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    • 81. 发明专利
    • (co)polymer for resist and resist composition
    • (CO)聚合物用于耐腐蚀和耐腐蚀组合物
    • JP2014001386A
    • 2014-01-09
    • JP2013142449
    • 2013-07-08
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • MOMOSE HIKARUWAKABAYASHI SHIGEO
    • C08F20/10C08F2/38C08F4/04C08F4/32G03F7/039
    • PROBLEM TO BE SOLVED: To provide a (co)polymer for a resist giving high sensitivity and/or resolution when used in DUV excimer laser lithography, electron beam lithography or the like.SOLUTION: The (co)polymer for a resist contains at least one kind of monomer unit selected from a monomer unit having an alicyclic skeleton and a monomer unit having a lactone skeleton, and does not contain a molecular terminal group expressed by formula (1) at a molecular terminal. In the formula, Rand Reach represent H, an alkyl group having 1 to 10 carbon atoms, -COO-R, -X-COO-R, -CONR-R, -X-CONR-R, -NR-Ror -X-NR-R; Rrepresents a cyano group or a cyanoalkyl group having 2 to 10 carbon atoms; X represents an alkylene group having 1 to 10 carbon atoms; and Rand Reach represent H or an alkyl group having 1 to 10 carbon atoms.
    • 要解决的问题:当用于DUV准分子激光光刻,电子束光刻等时,提供用于抗蚀剂的(共)​​聚合物,其具有高灵敏度和/或分辨率。解决方案:抗蚀剂的(共)​​聚合物至少包含 选自具有脂环骨架的单体单元和具有内酯骨架的单体单元的一种单体单元,并且在分子末端不含有由式(1)表示的分子末端基团。 在该式中,Rand Reach代表H,具有1-10个碳原子的烷基,-COO-R,-X-COO-R,-CONR-R,-X-CONR-R,-NR-ROR- NR-R; R表示氰基或具有2〜10个碳原子的氰基烷基; X表示碳原子数1〜10的亚烷基。 和Rand Reach代表H或具有1-10个碳原子的烷基。
    • 84. 发明专利
    • Method for producing syrup
    • 生产SYRUP的方法
    • JP2013256619A
    • 2013-12-26
    • JP2012134580
    • 2012-06-14
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HIRANO AKIKOOKUBO TAKASHIHIRANO TAKAYUKI
    • C08F2/38C08F20/00
    • PROBLEM TO BE SOLVED: To provide a method for producing syrup excellent in colorless transparency and suppressed of cost.SOLUTION: There is disclosed a production method of syrup by polymerizing a vinyl monomer using a thermally degradable radical polymerization initiator including a process, where primary mercaptan containing only one SH group and containing no -OH group nor -COOH group in the molecule is added in a vinyl monomer after adding the radical polymerization initiator to the vinyl monomer in an amount Y (part mass) of 0.008 pt.mass or more and satisfying a formula: Y≤-1.7I+0.13 (wherein, I represents a part mass of the radical polymerization initiator remaining at the time of adding the primary mercaptan). However, each the part mass represents a part mass based on 100 pts.mass of the vinyl monomer before polymerization.
