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    • 60. 发明专利
    • REDOX-FLOW CELL
    • JPS63285875A
    • 1988-11-22
    • JP11905587
    • 1987-05-18
    • CHUBU ELECTRIC POWERNIPPON KOKAN KK
    • YOSHIDA HIROSHIHIRAMATSU MASAYOSHIOKAMOTO HARUHITOFUJII EIJI
    • H01M8/04H01M8/18
    • PURPOSE:To increase energy storage density by dividing the electrolyte tank for each of positive and negative electrodes into two tanks connected in series, and cooling one of two tanks in connection with charge or discharge. CONSTITUTION:The electrolyte tank for a negative electrode 2 is divided into two tanks 5a, 5b connected in series. One of the tanks 5a, 5b is cooled in connection with charge or discharge with a cooling unit 10. A negative active material such as trivalent solid chromium chloride is previously put in the tank 5b. For example, the tank 5a for charging is cooled and divalent chromium chloride for the negative active material is deposited in a form of solid and left in the point B and the solution in the tank 5b is converted into the saturated solution of trivalent chromium chloride and supplied to the negative electrode 2. By repeating this circulation, the active material is stored in a form of solid and in high density. When a cell is discharged, this operation is reversely conducted. The operation in a positive electrode 1 is also performed in the same way.