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    • 3. 发明专利
    • toner
    • JP5419217B2
    • 2014-02-19
    • JP2009248037
    • 2009-10-28
    • 花王株式会社
    • 幸嗣 亀山栄田  朗宏英治 白井
    • G03G9/087G03G9/08
    • PROBLEM TO BE SOLVED: To provide a toner having excellent low temperature fixability, reducing fogging or scumming, and having excellent solid-image following capability and halftone image density. SOLUTION: The toner comprises toner base particles containing a binder resin, and an external additive. The binder resin comprises a crystalline resin and an amorphous resin. The crystalline resin comprises a composite resin containing a styrene resin component and a condensation polymerization resin component which is obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms and a carboxylic acid component containing an aromatic dicarboxylic acid compound. The weight ratio of the condensation polymerization resin component to the styrene resin component (condensation polymerization resin component/styrene resin component) in the composite resin ranges from 50/50 to 95/5, the external additive comprises melamine resin fine particles and resin fine particles obtained by polymerizing a radical polymerizable monomer, and the total content of the melamine resin fine particles and the resin fine particles obtained by polymerizing the radical polymerizable monomer ranges from 0.03 to 1.0 parts by weight with respect to 100 parts by weight of the toner base particles. COPYRIGHT: (C)2011,JPO&INPIT
    • 4. 发明专利
    • toner
    • JP5419216B2
    • 2014-02-19
    • JP2009248036
    • 2009-10-28
    • 花王株式会社
    • 幸嗣 亀山栄田  朗宏英治 白井
    • G03G9/087G03G9/08
    • PROBLEM TO BE SOLVED: To provide a toner having excellent low temperature fixability, reducing fogging or scumming, and having excellent solid-image following capability and halftone image density. SOLUTION: The toner comprises toner base particles containing a binder resin, and an external additive. The binder resin comprises a crystalline resin and an amorphous resin. The crystalline resin comprises a composite resin containing a styrene resin component and a condensation polymerization resin component which is obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms and a carboxylic acid component containing an aromatic dicarboxylic acid compound. The weight ratio of the condensation polymerization resin component to the styrene resin component (condensation polymerization resin component/styrene resin component) in the composite resin ranges from 50/50 to 95/5. The external additive comprises resin fine particles obtained by polymerizing a radical polymerizable monomer, the glass transition point of the resin fine particles is 80 to 150°C and the average particle diameter of the resin fine particle is 0.1 to 0.8 μm, and the content of the resin fine particles ranges from 0.03 to 1.0 part by weight with respect to 100 parts by weight of the toner base particles. COPYRIGHT: (C)2011,JPO&INPIT
    • 7. 发明专利
    • Toner for electrophotography
    • JP5273719B2
    • 2013-08-28
    • JP2008328549
    • 2008-12-24
    • 花王株式会社
    • 英治 白井憲廣 福利
    • G03G9/087
    • PROBLEM TO BE SOLVED: To provide toner for electrophotography having an excellent pressurization storage property while satisfying excellent low-temperature fixability, crystalline polyester composition used in the toner, binder resin containing the crystalline polyester composition, and a manufacturing method for the binder resin. SOLUTION: This crystalline polyester composition for toner is formed by mixing at least two kinds of crystalline polyester: crystalline polyester A whose storage modulus of elasticity is 120-100,000 Pa at 160 °C; and crystalline polyester B whose storage modulus of elasticity is 0.01-500 Pa at 160 °C. The storage modulus of elasticity of the crystalline polyester A is larger than that of the crystalline polyester B, and a difference in storage modulus of elasticity between the crystalline polyester A and the crystalline polyester B is 100 Pa or more. This binder resin contains the above crystalline polyester composition. The invention provides a manufacturing method for the same, and provides toner for electrophotography containing the above binder resin. COPYRIGHT: (C)2010,JPO&INPIT