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    • 43. 发明专利
    • Aqueous resin composition, method for manufacturing the same, and metallic coating material
    • 水性树脂组合物,其制造方法和金属涂料
    • JP2012001584A
    • 2012-01-05
    • JP2010135827
    • 2010-06-15
    • Dai Ichi Kogyo Seiyaku Co Ltd第一工業製薬株式会社
    • TAKEKAWA JUNWATANABE SATOYANAGAO KENJI
    • C08L57/00C08F2/28C08G18/10C08L75/04C09D5/02C09D157/00C09D175/12
    • PROBLEM TO BE SOLVED: To provide an aqueous resin composition which ensures the good appearance of a coating film and superior compounding stability with an unsaturated polymerizable monomer polymer, a method for manufacturing the same, and a metallic coating material.SOLUTION: The aqueous resin composition and the metallic coating material are characterized in that an unsaturated polymerizable monomer polymer (A) is emulsified with a cationic group-containing polyurethane resin (B). The method for producing the aqueous resin composition includes: a step of dispersing in water a solution containing an unsaturated polymerizable monomer (a) and a cationic group-containing isocyanate group-terminated urethane prepolymer (b); a step of emulsifying a cationic group-containing polyurethane resin (B) by chain elongation of the cationic group-containing isocyanate group-terminated urethane prepolymer (b) with water and/or a polyamine; and a step of yielding an unsaturated polymerizable monomer polymer (A) by polymerizing the unsaturated polymerizable monomer (a).
    • 要解决的问题:提供确保涂膜的良好外观和与不饱和可聚合单体聚合物的优异的配混稳定性的水性树脂组合物,其制造方法和金属涂层材料。 解决方案:水性树脂组合物和金属涂层材料的特征在于不饱和可聚合单体聚合物(A)用含阳离子基团的聚氨酯树脂(B)乳化。 水性树脂组合物的制造方法包括:在水中分散含有不饱和可聚合单体(a)和含阳离子基团的异氰酸酯基封端的氨基甲酸酯预聚物(b)的溶液的步骤; 通过含阳离子基团的异氰酸酯基封端的氨基甲酸酯预聚物(b)与水和/或多胺的链延长来乳化含阳离子基团的聚氨酯树脂(B)的步骤; 和通过聚合不饱和可聚合单体(a)得到不饱和可聚合单体聚合物(A)的步骤。 版权所有(C)2012,JPO&INPIT