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    • 41. 发明专利
    • METAL OXIDE FILM AND ITS PRODUCTION
    • JPH10102293A
    • 1998-04-21
    • JP25976696
    • 1996-09-30
    • MINOLTA CO LTD
    • KITAOKA KENJI
    • C25D13/02
    • PROBLEM TO BE SOLVED: To stably produce dense metal oxide film almost free from impurities by depositing powder on an electrode substrate by electrophoresis using metal powder produced by a sol-gel method as starting material, sintering and oxidizing the deposited powder by heating. SOLUTION: Compds. of metals such as Pb, La, Zr, Ti and Li are gelatinized in a soln. through a sol state and the soln. is concd. by heating or spray-dried to form an amorphous or crystal phase compsn. This dry product is pulverized and added to a solvent to prepare a soln. for deposition by electrophoresis and electric current is supplied between a Pt electrode 3 as the cathode and an alumina substrate 1 as the cathode in the soln. to electrodeposit metal powder on the substrate 1. The substrate 1 is then pulled up and the powder is sintered and oxidized by heating in air. The objective very dense nonporous metal oxide film almost free from impurities is stably produced. The metal oxide is, e.g. (Pb, La) (Zr, Ti)O3 .
    • 47. 发明专利
    • FORMATION OF HEATER PROTECTION FILM
    • JPH08321374A
    • 1996-12-03
    • JP15081495
    • 1995-05-25
    • TANAKA PRECIOUS METAL IND
    • MIYAZAKI KENICHI
    • H05B3/10C25D13/02C25D13/12
    • PURPOSE: To prevent the deterioration of a heater base material and improve the durability thereof by restraining the evaporation or oxidation of the base material via the formation of a ceramic film thereon at a sintering process after the electrode-deposition of ceramic particles, using the electrophoresis method. CONSTITUTION: Ceramic particles are electro-deposited on a heater base material in water or nonaqueous solvent suspension, using the electrophoresis method and sintered at the preset temperature, thereby forming a ceramic film on the base material. As a result, a dense ceramic protection film of uniform thickness is formed on the base material over a wide range. In this case, the base material is preferably a kanthal, platinum alloy, molybdenum or tungsten filament. Also, alumina fine particles are used as the ceramic particles. Furthermore, the electro-deposition of ceramic particles is made at voltage between 1 and 35V over 0.5 to 15 minutes, and preferably the particles are sintered at a temperature between 1,500 and 1,650 deg.C.