROHEPTAFLUOROCYCLOPENTENE 失效
公开(公告)号：JP2001261594A
公开(公告)日：2001-09-26
申请号：JP2000076839
申请日：2000-03-17
申请人： NIPPON ZEON CO , CENTRAL GLASS CO LTD
发明人： IMURA HIDEAKI , TAKADA NAOKADO , KOMATA TAKEO
IPC分类号： B01J23/42 , B01J23/50 , B01J23/60 , B01J23/62 , B01J23/644 , B01J23/652 , B01J23/89 , C07B61/00 , C07C17/23 , C07C17/25 , C07C23/08
摘要： PROBLEM TO BE SOLVED: To provide an industrially suitable method for producing 1- chloroheptafluorocyclopentene in high selectivity. SOLUTION: The objective compound is produced by reducing 1,1- dichlorooctafluorocyclopentane with hydrogen in the presence of a catalyst composed of a group VIII metal of the periodic table.

10. 发明专利

JP2000226345A PRODUCTION OF PERHALOGENATED CYCLOPENTENE 失效
公开(公告)号：JP2000226345A
公开(公告)日：2000-08-15
申请号：JP30146699
申请日：1999-10-22
申请人： NIPPON ZEON CO , CENTRAL GLASS CO LTD
发明人： KOMATA TAKEO , IMURA HIDEAKI
IPC分类号： B01J23/18 , C07B61/00 , C07C17/04 , C07C17/21 , C07C23/08
摘要： PROBLEM TO BE SOLVED: To obtain a perhalogenated cyclopentene by a method capable of reducing load to an apparatus and suitable for industrial production in fewer steps by reacting perchlorocyclopentadiene with chlorine and hydrogen fluoride in the presence of a specific catalyst in a gaseous phase. SOLUTION: (A) Perchlorocyclopentadiene is reacted with (B) chlorine and (C) hydrogen fluoride in a gaseous phase in the presence of (D) a fluorinating catalyst which is an activated carbon on which a metal compound is supported or not supported to provide the objective compound of the formula C5ClAF8-A (A is 0-7). A catalyst in which a metal selected from 4 group to 7 group, 9 group to 11 group, 14 group and 15 group is supported on the activated carbon, or the like, is preferably used as the component D. The metal includes molybdenum, niobium, tantalum or antimony. An activated carbon having >=400 m2/g surface area and >=0.1 cm3/g pore volume is preferable as the activated carbon.

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