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    • 32. 发明专利
    • Electrode
    • 电极
    • JP2005310745A
    • 2005-11-04
    • JP2004377492
    • 2004-12-27
    • Toyota Central Res & Dev Lab Inc株式会社豊田中央研究所
    • FUKANO TATSUOMOTOHIRO TOMOMI
    • H05B33/28H01L51/50H05B33/14
    • Y02E10/50
    • PROBLEM TO BE SOLVED: To provide an electrode, in which the ionization potential at the surface of the current carrying part can be made sufficiently large and at low cost.
      SOLUTION: The electrode comprises a first current-carrying part 4 having a first metal oxide on a substrate 2, and a second current-carrying part 6 having a second metal oxide different from the first metal oxide on the first conductive 4, wherein the thickness of the second current-carrying part is not larger than 30 nm, or the second current carrying part has a plurality of island-like parts. In the constitution of the electrode 10, the ionization potential of the second current-carrying part of the electrode can be made sufficiently larger than that of the first current-carrying part or of the second current-carrying part, each of which is independently disposed on the substrate. Thus, since the use of oxygen ions, active oxygen or ion plating method can be dispensed with production cost is lowered. Further, the ionization potential of the second current-carrying part is stabilized at a high level, regardless of the utilization environment of the electrode.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种能够使载流部件的表面的电离电位足够大并且成本低的电极。 解决方案:电极包括在基板2上具有第一金属氧化物的第一载流部分4和在第一导电4上具有不同于第一金属氧化物的第二金属氧化物的第二载流部分6, 其中第二载流部分的厚度不大于30nm,或者第二载流部分具有多个岛状部分。 在电极10的结构中,电极的第二载流部分的电离电位可以比第一载流部分或第二载流部分的电离电位充分大, 在基板上。 因此,由于使用氧离子,可以省去活性氧或离子镀方法,生产成本降低。 此外,无论电极的利用环境如何,第二载流部分的电离电位稳定在高水平。 版权所有(C)2006,JPO&NCIPI
    • 33. 发明专利
    • Photoelectrode and dye-sensitized solar cell equipped with above
    • 具有上述光电和透明的太阳能电池
    • JP2005302695A
    • 2005-10-27
    • JP2004371953
    • 2004-12-22
    • Aisin Seiki Co LtdToyota Central Res & Dev Lab Incアイシン精機株式会社株式会社豊田中央研究所
    • FUKANO TATSUOMOTOHIRO TOMOMITOYAMA TOMOYUKIITO MUTSUMITOYODA TATSUO
    • H01L31/04H01M14/00
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a photoelectrode and a dye-sensitized solar cell capable of sufficiently reducing leak current with sufficiently reducing resistance of a transparent conductive membrane in a dye-sensitized solar cell. SOLUTION: The photoelectrode 10 includes a semiconductor electrode 2 having a light-acceptance surface F2, a transparent conductive membrane 3b arranged adjacently on the acceptance surface F2 and containing fluorine dope tin oxide, a transparent conductive membrane 3a arranged adjacently on the transparent conductive membrane 3b and containing tin dope indium oxide, and a transparent substrate 4 arranged adjacently on the transparent conductive membrane 3a. The semiconductor electrode 2 includes an oxide semiconductor particle and a sensitizing dye, with a thickness of the transparent conductive membrane 3b of 30nm or more, ionized potentials of the transparent conductive membranes 3a, 3b of not less than an ionized potential of the oxide semiconductor particle and 4.8eV or less. COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决问题:提供能够充分降低染料敏化太阳能电池中的透明导电膜的电阻的充分降低漏电流的光电极和染料敏化太阳能电池。 解决方案:光电极10包括具有光接收表面F2的半导体电极2,邻接在接收表面F2上并且包含氟掺杂氧化锡的透明导电膜3b,邻近地设置在透明的透明导电膜3a上的透明导电膜3a 导电膜3b并且含有锡掺杂氧化铟,以及相邻地设置在透明导电膜3a上的透明基板4。 半导体电极2包括透明导电膜3b的厚度为30nm以上的氧化物半导体粒子和增感染料,透明导电膜3a,3b的离子化电位为氧化物半导体粒子的电离电位以上 和4.8eV以下。 版权所有(C)2006,JPO&NCIPI
    • 34. 发明专利
    • Dye-sensitized solar cell
    • 透明的太阳能电池
    • JP2004349129A
    • 2004-12-09
    • JP2003145277
    • 2003-05-22
    • Aisin Seiki Co LtdToyota Central Res & Dev Lab Incアイシン精機株式会社株式会社豊田中央研究所
    • FUKANO TATSUOMOTOHIRO TOMOMINISHIMURA KAZUHIKO
    • H01L31/04H01M14/00
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a dye sensitized solar cell superior in durability wherein an enough photoelectric conversion efficiency can be maintained for a long term, in a dye sensitized solar cell which comprises a semiconductor electrode containing anatase-type titanium dioxide and an electrolyte containing a compound having an ester bond. SOLUTION: The dye sensitized solar cell 20 comprises a photoelectrode 10 which comprises the semiconductor electrode 2 with a light receiving surface F2 containing anatase-type titanium dioxide, and dye as component materials and a transparent electrode 1 having the light receiving surface F1 on the opposite side of a face contacting the semiconductor electrode 2; and a counter electrode CE. The semiconductor electrode 2 and the counter electrode CE are disposed via the electrolyte E so as to be opposed to each other. A compound having an ester bond is contained as a solvent in the electrolyte E; and a light absorption member A is adjacent to the light receiving surface F1 of the photoelectrode 10, and has light transmission characteristics. The light transmittance is not more than 0.2% at a wavelength of ≥290 nm and ≤385 nm, and the light transmittance is not less than 85% at a wavelength of ≥450 nm and ≤900 nm. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了提供一种染料敏化太阳能电池,其耐久性优异,其中长期保持足够的光电转换效率,包括含有锐钛矿型二氧化钛的半导体电极和 含有具有酯键的化合物的电解质。 解决方案:染料敏化太阳能电池20包括光电极10,其包括具有含有锐钛矿型二氧化钛的受光面F2和作为成分材料的染料的半导体电极2和具有受光面F1的透明电极1 在与半导体电极2接触的面的相反侧; 和对电极CE。 半导体电极2和对电极CE经由电解质E配置成彼此相对。 在电解质E中含有具有酯键的化合物作为溶剂; 光吸收构件A与光电极10的受光面F1相邻,具有透光特性。 在≥290nm和≤385nm的波长下的透光率不大于0.2%,在≥450nm和≤900nm的波长下的透光率不小于85%。 版权所有(C)2005,JPO&NCIPI