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71. 发明专利

JPH05163439A NEW WATER-SOLUBLE TETRAAZAPORPHINE, FLUORESCENT LABELING PIGMENT CONTAINING THE SAME, BIOLOGICAL SUBSTANCE LABELED WITH FLUORESCENT LABELING PIGMENT, REAGENT CONTAINING THE SAME AND FLUORESCENT ANALYSIS METHOD USING THE SAME 失效
公开(公告)号：JPH05163439A
公开(公告)日：1993-06-29
申请号：JP2219292
申请日：1992-02-07
申请人： HITACHI CHEMICAL CO LTD
发明人： TAI SEIJI , KATAYOSE MITSUO , WATANABE HIROO
IPC分类号： C07H19/00 , C09B47/00 , C09B47/04 , C09B47/24 , G01N33/533
摘要： PURPOSE:To provide the subject compound useful as a fluorescent labeling pigment, useful for the analysis of antibodies, chemicals, DNA, etc. CONSTITUTION:A compound of the formula [M is H2, Mg, Al, etc.; Y is halogen,-OR ,-NR22,-SR (R -R are H, alkyl, aryl, etc.,); p is 0-2; A is a condensed polycyclic aromatic ring having m substituents; X is O, N; Q is hydrocarbon, heterocyclic ring; m is 1-4; p is >=0; four (n) are >=1, respectively; Z is anion, and E is cationic group; or Z does not exist, and E is polyethylene glycol residue, etc.,]. For example, sodium salt of zinc phthalocyanine tetracarboxylic acid. The compound of the formula is obtained e.g. by reacting zinc tetra (n- amyloxycarbonyl) naphthalocyanine in a solvent such as ethanol in the presence of a base such as sodium hydroxide.

72. 发明专利

JPH05124355A NAPHTHALOCYANINE COMPOSITION AND OPTICAL RECORDING MEDIUM USING SAME 失效
公开(公告)号：JPH05124355A
公开(公告)日：1993-05-21
申请号：JP28781491
申请日：1991-11-01
申请人： HITACHI CHEMICAL CO LTD
发明人： KATAYOSE MITSUO , TAI SEIJI
IPC分类号： B41M5/26 , C07D487/22 , C09B67/22 , G11B7/24 , G11B7/244 , G11B7/26
摘要： PURPOSE:To provide a naphthalocyanine composition capable of enhancing the stability against the long-term irradiation with regenerating laser beam and environmental resistance in an optical recording medium. CONSTITUTION:A composition consisting of trimethylsilyl substituted silicon naphthalocyanine having a bulky substituent on the center metal thereof and trymethylsilyl metal free naphthalocyanine is used as the recording layer of an optical recording medium.

73. 发明专利

JPH04363290A OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPH04363290A
公开(公告)日：1992-12-16
申请号：JP13890891
申请日：1991-06-11
申请人： HITACHI CHEMICAL CO LTD
发明人： KATAYOSE MITSUO , TAI SEIJI , MORISHITA YOSHII
IPC分类号： B41M5/26 , G11B7/24 , G11B7/244
摘要： PURPOSE:To provide an optical recording medium having large absorptivity and reflectivity to semiconductor laser having an oscillation wavelength within a wavelength region of 800mn or less and excellent in sensitivity and durability. CONSTITUTION:An optical recording medium is constituted by forming a recording layer based on a compound having a specific structure wherein center metals of a macrocyclic compound having a tetraazaporphin skeleton are bonded by an oxygen atom and the respective center metals have substituents on a substrate.

74. 发明专利

JPH04362653A ELECTROPHOTOGRAPHIC SENSITIVE BODY 失效
公开(公告)号：JPH04362653A
公开(公告)日：1992-12-15
申请号：JP13890991
申请日：1991-06-11
申请人： HITACHI CHEMICAL CO LTD
发明人： TAI SEIJI , KATAYOSE MITSUO , MORISHITA YOSHII
IPC分类号： G03G5/06
摘要： PURPOSE:To obtain the photosensitive body high in sensitivity, especially, to light in a specified long-wavelength region by incorporating a specified compound as an organic photoconductor. CONSTITUTION:The photosensitive layer has a photoconductive layer containing the organic photoconductor on a conductive substrate. This photoconductor has a large circular tetraazaporphyrin structure having its central metal atom combined through oygen with each other represented by formula I in which M is Al, Ga, In, Si, Ge, or Sn; rings A1-A8 is, independently, benzene, naphthalene, or anthracene: X is halogen, -R , -OR , SR , or the like; each of g-n is, independently, an integer of 0-8, and indicating the number of each substituents; each of Y1 and Y2 may exist or not and independently represents halogen, hydroxy, or the like; and each of R -R is H, alkyl, cyclo-alkyl, or the like.

