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31. 发明专利

JPS59226020A MANUFACTURE OF POLYPYRROLE 失效
公开(公告)号：JPS59226020A
公开(公告)日：1984-12-19
申请号：JP10378084
申请日：1984-05-24
申请人： BASF AG
发明人： HERUBERUTO NAARUMAN , YOHAN NITSUKURU , GERUNOOTO KEERAA
IPC分类号： C08F34/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08G73/06 , C08L101/12 , C09D5/44 , C25D13/08 , H01B1/12 , H01L51/30 , H01M4/60 , C08G73/00 , C08F2/58

32. 发明专利

JPS59164304A Apparatus for forming polymer membrane 失效
标题翻译：用于形成聚合物膜的装置
公开(公告)号：JPS59164304A
公开(公告)日：1984-09-17
申请号：JP3857483
申请日：1983-03-07
申请人： Mitsubishi Electric Corp
发明人： FUJII HARUHISA
IPC分类号： C08F2/00 , C08F2/54 , C08F2/58 , C08G85/00 , H01L21/312
摘要： PURPOSE: An apparatus for forming a polymer membrane free from free radical and having uniform quality by giving, in a high vacuum, energy necessary for the polymerization of a monomer gas which is ejected against the surface of an object to be treated and forms a polymer membrane thereon.
CONSTITUTION: A reaction vessel 1 having a holder for securing an object 2 to be treated in its inside and being evacuated to a high vacuum is provided with a mechanism for giving thermal energy which is necessary at least for the polymerization reaction of a monomer gas which is ejected against the surface of the object 2 and forms a polymer membrane. Said mechanism for giving energy is composed of a cylindrical body having a small-diameter nozzle 14a in a position opposite to the body 2 and comprises a mechanism 14 for giving kinetic energy transformed from the static pressure of the monomer gas fed into the interior, a mechanism 15 for giving thermal energy and a mechanism 25 for increasing energy by electrical acceleration.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：一种用于形成不含自由基并具有均匀质量的聚合物膜的装置，其在高真空中提供聚合单体气体所需的能量，该单体气体被喷射到被处理物体的表面并形成聚合物膜上。构成：具有用于将待处理物体2固定在其内部并被抽真空至高真空的保持器的反应容器1设置有至少用于单体气体的聚合反应所需的热能的机构，被喷射到物体2的表面上并形成聚合物膜。所述供能机构由具有与主体2相反的位置的小直径喷嘴14a的圆柱体构成，并且包括用于产生从供给到内部的单体气体的静压转换的动能的机构14，用于产生热能的机构15和用于通过电加速度增加能量的机构25。

33. 发明专利

JPS59133204A Production of novel polymer composition 失效
标题翻译：新型聚合物组合物的生产
公开(公告)号：JPS59133204A
公开(公告)日：1984-07-31
申请号：JP660183
申请日：1983-01-20
申请人： Mitsubishi Rayon Co Ltd
发明人： KISHIDA KAZUO , SASAKI ISAO , ASAI HAJIME , MUKAI NOBUHIRO
IPC分类号： C08F2/00 , C08F2/58 , C08G79/00 , C08K7/06 , C08L85/00
摘要： PURPOSE: To obtain a polymer composition comprising carbon fiber firmly united with an organotitanate polymer, by electrolytically polymerizing a reactive monomer at least part of which comprises an organotitanate compound by using carbon fiber as an electrode.
CONSTITUTION: Carbon fiber 3 is set in an electrolytic polymerization tank 5, and an electrolytic reaction solution 4 containing both an organotitanate compound (and, if necessary, other reactive monomers) and a supporting electrolyte is poured into the tank. The reactive monomer is electrolytically polymerized by using carbon fiber 3 as an electrode to obtain the purpose polymer composition comprising the carbon fiber firmly united with the organotitanate polymer. Suitable organotitanate compounds include those of formulas I and II (wherein R
1 is a 1W50 C alkyl, R
2 is H, a 1W40C alkyl, and R
3 is 1W40C alkyl), e.g., isopropoxytitanium triisostearate.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了获得包含与有机钛酸酯聚合物牢固结合的碳纤维的聚合物组合物，通过电解聚合反应性单体，其中至少一部分反应性单体通过使用碳纤维作为电极而包含有机钛酸盐化合物。构成：将碳纤维3置于电解聚合槽5中，并将含有有机钛酸盐化合物（和必要时的其它反应性单体）的电解反应溶液4和支持电解质注入槽中。反应性单体通过使用碳纤维3作为电极进行电解聚合，以获得包含与有机钛酸酯聚合物牢固结合的碳纤维的目的聚合物组合物。合适的有机钛酸酯化合物包括式I和II（其中R 1为1-50 C烷基，R 2为H，1-40 C烷基，R 3为1-40 C烷基）的那些，例如异丁氧基三异硬脂酸钛。

