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    • 39. 发明专利
    • CARBON DIOXIDE CLATHRATE PRODUCTION MEASURING APPARATUS
    • JPH0658896A
    • 1994-03-04
    • JP21272092
    • 1992-08-10
    • CHUBU ELECTRIC POWERMITSUBISHI HEAVY IND LTD
    • SAKAI MATSUSHIGESAJI AKIRANODA HIDETOMOTANII TADAAKINEGORO MASAAKIMINEMOTO MASAKIKITAMURA HIKARIKAMATA TOSHIHIRO
    • C01B32/50G01N27/06C01B31/20
    • PURPOSE:To determine production of carbon dioxide clathrate quantitatively by previously separating solid state clathrate mixed in a solution contained in a reaction vessel through a filter and then measuring electric conductivity of solution subjected to pretreatment. CONSTITUTION:Sample water 12 containing chlorine ions is injected through a sample liquid injection pump 13 into a reaction vessel 11 while furthermore carbon dioxide 14 is injected through an injection pump 15. The vessel 11 is placed in a cooling water tank 16. Carbon dioxide clathrate reaction is then promoted while stirring water and carbon dioxide by means of a stirrer 18 coupled with a motor 17. Reaction temperature and reaction pressure are measured, respectively, through a thermometer 19 and a pressure gauge 20 and recorded on a recorder 21. At that time, a solution discharge valve 22 for measuring electric conductivity in the reaction vessel is opened to produce pressure difference with respect to the atmospheric pressure thus separating solid state carbon dioxide clathrate through a filter 24 disposed in front of a vessel 23 for measuring electric conductivity in the reaction vessel. Solution mixed with no carbon dioxide clathrate is then filled in the vessel 23 and electric conductivity thereof is measured by means of an electric conductivity meter 26 associated with a sensor 25 for measuring electric conductivity. Measurement of electric conductivity is then converted through a data analyzer 27 into a production quantity of carbon dioxide clathrate.