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    • 35. 发明专利
    • JPH05237351A
    • 1993-09-17
    • JP4336392
    • 1992-02-28
    • DAICEL CHEM
    • OKAMOTO YOSHIOYASHIMA EIJI
    • B01D69/00B01D71/08C07B57/00
    • PURPOSE:To obtain an optically active material suitable for treatment in a large amt. with a simple operation by using an optical splitting membrane for which a material having a function for optical splitting ability such as polysaccharide deriv. is fixed to the inside and both surfaces of a base membrane and bringing a racemic compound source solution into contact with the one surface of the membrane film and then washing the other surface of the membrane with a washing solution. CONSTITUTION:A material having the optical splitting ability such as polysaccharide deriv. of beta-1,4-glucan (cellulose) is dissolved in an org. solvent, and then applied on the base membrane such as ultrafiltration membrane or precision filtration membrane by coating or immersing to be fixed to the inside and both surfaces of the base membrane. A racemic compound source solution being a compound to be split is brought into contact with the one surface of the obtd. optical splitting membrane, while the other surface of the membrane is maintained as vacant. The membrane is intermittently washed with the washing solution so that the optically active material selectively adsorbed to the inside of the membrane is recovered in the washing solution.