    • 要解决的问题:提供一种制备无色透明性优异且抑制成本低的糖浆的制备方法。解决方案:公开了一种使用可热降解的自由基聚合引发剂聚合乙烯基单体的糖浆的制备方法,其包括其中将伯硫醇 在乙烯基单体中加入Y(部分质量)为0.008pt.mass以上的乙烯基单体后,在乙烯基单体中仅含有一个SH基团,在分子中不含-OH基团和-COOH基团, 满足公式:Y≤-1.7I + 0.13(其中,I表示在添加伯硫醇时保留的自由基聚合引发剂的一部分质量)。 然而,每个部件质量是指聚合前基于100个聚乙烯基单体的部分质量。
    • 85. 发明专利
    • Membrane filtration unit
    • 膜过滤装置
    • JP2013255919A
    • 2013-12-26
    • JP2013168674
    • 2013-08-14
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • NAKAHARA SADAHITOTORII TETSUYAOKAZAKI HIROYUKI
    • C02F1/44B01D63/04C02F3/34
    • PROBLEM TO BE SOLVED: To provide a membrane filtration unit capable of securing the durability of a hollow fiber membrane module by preventing the mutual entanglement or hooking of hair, fibers, paper pieces or the like between a hollow fiber membrane and a peripheral frame material or the like in activated sludge treatment.SOLUTION: A membrane filtration unit 5 includes a hollow fiber membrane module 9 constituted by parallelly arranging a plurality of sheet-like hollow fiber membrane elements 10 obtained by arranging porous hollow fiber membranes 10a in parallel at predetermined intervals and an air diffuser 15 arranged under the hollow fiber membrane module to discharge fine air bubbles toward the lower end of the hollow fiber membrane module to thereby produce gas-liquid mixed streams and has a first gap region wherein the gaps between the porous hollow fiber membranes vertically arranged in parallel to constitute the hollow fiber membrane element is fine and a second gap region disposed between the first gap regions and having gaps wider than the fine gaps between the hollow fiber membrane elements. The gaps between a plurality of the hollow fiber membrane elements adjacent in the parallelly arranged direction of the hollow fiber membrane module are partially widely formed.
    • 要解决的问题:提供一种膜过滤单元,其能够通过防止中空纤维膜和周边框架材料之间的毛发,纤维,纸片等的相互缠结或钩住来确保中空纤维膜组件的耐久性,或者 活性污泥处理中的类似物。解决方案:膜过滤单元5包括中空纤维膜组件9,其通过平行布置多个片状中空纤维膜元件10,该多个片状中空纤维膜元件10通过以预定间隔平行布置多孔中空纤维膜10a而获得, 布置在中空纤维膜组件下方的空气扩散器15,以向中空纤维膜组件的下端排出细小气泡,从而产生气液混合流,并具有第一间隙区域,其中多孔中空纤维膜之间的间隙垂直 平行排列构成中空纤维膜元件是细的,第二间隙区域di 在第一间隙区域之间并且具有比中空纤维膜元件之间的细小间隙更宽的间隙。 在中空纤维膜组件的平行布置方向上相邻的多个中空纤维膜元件之间的间隙部分地广泛地形成。
    • 86. 发明专利
    • Production method for optically active amino acid and n-alkoxycarbonylamino acid
    • 光活性氨基酸和N-烷氧羰基氨基酸的生产方法
    • JP2013255505A
    • 2013-12-26
    • JP2013162935
    • 2013-08-06
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • KATO OSAMUMORI HIROYUKI
    • C12P41/00C07C227/32C07C229/08
    • PROBLEM TO BE SOLVED: To produce an optically active amino acid and an optically active N-alkoxycarbonylamino acid which can obtain an optically active amino acid and an optically active N-alkoxycarbonylamino acid with good yield.SOLUTION: After a pH of an aqueous solution including racemic amino acid amide is adjusted by an acid in the vicinity of neutral, enantioselective hydrolysis reaction by amidase of amino acid amide is carried out. Afterwards, in a production method for an optically active amino acid, an inorganic base compound of an amount of mol with which the acid is almost neutralized is added in the aqueous solution, and furthermore, an optically active amino acid is crystalized and recovered by substituting the solvent of the aqueous solution from water by the solvent of an alcohol with three or more carbons. A production method for an optically active N-alkoxycarbonylamino acid uses a raw material of optically active N-alkoxycarbonylamino acid production without purification operation of optically active amino acid which is recovered from a hydrolysis reaction solution.
