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81. 发明专利

JP5373410B2 Ammonia synthesis method 有权
公开(公告)号：JP5373410B2
公开(公告)日：2013-12-18
申请号：JP2009003851
申请日：2009-01-09
申请人：トヨタ自動車株式会社 , 日立造船株式会社
发明人：治通中西 , 徳彦中村 , 英一有川 , 進日数谷 , 近稲住
IPC分类号： C01C1/04 , B01J35/02
CPC分类号： C01B3/042 , B01J35/004 , C01B3/025 , C01B3/061 , C01B3/063 , C01B3/501 , C01B3/56 , C01B5/00 , C01B13/0207 , C01B13/0251 , C01B13/0281 , C01B2203/042 , C01B2203/068 , C01B2210/0053 , C01C1/0405 , Y02E60/364 , Y02P20/134 , Y02P20/52
摘要： The invention provides a process for efficient synthesis of ammonia. The process of the invention for synthesis of ammonia comprises (a) a water-splitting step (101) in which water is decomposed to obtain a first source gas comprising hydrogen and oxygen, (b) a first oxygen removal step (102) in which the oxygen contained in the first source gas is at least partially separated and removed by an oxygen separating membrane or hydrogen separating membrane to obtain a second source gas having a lower oxygen concentration than the first source gas, (c) a second oxygen removal step (103) in which the oxygen in the second source gas is reacted with hydrogen to produce water for removal, or is adsorbed onto an adsorption medium for removal, to obtain a third source gas having a lower oxygen concentration than the second source gas, and (d) an ammonia synthesis step (104) in which the hydrogen in the third source gas is reacted with nitrogen to synthesize ammonia.

82. 发明专利

JP5344489B2 Visible-light-responsive three-dimensional fine cell structure photocatalytic filter and a method for manufacturing the same, and purification equipment 有权
公开(公告)号：JP5344489B2
公开(公告)日：2013-11-20
申请号：JP2010192924
申请日：2010-08-30
申请人：独立行政法人産業技術総合研究所
发明人：英治谷 , 邦夫木村
IPC分类号： B01J35/02 , B01D53/86 , B01D53/88 , B01J21/06 , B01J27/224 , B01J35/00 , B01J35/04 , B01J37/02 , B01J37/08 , C02F1/30 , C02F1/72 , C04B41/50 , C04B41/87
CPC分类号： C04B41/009 , B01D53/8628 , B01D53/885 , B01D2255/802 , B01J35/004 , C02F1/001 , C02F1/30 , C02F1/725 , C02F2305/10 , C04B41/5041 , C04B41/87 , C04B2111/00827 , C04B35/565 , C04B35/584 , C04B35/52 , C04B38/00
摘要： A visible-light-responsive three-dimensional fine cell-structured photocatalytic filter in accordance with the present invention includes a sponge-like porous structure (B) containing an anatase-type titanium oxide coating formed on a surface of a sponge-like porous structural body (A) which has a porosity of 85 vol% or more. The sponge-like porous structural body (A) is composed of one material selected from the group consisting of one metal selected from the group consisting of (a) to (e): (a) carbon and either or both of silicon and a silicon alloy; (b) silicon carbide and at least one material selected from the group consisting of silicon, a silicon alloy, and carbon; (c) silicon nitride and at least one material selected from the group consisting of silicon, a silicon alloy, carbon, and silicon carbide; (d) carbon; and (e) carbon and one metal selected from the group consisting of titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, ruthenium, rhodium, palladium, silver, platinum, and gold.

83. 发明专利

JP5342555B2 How to quickly prepare the titania or precursor thereof of easy to control microporous-mesoporous structure 有权
公开(公告)号：JP5342555B2
公开(公告)日：2013-11-13
申请号：JP2010519322
申请日：2007-08-07
申请人：南京工▲業▼大学Nanjing University Of Technology , 南京▲たい▼威科技有限公司Nanjing Taiwei Technology Co.,Ltd.
发明人： ▲陸▼小▲華▼ , 周▲亞▼新 , ▲劉▼▲暢▼ , ▲馮▼新 , ▲楊▼祝▲紅▼ , 王昌松
IPC分类号： C01G23/053
CPC分类号： C01G23/047 , B01J21/063 , B01J35/004 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1057 , B01J35/1061 , B01J37/06 , B01J37/10 , C01G23/005 , C01G23/053 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要： A method for quick preparing titanium oxide or precursor thereof with a controllable structure from micropore to mesopore is provided. The method is characterized in that the alkali metal titanate as raw material is reacted for 0.5 ~ 72 hours in the wet atmosphere with humidity oaf 2 ~ 100 % at temperature of 20 ~ 250 °C, then washed with water or acid, finally calcined in air atmosphere or heat-treated in solvent. The method has advantages that the raw material is easy to be obtained, the conditions and preparation are controllable, the pore structure may be adjusted from micropore to mesopore, crystal mixing and doping are easy, reacting time is short, preparing cost is low, and the said method is suitable for large scale production and so on. The most probable aperture of titanium oxide or precursor thereof with a controllable structure from micropore to mesopore is in the range of 1~20 nm, the pore volume thereof is in the range of 0.05 ~ 0.4 cm 3 /g, and the specific surface area thereof is more than 30 m 2 /g.

