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    • 89. 发明专利
    • BRANCHED POLYCARBONATE
    • JPH04268328A
    • 1992-09-24
    • JP4859791
    • 1991-02-22
    • IDEMITSU PETROCHEMICAL CO
    • KUZE SHIGEKIKOMATSU TAKASHI
    • C08G64/00C08G64/10C08G64/14
    • PURPOSE:To obtain a branched polycarbonate improved in flame retardancy, mechanical properties and melt properties (blow moldability) by specifying the branched structure, the repeating units and the viscosity-average molecular weight. CONSTITUTION:A mixture of a branching agent (a) of formula I (wherein R is H or 1-5C alkyl; and R to R are each R or halogen) with an alkaline aqueous solution (b) of (tetrahalo)bisphenol A and an alkaline aqueous solution (c) of bisphenol A in a solution in the presence of a catalyst is reacted with phosgene (d) to obtain a polycarbonate oligomer solution. This solution is mixed with the bisphenol A, the solvent, component (b) and the catalyst and reacted to obtain a branched polycarbonate having 0.1-2.0mol% branched structure derived from component (a) and repeating units of formulas II and III (wherein X and X are each halogen), terminated with a trihalogenoxy group of formula IV (wherein X to X are each X ), and having a viscosity-average molecular weight of 10000-50000 and a content of units of formula III of 10mol%.