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    • 31. 发明专利
    • Ethylene polymer composition and film
    • 乙烯聚合物组合物和膜
    • JP2009001778A
    • 2009-01-08
    • JP2008125650
    • 2008-05-13
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • NOZUE YOSHINOBUKAWASHIMA YASUTOYOYAMADA KATSUHIRO
    • C08L23/08
    • C08J5/18C08J2323/08C08L23/0815C08L2205/02C08L2666/06
    • PROBLEM TO BE SOLVED: To provide an ethylene polymer composition whose transparency is increased without excessively deteriorating the impact strength of linear low density polyethylene, and to provide a film obtained by subjecting the polymer composition to extrusion molding.
      SOLUTION: Disclosed is an ethylene polymer composition containing the component (A) and the component (B) defined below. The component (B) is contained in an amount of 0.1 to 20 parts by weight per 100 parts by weight of the component (A). Component (A): an ethylene-α-olefin copolymer satisfying all of the following conditions: the density is within the range of 890 to 925 kg/m
      3 ; the melt flow rate (MFR) is within the range of 0.1 to 10 g/10 minutes; and the flow activation energy (Ea) is less than 50 kJ/mol. Component (B): an ethylene-α-olefin copolymer satisfying all of the following conditions: the density is within the range of 890 to 925 kg/m
      3 ; the limiting viscosity [η] is within the range of 4 to 15 dL/g; and the flow activation energy (Ea) is less than 50 kJ/mol.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供透明度提高而不会使线性低密度聚乙烯的冲击强度过分劣化的乙烯聚合物组合物,并提供通过使聚合物组合物进行挤出成型获得的膜。 解决方案:公开了含有下述(A)成分和(B)成分的乙烯聚合物组合物。 组分(B)的含量相对于(A)成分为100重量份为0.1〜20重量份。 组分(A):满足以下所有条件的乙烯-α-烯烃共聚物:密度在890至925kg / m 3的范围内。 熔体流动速率(MFR)在0.1〜10g / 10分钟的范围内; 流动活化能(Ea)小于50kJ / mol。 组分(B):满足以下所有条件的乙烯-α-烯烃共聚物:密度在890至925kg / m 3的范围内; 特性粘度[η]在4〜15dL / g的范围内; 流动活化能(Ea)小于50kJ / mol。 版权所有(C)2009,JPO&INPIT
    • 35. 发明专利
    • Injection molding
    • 注射成型
    • JP2012153795A
    • 2012-08-16
    • JP2011013888
    • 2011-01-26
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • MASAMI TOSHIHIKONOMURA JUNMANOZUE YOSHINOBU
    • C08L67/00C08F210/16C08L23/08C08L101/00C08L101/16
    • PROBLEM TO BE SOLVED: To provide an injection molding which has an excellent balance in impact strength and tensile elongation at break.SOLUTION: The injection molding is composed of a polyethylene-based resin composition comprising: 18 to 50 mass% of aliphatic polyester (A); 40 to 77 mass% of the following component (B); and 3 to 15 mass% of a compatibilizer (C) (wherein, the total content of the component (A), the component (B) and the component (C) is 100 mass%). The component (B) denotes an ethylene-α-olefin copolymer in which density is 905 to 950 kg/m, a melt flow rate is 0.5 to 20 g/10 min, and the activation energy (Ea) of a flow is 55 to 100 kJ/mol.
    • 要解决的问题:提供冲击强度和断裂拉伸伸长率之间具有优异平衡的注射成型。 注塑成型由聚乙烯系树脂组合物构成,其含有18〜50质量%的脂肪族聚酯(A), 40〜77质量%的下述成分(B); 和3〜15质量%的增容剂(C)(其中,成分(A),成分(B)和成分(C)的总含量为100质量%)。 组分(B)表示密度为905至950kg / m 2,熔体流动速率为0.5至20g / 10min的乙烯-α-烯烃共聚物, 流动的活化能(Ea)为55〜100kJ / mol。 版权所有(C)2012,JPO&INPIT
    • 36. 发明专利
    • ETHYLENE-α-OLEFIN COPOLYMER AND MOLDED ARTICLE
    • 乙烯-α-烯烃共聚物和成型品
    • JP2011213998A
    • 2011-10-27
    • JP2011055276
    • 2011-03-14
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • NOZUE YOSHINOBUOCHI NAOKO
    • C08F210/02B29C47/00
    • C08F210/16C08F4/65916C08F10/00C08F4/65904C08F210/14C08F2500/04C08F2500/12C08F2500/17C08F2500/19C08F2500/20