84. 发明专利

JPWO2012026194A1 金属酸化物ナノ粒子構造体およびその製造方法审中-公开
公开(公告)号：JPWO2012026194A1
公开(公告)日：2013-10-28
申请号：JP2012530569
申请日：2011-06-21
申请人：国立大学法人徳島大学
发明人：幸壱朗林 , 幸壱朗林
IPC分类号： C01B13/36 , A61K41/00 , A61K49/00 , B01J35/02 , B01J37/03 , C01F17/00 , C01G3/02 , C01G9/02 , C01G23/053 , C01G49/08 , C01G51/04 , C01G53/04
CPC分类号： C01G49/08 , B01J21/063 , B01J23/06 , B01J23/10 , B01J23/72 , B01J23/745 , B01J23/75 , B01J23/755 , B01J35/002 , B01J35/004 , B01J35/1019 , B01J37/03 , C01B13/36 , C01F17/0043 , C01G3/02 , C01G9/02 , C01G23/053 , C01G51/04 , C01G53/04 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2006/12 , C01P2006/42 , C12P3/00 , C12Y305/01005
摘要：【課題】生体模倣プロセスを用いて金属酸化物の二次元または三次元構造体を提供すること。【解決手段】本発明は、ウレアーゼとしてジャックビーンズ由来のタチナタマメウレアーゼ(JBU)を用い、そのテンプレート効果により、尿素を分解させ、金属酸化物のナノ粒子からなる二次元または三次元構造物を製造する。本発明によれば、鉄系酸化物はシート状に形成されて超常磁性を示し、花型階層構造体は好ましい強磁性を示し、MRI造影剤として有用性を示す。チタン系酸化物は37℃という低温で、高い光触媒活性を示すルチル型チタン酸化物が形成される。【選択図】図20

85. 发明专利

JP2013198826A Use of composite material equipped with photocatalyst layer 审中-公开
标题翻译：使用配有光催化层的复合材料
公开(公告)号：JP2013198826A
公开(公告)日：2013-10-03
申请号：JP2010165880
申请日：2010-07-23
申请人： Toto Ltd , Toto株式会社
发明人： HAYAKAWA MAKOTO , TERASAKI HIROSHI , KAMESHIMA JUNJI , FUJII HIROYUKI , HYOFU KOJI , KITAZAKI SATOSHI , SUGANO MITSUMASA
IPC分类号： B01J35/02 , B01J31/38
CPC分类号： B01J37/0215 , B01J21/063 , B01J35/004 , B01J35/023 , C03C17/007 , C03C2217/212 , C03C2217/23 , C03C2217/477 , C03C2217/71 , C09D5/1618
摘要： PROBLEM TO BE SOLVED: To provide a use of a composite material which has a transparent photocatalyst layer having utilizable substrate design and exerts the function of photocatalytic decomposition while effectively inhibiting over a long period the appearance change caused by silicone fouling.SOLUTION: There is provided a use of a composite material comprising a photocatalyst layer for generating the photocatalytic decomposition of substances in the outdoor causing silicone fouling. The photocatalyst layer comprises photocatalyst particles and inorganic oxide particles, and the total mass of those two particles is 80-100 mass% based on 100 mass% of the whole photocatalyst layer. The particle components of the photocatalyst layer have less than 90 nm of a number-average particle size which is calculated through measurements of the lengths of any 100 particles present in a field of view obtained with a scanning electron microscope and having a magnification of 200,000. The photocatalyst layer is transparent and has a film thickness of 3 μm or less. The photocatalyst is photoexcited by sunlight to decompose the substances, and silicone fouling on the surface of the photocatalyst layer is reduced or prevented.
摘要翻译：要解决的问题：为了提供具有可利用的基板设计的透明光催化剂层的复合材料的使用，并且发挥光催化分解的功能，同时有效地长时间地抑制由硅酮污垢引起的外观变化。解决方案：提供使用包含光催化剂层的复合材料来产生室外的物质的光催化分解引起有机硅污垢。光催化剂层包含光催化剂颗粒和无机氧化物颗粒，并且基于整个光催化剂层的100质量％，这两个颗粒的总质量为80-100质量％。光催化剂层的粒子成分的数均粒径小于90nm，通过使用扫描型电子显微镜获得的放大率为20万，通过测定存在于视场内的任何100个粒子的长度而计算出的数均粒径。光催化剂层是透明的，膜厚度为3μm以下。光催化剂被太阳光照射以分解物质，并且光催化剂层表面上的硅氧烷结垢减少或防止。