34. 发明专利

JPS59120620A PRODUCTION OF NEW POLYMER COMPOSITION 失效
公开(公告)号：JPS59120620A
公开(公告)日：1984-07-12
申请号：JP22665282
申请日：1982-12-27
申请人： MITSUBISHI RAYON CO
发明人： KISHIDA KAZUO , SASAKI ISAO , ASAI HAJIME , MUKAI NOBUHIRO
IPC分类号： D06M13/00 , C08F2/00 , C08F2/58 , C08F293/00 , C08G59/00 , C08G59/18 , C08G59/20 , C08J5/06 , C08J5/24 , C08K7/06 , C08L63/00 , D06M101/00 , D06M101/40
摘要： PURPOSE:To obtain a polymer consisting of carbon fiber and an epoxy polymer which are strongly united, by using a cycloaliphatic epoxy compound as at least part of a reactive monomer and electrolytically polymerizing the monomer by using carbon fiber as an electrode. CONSTITUTION:A cycloaliphatic epoxy compound of, for example, formula I or II(wherein R1 is a group of formula III, R3 is a 1-20C alkylene, R2 is a 1-30C alkyelen, and R4 is a 30C or lower alkylene) is used as at least part of a reactive monomer, and the monomer and a strongly electrolytic inorganic salt (e.g., sodium nitrate) are dissolved in a solvent. The resulting solution is poured into a electrolytic polymerization apparatus 5 as an electrolyte 4. Carbon fiber rovings 3 are immersed in the electrolyte 4 and a D.C. current is passed between the electrolyte 4 and the carbon fiber 3. Thus the reaction mixture is electrolytically polymerized to obtain the purpose polymer composition consisting of the carbon fiber 3 and the epoxy polymer which are strongly united.

35. 发明专利

JPS5974110A Production of new polymer composition 失效
标题翻译：生产新型聚合物组合物
公开(公告)号：JPS5974110A
公开(公告)日：1984-04-26
申请号：JP18329582
申请日：1982-10-19
申请人： Mitsubishi Rayon Co Ltd
发明人： KISHIDA KAZUO , SASAKI ISAO , MUKAI NOBUHIRO , ASAI HAJIME
IPC分类号： C08F2/00 , C08F2/44 , C08F2/58 , C08F30/00 , C08F30/08 , C08F230/08 , C08F292/00 , D06M14/00 , D06M14/36 , D06M15/21 , D06M101/00 , D06M101/40
摘要： PURPOSE: To obtain a new polymer composition containing carbon fiber and an organic polymer strongly united therewith useful in the fields of aircrafts, aerospaces, cars, etc., by using carbon fiber as an electrode and a specified vinylsilane compound as a reactive monomer.
CONSTITUTION: By electrolytically polymerizing a reactive monomer component by using carbon fiber as an electrode, the desired new polymer composition is obtained by using a vinylsilane compound of the formula [wherein R
1 is H, a 1W20C alkyl or phenyl or a derivative thereof, or a halogen; R
2 is (CH
2 )
n or COO(CH
2 )
n ; n is 0W30; m is 0W20, R
3 is H, a 1W15C alkyl or -Y-O-Z; Y is a 1W15C alkylene; and Z is a 1W15C alkyl], e.g., vinyltriethoxysilane, as at least part of said reactive monomer component. An embodiment of this process comprises immersing carbon fiber roving 3 in an electrolytic polymerization solution 4 and effecting an electrolytic polymerization reaction by applying a voltage between the electrolytic solution and the carbon fiber.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过使用碳纤维作为电极和指定的乙烯基硅烷化合物作为反应性单体，获得含有碳纤维和与其结合牢固的有机聚合物的新的聚合物组合物，可用于飞机，空中飞行，汽车等领域。构成：通过使用碳纤维作为电极使反应性单体组分电解聚合，通过使用下式的乙烯基硅烷化合物[其中R1是H，1-20C烷基或苯基或其衍生物，或卤素; R2是（CH2）n或COO（CH2）n; n为0-30; m为0-20，R3为H，1-15C烷基或-Y-O-Z; Y为1-15C亚烷基; 和Z为1-15C烷基]，例如乙烯基三乙氧基硅烷作为所述反应性单体组分的至少一部分。该方法的一个实施方案包括将碳纤维粗纱3浸入电解聚合溶液4中，并通过在电解溶液和碳纤维之间施加电压来进行电解聚合反应。

