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    • 31. 发明专利
    • Method for producing oxide superconductive thin film
    • 生产氧化物超导薄膜的方法
    • JP2011230946A
    • 2011-11-17
    • JP2010101261
    • 2010-04-26
    • National Institute Of Advanced Industrial Science & TechnologySumitomo Electric Ind Ltd住友電気工業株式会社独立行政法人産業技術総合研究所
    • YAMAGUCHI IWAOKUMAGAI TOSHIYAHIKATA TAKESHIOKI YASUTARO
    • C01G1/00B05D5/12H01B13/00
    • PROBLEM TO BE SOLVED: To provide a method for producing an oxide superconductive thin film which forms a calcined film in which roughening generated in the surface is suppressed upon the calcining of a coating film of an MOD (Metal Organic Deposition) solution, and produces an oxide superconductive thin film having sufficiently high Jc and Ic by the subsequent normal firing.SOLUTION: The method for producing an oxide superconductive thin film uses a metal organic compound as raw material to produce an oxide superconductive thin film used for producing a superconductive wire rod, by metal organic deposition. The method includes: a coating film producing step of coating the surface of a substrate with a solution of a metal organic compound to produce a coating film; a calcining heat treatment step of thermally decomposing and removing organic components contained in the metal organic compound of the coating film to produce a calcined film; and a normal firing heat treatment step of crystallizing the calcined film to produce an oxide superconductive thin film. In the calcining heat treatment, temperature rising till a calcining heat treatment temperature is performed under a pressure atmosphere lower than the atmospheric pressure.
    • 要解决的问题:提供一种形成氧化物超导薄膜的方法,该氧化物超导薄膜形成煅烧膜,其中在对MOD(金属有机沉积)溶液的涂膜进行煅烧时,在表面产生粗糙度被抑制, 并通过随后的正常烧制产生具有足够高的Jc和Ic的氧化物超导薄膜。 解决方案:氧化物超导薄膜的制造方法使用金属有机化合物作为原料,通过金属有机沉积来制造用于制造超导线材的氧化物超导薄膜。 该方法包括:涂膜生产步骤,用金属有机化合物的溶液涂覆基材的表面以产生涂膜; 煅烧热处理步骤,热分解和除去涂膜的金属有机化合物中所含的有机组分以产生煅烧膜; 以及将煅烧膜结晶以产生氧化物超导薄膜的正常烧成热处理步骤。 在煅烧热处理中,在低于大气压的压力气氛下进行升温至煅烧热处理温度。 版权所有(C)2012,JPO&INPIT
    • 33. 发明专利
    • Method for manufacturing oxide superconducting wire and oxide superconducting wire
    • 氧化物超导电线和氧化物超导线的制造方法
    • JP2011071031A
    • 2011-04-07
    • JP2009222654
    • 2009-09-28
    • Sumitomo Electric Ind Ltd住友電気工業株式会社
    • HIKATA TAKESHI
    • H01B13/00C01G1/00H01B12/06
    • Y02E40/642
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing an oxide superconducting wire, forming a thin film of an oxide superconductor having high crystal denseness and orientation at a low cost. SOLUTION: The method for manufacturing an oxide superconducting wire includes steps of: (S10) preparing powder comprising an oxide superconductor; (S30) aerosolizing the powder; and (S40) jetting an aerosol formed by the aerosolizing step on the main surface of a substrate. The powder may comprise a precursor for forming the oxide superconductor. The method for manufacturing an oxide superconducting wire also includes a step (S50) of converting a thin film formed by the jetting step to a dense film of an oxide superconductor after the jetting step. It is preferable that the temperature inside the thin film in the converting step is increased as the thin film gets close to the substrate from a region apart from the substrate. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决的问题:提供一种制造氧化物超导线材的方法,以低成本形成具有高结晶致密度和取向性的氧化物超导体的薄膜。 解决方案:制造氧化物超导线的方法包括以下步骤:(S10)制备包含氧化物超导体的粉末; (S30)使粉末雾化; 和(S40)将通过雾化步骤形成的气溶胶喷射到基板的主表面上。 粉末可以包含用于形成氧化物超导体的前体。 制造氧化物超导线的方法还包括在喷射步骤之后将通过喷射步骤形成的薄膜转化为氧化物超导体的致密膜的步骤(S50)。 优选的是,随着薄膜从离开基板的区域靠近基板而使转换步骤中的薄膜内的温度升高。 版权所有(C)2011,JPO&INPIT