    • PROBLEM TO BE SOLVED: To provide an ethylene-α-olefin copolymer having low extrusion load, high melt tension, and excellent in a drawing/taking property when the copolymer melted in a tension-constant condition is drawn/taken, excellent in a strain hardening property, and excellent in a secondary processability.SOLUTION: The ethylene-α-olefin copolymer has a density of 860-950 kg/m, a melt flow rate of 0.01-100 g/10 minutes, and a molecular weight distribution curve measured by gel permeation chromatography, wherein the molecular weight giving a maximum peak is within the range of 10,000-20,000, the height of maximum peak at the position of 177,000 of the molecular weight is ≥5% to ≤30% when the height of the maximum peak is 100%, and a characteristic relaxation time satisfies the formula (1): 40.2×MFR
    • 要解决的问题:提供具有低挤出载荷,高熔体张力,拉伸/拉伸常数条件下共聚物拉伸/取出性优异的乙烯-α-烯烃共聚物,应变优异 硬化性能和二次加工性优异。溶液:乙烯-α-烯烃共聚物的密度为860-950kg / m 2,熔体流动速率为0.01-100g / 10分钟,测得的分子量分布曲线 通过凝胶渗透色谱法,其中给出最大峰的分子量在10,000-20,000的范围内,当最大峰的高度为177,000时,分子量的最高峰的高度为≥5%至≤30% 峰值为100%,特征弛豫时间满足式(1):40.2×MFR <τ<71.8×MFR,存在通过差示扫描量热计观察到的多个熔融峰。
    • 37. 发明专利
    • Preliminary polymerization catalyst component, and method for producing preliminary polymerization catalyst component
    • 初步聚合催化剂组分和生产初步聚合催化剂组分的方法
    • JP2011063713A
    • 2011-03-31
    • JP2009215517
    • 2009-09-17
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • KAWASHIMA YASUTOYONOZUE YOSHINOBU
    • C08F4/65C08F10/00
    • PROBLEM TO BE SOLVED: To provide a preliminary polymerization catalyst component giving an ethylene-α-olefin copolymer having a high molding property on melting and having the less fish eyes of film obtained by fabrication, and a method for producing the olefin polymer by using the preliminary polymerization catalyst.
      SOLUTION: This preliminary polymerization catalyst component for the copolymerization of the ethylene-α-olefin, obtained by the preliminary polymerization of olefins under the presence of a solid catalyst component is provided with that the preliminary polymer obtained by the preliminary polymerization of the olefins satisfies all of the following (a) to (d) requirements. (a) Intrinsic viscosity is ≥1 and ≤5 dl/g, (b) The value of short chain branches (SCB) per 1,000 carbon atoms is ≥5 and ≤30, (c) Mw/Mn is ≥7 and ≤15, and (d) Mz/Mw is ≥5 and ≤15.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:提供一种预聚合催化剂组分,其产生在熔融时具有高模塑性能并且通过制造获得的膜的鱼眼较少的乙烯-α-烯烃共聚物,以及制备烯烃聚合物的方法 通过使用预聚合催化剂。 解决方案:通过在固体催化剂组分存在下通过烯烃的预聚合获得的用于共聚乙烯-α-烯烃的预聚合催化剂组分提供了通过预聚合得到的预聚合物 烯烃满足以下所有(a)至(d)要求。 (a)特性粘度≥1和≤5dl / g,(b)每1000个碳原子的短链支链(SCB)的值为≥5且≤30,(c)Mw / Mn为≥7且≤15 ,(d)Mz / Mw≥5且≤15。 版权所有(C)2011,JPO&INPIT
    • 39. 发明专利
    • Resin composition for cross-linked foaming and cross-linked foam body
    • 用于交联泡沫和交联泡沫体的树脂组合物
    • JP2011006678A
    • 2011-01-13
    • JP2010122511
    • 2010-05-28
    • Sumitomo Chemical Co Ltd住友化学株式会社
    • MASAMI TOSHIHIKONOZUE YOSHINOBU
    • C08J9/04C08F210/02
    • PROBLEM TO BE SOLVED: To provide a resin composition for cross-linked foaming suited for producing a cross-linked foam body excellent in expansion ratio.SOLUTION: The resin composition for cross-linked foaming is obtained by irradiating a resin composition containing the following component (A) of 100 pts.wt. and the following component (B) of 1 to 70 pts.wt. with respect to the component (A) of 100 pts.wt. with ionizing radiation. The component (A) is an ethylene-α-olefin copolymer component which has a monomer unit based on ethylene and a monomer unit based on 3-20C α-olefin, in which density (d) is 860 to 950 kg/m, the melt flow rate (MFR) is 0.01 to 100 g/10 min, the molecular weight distribution has two peaks and the melting peak measured by a differential scanning calorimeter (DSC) is single. The component (B) is a thermo-decomposition type foaming agent of which the decomposition temperature is 120 to 240°C.
    • 要解决的问题:提供一种交联发泡用树脂组合物,其适用于制造发泡倍率优异的交联泡沫体。溶解性交联发泡用树脂组合物是将下述成分 (A)为100重量 和以下成分(B)为1〜70重量份 相对于100重量份的组分(A) 与电离辐射。 组分(A)是乙烯-α-烯烃共聚物组分,其具有基于乙烯的单体单元和基于3-20℃α-烯烃的单体单元,其中密度(d)为860至950kg / m 2, 熔体流动速率(MFR)为0.01〜100g / 10分钟,分子量分布为2个峰,差示扫描量热仪(DSC)测定的熔融峰为单峰。 组分(B)是分解温度为120-240℃的热分解型发泡剂。