36. 发明专利

JPS5941699A Improved turbo-type vacuum pump 失效
标题翻译：改进的涡轮式真空泵
公开(公告)号：JPS5941699A
公开(公告)日：1984-03-07
申请号：JP15212082
申请日：1982-08-31
申请人： Shimadzu Corp
发明人： OKA SHIYOUTAROU , TAWARA OSAMU
IPC分类号： C08F2/00 , C08F2/58 , F04B37/16 , F04D19/04 , F04D29/02 , F04D29/38
CPC分类号： F04D19/042
摘要： PURPOSE:To obtain high vacuum by forming a high-polymeric thin film closely onto the surface of a turbine blade through plasma polymerization method and preventing gas from intruding into between the blade and the film. CONSTITUTION:An air intake port 7 of an air cooling type turbo molecular pump 1 is connected to an object apparatus, and a motor 2 is driven, and then the gas in the apparatus is discharged through the pump 1. The surface of a turbine blade possesses the superior resistance to chemicals, since the surface is coated and protected by a plasma-polymerized polymethacrolein film 11. Since said film 11 is formed from in close adhesion the corresponding monomer in the vacuum environment, there is no possibility for gas to invade into between the film 11 and the blade 10. Therefore, the high vacuum or super high vacuum in the equal degree to that with the turbine blade onto which surface processing is not applied can be obtained.
摘要翻译：目的：通过等离子体聚合法将涡轮叶片的表面紧密地形成高分子薄膜，防止气体进入到叶片和薄膜之间，从而获得高真空度。构成：空气冷却型涡轮分子泵1的进气口7连接到物体设备，驱动马达2，然后通过泵1将设备中的气体排出。涡轮叶片的表面具有优异的耐化学性，因为表面被等离子体聚合的聚甲基丙烯醛膜11涂覆和保护。由于所述膜11由真空环境中相应的单体紧密粘合形成，所以气体不可能侵入因此，可以获得与没有施加表面处理的涡轮叶片相同程度的高真空或超高真空。

37. 发明专利

JPS57196200A METHOD OF FIXING ACTINIDE METAL OXIDE ION 失效
公开(公告)号：JPS57196200A
公开(公告)日：1982-12-02
申请号：JP8256782
申请日：1982-05-18
申请人： WESTINGHOUSE ELECTRIC CORP
发明人： PIITAA MAIYAA KIYATSUSURU , JIEEMUZU DEBITSUDO BURATSUKUHO , DEI KORIN FUIRITSUPUSU
IPC分类号： C08F2/58 , G21F9/00 , G21F9/16 , G21F9/30

38. 发明专利

JPS575711A PRODUCTION OF POLYMER GRAFTED TO CARBONACEOUS SUBSTANCE 失效
公开(公告)号：JPS575711A
公开(公告)日：1982-01-12
申请号：JP7991480
申请日：1980-06-12
申请人： MORIKAWA TAKESHI , DAIEI GOMU KK , TOYO TANSO CO
发明人： MORIKAWA TAKESHI , YOSHIDA MINORU , ISHIGURO JIROU
IPC分类号： C08F2/00 , C08F2/44 , C08F2/58 , C08F292/00
摘要： PURPOSE:A carbonaceous substance is brought into contact with a radically polymerizable monomer and electricity is applied to the carbonaceous substance to generate Joule heat, which causes the graft polymerization of the monomer onto the substance, thus producing the titled uniform polymer readily separable with a saved amount of heat in high efficiency. CONSTITUTION:A carbonaceous substance that is made by impregnating a carbonaceous powder with a radically polymerizable monomer such as styrene is charged from the inlet 2 into an electrically insulated reactor 4, e.g., a glass reactor equipped with electrode plate 3. Then, the plate 6 provided with the other electrode 3' is shifted so that plate 6 comes into uniform contact with the bulk of the carbonaceous powder. Then, electricity is applied between electrodes 3 and 3' to pass an electric current through the carbonaceous powdery bulk 1. Joule heat is generated in the bulk and the polymerization of the monomer is initiated to give polymers grafted chemically and physically to the carbonaceous substance.

39. 发明专利

JPS5146151B1 失效
公开(公告)号：JPS5146151B1
公开(公告)日：1976-12-07
申请号：JP4691172
申请日：1972-05-13
IPC分类号： C08F2/52 , C08F2/58 , C08F4/00

40. 发明专利

JP2019163482A 1,1−二置換アルケン化合物を有する組成物の電解開始重合审中-公开
公开(公告)号：JP2019163482A
公开(公告)日：2019-09-26
申请号：JP2019099042
申请日：2019-05-28
申请人：シラス・インコーポレイテッド
发明人：ピーター・ルーロン・スティーブンソン , ジェフリー・エム・サリバン
IPC分类号： C08F2/00 , C08F22/14 , C08F2/38 , C08F2/58
摘要：【課題】優れた機械的特性を保持しながら、重合開始剤を添加することなく、種々の基材上で容易に硬化することができる重合可能な系を提供する。【解決手段】重合を開始する方法であって、前記方法は、重合可能な組成物を基材と接触させることを含み、前記重合可能な組成物が、1つ以上の1,1−二置換アルケン化合物を含み;さらに前記方法が、重合を開始するために、前記重合可能な組成物に電荷を流すことを含む、前記方法。組成物は、基材に電解グラフトし、または導電性共力剤を含むこともできる。【選択図】なし

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