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    • 81. 发明专利
    • THERMOPLASTIC POLYURETHANE COMPOSITION
    • JPH11256028A
    • 1999-09-21
    • JP5791798
    • 1998-03-10
    • KURARAY CO
    • SAITO HIDEKAZUYOKOTA SHINICHI
    • C08L75/04C08L23/08
    • PROBLEM TO BE SOLVED: To provide a thermoplastic polyurethane composition which can give in high productivity a molding such as a film or a sheet having not only suitable strength and small residual strain after elongation but also excellent adhesion to various substrates and to provide a molding made therefrom. SOLUTION: There is provided a thermoplastic polyurethane resin composition comprising a thermoplastic polyurethane (a) comprising units of an polymer polyol having 2.01-2.10 hydroxyl groups per molecule and having a number- average molecular weight of 500-8,000, units of an organic diisocyanate, and units of a chain extender and having a nitrogen content of 2.5 wt.% or below, a thermoplastic polyurethane (b) comprising units of a polyester diol having a number-average molecular weight of 1,500-5,000, units of an organic diisocyanate, and units of a chain extender, having a nitrogen content of 2.6 wt.% or above, showing an endothermic peak at 200-220 deg.C as measured by differential scanning calorimetry, and having a crystallization enthalpy of 2-15 J/g as determined from the endothermic peak, and an ethylene/α-olefin copolymer (c) and containing 40-80 wt.% component (a), 60-20 wt.% component (b), and 5-250 wt.% component (c) [each amount is based on the total weight of components (a) and (b)].
    • 86. 发明专利
    • PRODUCTION OF POLYAMIDE
    • JPH07228693A
    • 1995-08-29
    • JP2056494
    • 1994-02-17
    • KURARAY CO
    • OKA HIDEAKIKASHIWAMURA TSUGIFUMIYOKOTA SHINICHIHAYASHIBARA HIROSHI
    • C08G69/28C08G69/26
    • PURPOSE:To obtain a polyamide having excellent various performances such as mechanical performance, heat resistance, low water absorption properties, chemical resistance, etc. CONSTITUTION:In producing a crystalline polyamide comprising a dicarboxylic acid component composed of 60-100mol% of terephthalic acid in the dicarboxylic acid component and a diamine component constituted of 60-100mol% of a 6-18C aliphatic diamine component in the diamine component as a first stage, a low- molecular condensate [A] is synthesized as a second stage, the low-molecular condensate is heated in a solid phase state and subjected to polycondensation to give a prepolymer [B] and, as a third stage, the prepolymer [B] is further highly polymerized by a melt extruder to provide a method for producing a polyamide [C]. The heating temperature [T1] in the solid phase state at the second stage is in a temperature range between the melting point of the low- molecular [A] and a temperature 150 deg.C lower than this melting point and the heating temperature [T2] by the melt extruder at the third stage is a temperature range between the melting point of the prepolymer [B] and a temperature 150 deg.C higher than that melting point, in the objective methat.