86. 发明专利

JP5306181B2 The method of manufacturing the tungsten trioxide powder for a photocatalyst, a photocatalyst for tungsten trioxide powder and the photocatalytic products 有权
公开(公告)号：JP5306181B2
公开(公告)日：2013-10-02
申请号：JP2009506277
申请日：2008-03-11
申请人：株式会社東芝 , 東芝マテリアル株式会社
发明人：光佐藤 , 佳代中野 , 康博白川
IPC分类号： B01J35/02 , B01J23/30 , B01J35/10 , B01J37/34 , C01G41/02
CPC分类号： C01G41/02 , B01J23/30 , B01J35/002 , B01J35/004 , B01J35/006 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J37/0238 , B01J37/349 , B82Y30/00 , C01P2004/51 , C01P2004/64 , C01P2006/12 , Y10T428/2982
摘要： A method for producing a tungsten trioxide powder for a photocatalyst according to the present invention is characterized by comprising a sublimation step for obtaining a tungsten trioxide powder by subliming a tungsten metal powder or a tungsten compound powder by using inductively coupled plasma process in an oxygen atmosphere, and a heat treatment step for heat-treating the tungsten trioxide powder obtained in the sublimation step at 300° C. to 1000° C. for 10 minutes to 2 hours in an oxidizing atmosphere. A tungsten trioxide powder which is obtained by the method for producing a tungsten trioxide powder for a photocatalyst according to the present invention has excellent photocatalytic performance under visible light.

87. 发明专利

JP2013532228A Solar fuel cell 有权
公开(公告)号：JP2013532228A
公开(公告)日：2013-08-15
申请号：JP2013511179
申请日：2011-04-29
申请人：本田技研工業株式会社
发明人：ヒー、チング
IPC分类号： C25B9/00 , C25B3/00
CPC分类号： C25B1/003 , B01J19/127 , B01J19/2475 , B01J23/38 , B01J35/004 , B01J35/065 , B01J2219/0884 , B01J2219/0892 , Y02P20/135
摘要：本発明は、光吸収部材上で太陽光を吸収し、光電気化学的に水を酸化して、その水の酸化反応による生成物を触媒上で二酸化炭素のような炭素含有化合物と反応させて、所望の炭化水素化合物を生成させる反応によって、水と炭素含有化合物とから炭化水素を合成する方法にかかるものである。
【選択図】図１

89. 发明专利

JPWO2011118781A1 光触媒塗装体有权
公开(公告)号：JPWO2011118781A1
公开(公告)日：2013-07-04
申请号：JP2012507092
申请日：2011-03-25
申请人： Toto株式会社 , Toto株式会社
发明人：信早川 , 信早川 , 大久保　康次 , 康次大久保 , 中野　浩 , 浩中野 , 理浦 , 理浦 , 剛史山元 , 剛史山元 , 新美　泰志 , 泰志新美
IPC分类号： B32B7/04 , B01J35/02 , B01J37/02 , B05D5/00 , C09D7/12 , C09D201/00 , C09D201/10
CPC分类号： B01J35/004 , B01J21/063 , B01J37/0219 , B01J37/0244
摘要：光触媒層に含まれる光触媒量を低減しつつ、かつ光触媒分解機能に優れる光触媒塗装体が開示されている。この光触媒塗装体は、基材と、光触媒粒子を含んでなる光触媒層と、前記基材および前記光触媒層との間にあり前記光触媒層の下方に接するように設けられた中間層とを少なくとも備えてなる光触媒塗装体であって、前記中間層が、樹脂ビーズ、中空ガラスビーズ、および中空セラミックスビーズからなる群から選ばれる少なくとも一種のビーズと、シリコーン変性樹脂とを少なくとも含んでなり、該ビーズが前記中間層と前記光触媒層との界面にその形状に起因する凸部を形成してなることを特徴とするものである。

90. 发明专利

JP2013129559A Mixed valence copper compound-loaded tungsten oxide and method for producing same 有权
标题翻译：混合有机铜化合物负载氧化钨及其生产方法
公开(公告)号：JP2013129559A
公开(公告)日：2013-07-04
申请号：JP2011279745
申请日：2011-12-21
申请人： Showa Denko Kk , 昭和電工株式会社
发明人： HOSOKI YASUHIRO , KURODA YASUSHI
IPC分类号： C01G3/04 , A61K8/19 , A61K33/24 , A61K33/34 , A61P31/04 , A61P31/12 , A61Q15/00 , B01J27/132 , B01J35/02 , B01J37/02
CPC分类号： A61K33/24 , A61K33/34 , B01J27/132 , B01J35/0013 , B01J35/002 , B01J35/004 , B01J37/031
摘要： PROBLEM TO BE SOLVED: To provide a mixed valence copper compound-loaded tungsten oxide, and a method for producing the same.SOLUTION: A mixed valence copper compound-loaded tungsten oxide is composed of tungsten oxide that supports mixed valence copper iodide of monovalence and divalence. A method for producing the mixed valence copper compound-loaded tungsten oxide includes a step wherein tungsten oxide is suspended in a solution, in which copper ions are dissolved, and iodine ions are added thereto.
摘要翻译：要解决的问题：提供一种混合价铜化合物负载的钨氧化物及其制备方法。解决方案：一种混合价铜化合物负载的氧化钨由支持单价的混合价态碘化铜的氧化钨组成，二价制备混合化合价铜化合物的氧化钨的方法包括将氧化钨悬浮于其中溶解有铜离子的溶液中并加入碘离子的步骤。

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