75. 发明专利

JPH04352786A NAPHTHALOCYANINE DERIVATIVE CONTAINING PERFLUOROALKYL GROUP 失效
公开(公告)号：JPH04352786A
公开(公告)日：1992-12-07
申请号：JP2740191
申请日：1991-02-21
申请人： NIPPON OILS & FATS CO LTD , HITACHI CHEMICAL CO LTD
发明人： SAWADA HIDEO , MITANI MOTOHIRO , NAKAYAMA MASAHARU , MORISHITA YOSHII , KATAYOSE MITSUO , OKAMOTO TADASHI , HAYASHI NOBUYUKI
IPC分类号： C07D487/22 , C08K5/54 , C08K5/5465 , G03G5/06
摘要： PURPOSE:To provide the subject new compound useful as a polymeric materials such as optical information recording medium, photoelectric conversion medium, photosensitive material for electrophotography, high-performance film and thin film. CONSTITUTION:The compound of formula I (R is 1-10C alkyl; RF is 1-6C perfluoroalkyl), e.g. perfluoropropyl-bis(trihexylsiloxy)-silicon naphthalocyanine. The compound of formula I can be produced by reacting a diperfluoroalkanoyl peroxide of formula II with a naphthalocyanine compound of formula III preferably at 0-100 deg.C for 0.5-20hr.

76. 发明专利

JPH04320456A PIGMENT FOR FLUORESCENT LABELING, BIO SUBSTANCE LABELED THEREWITH, AND REAGENT CONTAINING THE SAME 失效
公开(公告)号：JPH04320456A
公开(公告)日：1992-11-11
申请号：JP8856391
申请日：1991-04-19
申请人： HITACHI CHEMICAL CO LTD
发明人： TAI SEIJI , KATAYOSE MITSUO , WATANABE HIROO
IPC分类号： C09B47/00 , G01N33/533
摘要： PURPOSE:To obtain the title pigment which can fluoresce at high efficiency and is suited for a reagent for assaying various antigens, drugs and the base sequence of DNA with the aid of a semiconductor laser having an oscillation wavelength near 630nm by rendering a tetraazaporphin ring cationic. CONSTITUTION:A pigment for fluorescent labeling represented by the formula [wherein M is H2, Al, Si, P, Cd, Sn or the like; at least one of Z1 to Z4 is N(+)-R group, and the others are C-R2 groups; R and R are each XQW, QW or W, X is O, N, S, P, Si, Se, CR R (wherein R and R are each H, alkyl or the like) or phenylenel; Q is a group bonding X to W and is an (un)saturated linear, branched or alicyclic group, a polyether group or the like; W is H, OH, CO2H, CO2, SO4 , NH2 or the like; Y is halogen, OR or NR (wherein R and R are each H or an alkyl, acyl, silyl or P-containing group which may have a hydrophilic substituent); and (m) is 0-2].

77. 发明专利

JPH04270686A OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPH04270686A
公开(公告)日：1992-09-28
申请号：JP3105691
申请日：1991-02-26
申请人： HITACHI CHEMICAL CO LTD
发明人： KATAYOSE MITSUO , MORISHITA YOSHII , OKAMOTO TADASHI , HAYASHI NOBUYUKI
IPC分类号： B41M5/26 , C07D487/22 , G03C1/72 , G11B7/24 , G11B7/244 , G11C13/04
摘要： PURPOSE:To improve resistance to regenerating laser light, resistance to environment, resistance to crystallization, and solubility and to enhance sensitivity and durability by forming a recording film layer mainly composed of a specific perfluoroalkyl-containing naphthalocyanine derivative shown by a formula or the mixture thereof on a substrate. CONSTITUTION:An optical recording medium is provided with a recording layer mainly composed of a naphthalocyanine derivative shown by a formula on a substrate [in the formula, M is H2, copper, (R)3SiO-Si-OSi(R)3, or F(CF2)n5(R)2SiO-Si-OSi(R)3] (where R is 1-10 C alkyl); n1, n2, n3, and n4 represent an integer of 0-2; n5 represents an integer of 1-10; but n1+n2+n3+n4not equal to 0 when M is H2, copper, or (R)3SiO-Si-OSi(R)3].