    • 要解决的问题:制备光学活性氨基酸和光学活性N-烷氧基羰基氨基酸,其可以以良好的产率获得光学活性氨基酸和光学活性N-烷氧基羰基氨基酸。溶液:在包括 外消旋氨基酸酰胺由中性附近的酸调节,进行酰氨基酰胺酰胺酶的对映选择性水解反应。 然后,在光学活性氨基酸的制造方法中,在该水溶液中添加摩尔量几乎中和的无机碱化合物,此外,光学活性氨基酸通过置换 通过具有三个或更多个碳的醇的溶剂将水溶液从水中溶解。 光学活性N-烷氧基羰基氨基酸的制备方法使用旋光活性N-烷氧基羰基氨基酸的原料,而不需要从水解反应溶液中回收的光学活性氨基酸的纯化操作。
    • 87. 发明专利
    • Porous electrode base material and method for producing the same
    • 多孔电极基材及其制造方法
    • JP2013251070A
    • 2013-12-12
    • JP2012123356
    • 2012-05-30
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • SUMIOKA KAZUHIRO
    • H01M4/88D04H1/4242H01M8/10
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To satisfy needs for: a porous electrode base material high in thickness accuracy, gas permeability and conductivity, having sufficient handleability, low in manufacturing cost, and less in weight loss in carbonization causing uneven thickness and undulation; and a method for producing the porous electrode base material.SOLUTION: A method for producing a porous electrode base material includes a step (1) of producing a precursor sheet comprising a carbon short fiber (A), a carbon precursor fiber (b) and carbon powder (C) which are dispersed therein, and a step (2) of subjecting the precursor sheet to carbonization treatment. In the method, a weight loss rate of the precursor sheet through the step (2) is 65% or less.
    • 要解决的问题:为了满足以下要求:厚度精度高,透气性和导电性高,制造成本低,制造成本低的多孔电极基材,碳化引起的重量减少,导致不均匀的厚度和起伏; 以及多孔电极母材的制造方法。解决方案:一种多孔电极母材的制造方法,其特征在于,包括:制造包含碳短纤维(A),碳前体纤维(b)和碳前体纤维 分散在其中的碳粉末(C)和使前体片材碳化处理的工序(2)。 在该方法中,通过工序(2)的前体片的重量损失率为65%以下。
    • 90. 发明专利
    • Optical film, optical sheet, surface light-emitting body, and method for manufacturing optical sheet
    • 光学薄膜,光学薄片,表面发光体以及制造光学薄片的方法
    • JP2013228656A
    • 2013-11-07
    • JP2012138146
    • 2012-06-19
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • HANABUSA AKIHIROYAMADA NAOKOSAEKI YUMIKOYAMASHITA TOMOYOSHI
    • G02B5/00H01L51/50H05B33/02H05B33/10
    • PROBLEM TO BE SOLVED: To provide a member suitable for manufacturing a surface light-emitting body such as an organic EL element in which the light emitted from a light-emitting layer can be effectively extracted to the outside without forming a transparent electrode, an organic light-emitting layer or the like on a rugged structure, and to provide a member suitable for manufacturing a surface light-emitting body in which the light emitted from a light emitting-layer can be effectively extracted to the outside without requiring a complicated process of filling a rugged structure of a diffraction grating with a transparent material having a high refractive index and then flattening the surface.SOLUTION: An optical film has a rugged structure on at least one surface thereof, comprises a resin having a fluorene skeleton and has a refractive index of 1.65 or more. An optical sheet includes a layer comprising the above optical film and a layer having a different refractive index from that of the optical film, in which rugged structures of the layers fitting to each other.
    • 要解决的问题:为了提供适合于制造诸如有机EL元件的表面发光体的构件,其中从发光层发射的光可以有效地提取到外部而不形成透明电极,有机 发光层等,并且提供适于制造表面发光体的构件,其中从发光层发射的光可以有效地提取到外部,而不需要复杂的工艺 用具有高折射率的透明材料填充衍射光栅的粗糙结构,然后使表面平坦化。解决方案:光学膜在其至少一个表面上具有坚固的结构,包括具有芴骨架并具有折射率 指数1.65以上。 光学片包括包含上述光学膜的层和具有与光学膜的折射率不同的折射率的层,其中这些层的凹凸结构彼此适配。