78. 发明专利

JPH0414486A ERASABLE TYPE OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPH0414486A
公开(公告)日：1992-01-20
申请号：JP11800990
申请日：1990-05-08
申请人： HITACHI CHEMICAL CO LTD
发明人： HAGIWARA HIDEO , HAYASHI NOBUYUKI , TAI SEIJI , AKIMOTO TAKAYUKI , KATAYOSE MITSUO
IPC分类号： B41M5/26 , G11B7/24 , G11B7/244
摘要： PURPOSE:To present an erasable type optical recording medium which has excellent durability and mass-productivity, and has high recording sensitivity and high erasing sensitivity, and of which characteristic properties do not decrease even when recording-erasing cycles are repeated by making at least one of two layers contain a specified tetra-azaporhin series compound. CONSTITUTION:On a supporting body, a layer for which a polymer under rubber shape at normal temperature is made to contain a dyestuff DY1 to absorb light in a polymer, and a layer for which a polymer under glass shape at normal temperature is made to contain a dyestuff DY2 to absorb light with a different wavelength from the light for previously mentioned DY1 are formed to be side by side. At least one of the dyestuff DY1 and DY2 is a tetra-azaporphin series compound shown by a formula 1. In the formula, M shows Si, Ge or Sn; Y shows aryloxyl group, alkoxyl group; and two (Y)s may be the same or different. A ring shown by A , A , A , and A shows an aromatic ring to which an organic substituting group may be combined, and A , A , A , and A may be the same or different. By selecting an appropriate aromatic ring as the ring shown by A , A , A , and A , various types of lasers can be used.

79. 发明专利

JPH0313382A OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPH0313382A
公开(公告)日：1991-01-22
申请号：JP14889889
申请日：1989-06-12
申请人： HITACHI CHEMICAL CO LTD
发明人： TAI SEIJI , HAYASHI NOBUYUKI , KATAYOSE MITSUO , HAGIWARA HIDEO , AKIMOTO TAKAYUKI , UEJIMA KOICHI
IPC分类号： B41M5/26 , C07D487/22 , C09K9/02 , G11B7/24 , G11B7/244
摘要： PURPOSE:To obtain an optical recording medium showing high absorption even to semiconductor laser having an oscillation wavelength within a wavelength region of 800nm or less and having high reflectivity by forming a recording layer based on specific tetraazaporphin to the surface of a substrate and changing the recording layer by the irradiation with laser beam to record data and reading said data on the basis of the optical density difference between the irradiated part and non-irradiated unchanged part of the recording layer. CONSTITUTION:A recording layer based on tetraazaporphin represented by formula I is formed and changed with the irradiation with laser beam to record data and data is read on the basis of the optical density difference between the irradiated part and non-irradiated unchanged part of the recording layer. In the formula, M is Si, Ge or Sn, Y is an aryloxy group, an alkoxyl group, a trialkylsiloxyl group, a triarylsiloxy group, a trialkoxysiloxyl group, a triaryloxysiloxyl group, a trityloxy group or an acyloxyl group and rings represented by A , A , A and A are an aromatic ring and at least one of them is a hetero atom-containing aromatic 5-membered ring.

80. 发明专利

JPH02147664A NAPHTHALOCYANINE DERIVATIVE, ITS PRODUCTION, OPTICAL RECORDING MEDIUM PREPARED BY USING SAME AND PRODUCTION OF OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPH02147664A
公开(公告)日：1990-06-06
申请号：JP22381189
申请日：1989-08-30
申请人： HITACHI CHEMICAL CO LTD
发明人： KATAYOSE MITSUO , HAYASHI NOBUYUKI , TAI SEIJI , AKIMOTO TAKAYUKI , UEJIMA KOICHI , HAGIWARA HIDEO
IPC分类号： B41M5/26 , C09B47/04 , G11B7/24 , G11B7/244 , G11B7/248
摘要： NEW MATERIAL:A compound of formula I [wherein k, l, m and n are each 0-4, k+l+m+n>=1; R is a (substituted) alkyl or aryl; M is Si, Ge or Sn; and Y is a halogen atom, a hydroxyl, an aryloxy, an alkoxy, a trialkyl-, triaryl-, trialkoxy- or triaryloxy-siloxyl, trityloxy or an acyloxyl]. EXAMPLE:A compound of formula II. USE:A recording material of an optical recording medium using semiconductor laser beams. PREPARATION:A naphthalocyanine derivative of formula III is reacted with a chlorosilane of the formula: (R )3SiCl (wherein R is an alkyl, an aryl, an alkoxyl or an aryloxyl), a silanol of the formula: (R )3SiOH (wherein R is R ), an alcohol of the formula: R OH (wherein R is an alkyl or an aryl) or a compound of the formula: R COX (wherein R is an alkyl, and X is a halogen atom, a hydroxyl or an acyloxyl).

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