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    • 31. 发明专利
    • Method of manufacturing negative electrode of lithium-ion secondary battery, and lithium-ion secondary battery including negative electrode obtained using its method
    • 锂离子二次电池负极的制造方法和锂离子二次电池,包括使用其方法获得的负极电极
    • JP2007207663A
    • 2007-08-16
    • JP2006027021
    • 2006-02-03
    • Matsushita Electric Ind Co Ltd松下電器産業株式会社
    • NAGAO NOBUAKIUGAJI MASAYAMINO TATSUJIFURUYUI YASUTAKA
    • H01M4/04H01M4/02H01M4/139H01M4/48H01M10/05
    • Y02P70/54
    • PROBLEM TO BE SOLVED: To solve problems that in the case silicon oxide is used as a negative electrode of a lithium ion secondary battery, individual columnar particles are peeled off from a current collector, and charge/discharge capacity is reduced if charge/discharge cycle is repeated.
      SOLUTION: This is a manufacturing method of forming an active material layer composed of silicon oxide having a chemical composition expressed by SiO
      x (0.05≤x≤0.3) on the sheet state current collector having conductivity by a vapor-deposition method, wherein a period of accumulating the active material on the current collector and a period of suspending the accumulation with the silicon as a vapor-deposition source in an atmosphere containing oxygen are alternately installed. By this, the negative electrode can be manufactured by a device of which the film forming rate is fast and which is comparatively simple and convenient. Moreover, the negative electrode obtained by this manufacturing method has an insular structure in which the columnar particles are aggregated in a plurality of numbers on the current collector, and even if the charge/discharge cycle is repeated, capacity deterioration derived from peeling-off from the current collector becomes reducible.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题为了解决在将二氧化硅用作锂离子二次电池的负极的情况下,将单个柱状颗粒从集电体剥离,并且如果电荷充电/放电容量降低,则充电/放电容量降低 /放电循环重复。 解决方案:这是在具有导电性的片状态集电体上形成由具有由SiO x (0.05≤x≤0.3)表示的化学组成的氧化硅组成的活性材料层的制造方法 通过气相沉积法,其中交替地安装在集电体上积聚活性物质的时段和悬浮在作为气相沉积源的硅作为含氧气氛的积聚期间。 由此,负极可以通过成膜速度快的装置制造,相对简单且方便。 此外,通过该制造方法获得的负极具有柱状粒子在集电体上以多个数量聚集的岛状结构,并且即使重复充放电循环,从剥离 集电器变得可以减少。 版权所有(C)2007,JPO&INPIT
    • 32. 发明专利
    • Negative electrode for lithium secondary battery, and lithium secondary battery using same
    • 用于锂二次电池的负极和使用其的锂二次电池
    • JP2007193965A
    • 2007-08-02
    • JP2006008437
    • 2006-01-17
    • Matsushita Electric Ind Co Ltd松下電器産業株式会社
    • MINO TATSUJIUGAJI MASAYANAGAO NOBUAKI
    • H01M4/02H01M4/13H01M4/131H01M4/134H01M4/136H01M4/38H01M4/48H01M4/58H01M10/05
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To provide a negative electrode for a lithium secondary battery that can prevent failures of the battery by using a high-capacity active material and minimizing the concentration of stress upon expansion due to storage of lithium ions, and to provide a lithium secondary battery using the same.
      SOLUTION: The negative electrode for a lithium secondary battery includes a first negative electrode active material layer 21 and a second negative electrode active material layer 23 formed on a sheet-like collector 22, each of the layers 21 and 23 containing particles grown in a slanting direction with respect to the normal to the collector 22. Directions of growth of the particles of the first negative electrode active material layer 21 include a direction d1 that is parallel to the collector 22, while directions of growth of the particles of the second negative electrode active material layer 23 include a direction d2 that is parallel to the collector 22, and an angle α formed between the directions d1 and d2 is within a range of 60 to 120 degrees. The lithium secondary battery is formed by incorporating this negative electrode.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种锂二次电池用负极,其可以通过使用高容量活性材料来防止电池的故障,并且由于锂离子的储存而使膨胀时的应力集中最小化,并且 提供使用其的锂二次电池。 解决方案:用于锂二次电池的负极包括形成在片状集电体22上的第一负极活性物质层21和第二负极活性物质层23,每个层21和23包含生长的颗粒 相对于集电体22的法线倾斜的方向。第一负极活性物质层21的粒子的生长方向包括平行于集电体22的方向d1,同时, 第二负极活性物质层23包括平行于集电体22的方向d2,并且在方向d1和d2之间形成的角度α在60至120度的范围内。 锂二次电池通过并入该负极而形成。 版权所有(C)2007,JPO&INPIT
    • 34. 发明专利
    • Negative electrode for battery and battery using this
    • 使用此电池和电池的负极
    • JP2006120337A
    • 2006-05-11
    • JP2004304089
    • 2004-10-19
    • Matsushita Electric Ind Co Ltd松下電器産業株式会社
    • UGAJI MASAYAMINO TATSUJISHIBANO YASUYUKIITO SHUJI
    • H01M4/02H01M4/134H01M4/40H01M4/62H01M10/05
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To solve problems that the ionic conductivity of an inorganic compound is deteriorated by minute moisture left without being removed in an electrolyte to decrease the cycle characteristics of a battery in the battery constituted of a negative electrode formed by depositing an ion conductivity inorganic compound layer on a conductor substrate for deposition, a positive electrode, and the electrolyte interposed between the inorganic compound layer and the positive electrode, and depositing lithium on the conductor substrate for deposition by charging. SOLUTION: The inorganic compound layer is formed with a material represented by general formula L x PT y O z or L x MO y N z which is an inorganic compound having ionic conductivity and stable in a wet environment. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了解决无机化合物的离子导电性由于在电解质中残留的微小水分而劣化的问题,以降低由通过沉积形成的负极构成的电池中的电池的循环特性 在用于沉积的导体基板上的离子传导性无机化合物层,正电极和介于无机化合物层和正电极之间的电解质,并且通过充电在所述导体基板上沉积锂以进行沉积。 解决方案:无机化合物层由通式L表示的材料形成,或者是<! - SIPO Z Z 。 版权所有(C)2006,JPO&NCIPI
    • 35. 发明专利
    • Negative electrode for battery and battery using this
    • 使用此电池和电池的负极
    • JP2006100083A
    • 2006-04-13
    • JP2004283846
    • 2004-09-29
    • Matsushita Electric Ind Co Ltd松下電器産業株式会社
    • UGAJI MASAYAMINO TATSUJISHIBANO YASUYUKIITO SHUJI
    • H01M4/02H01M4/134H01M4/40H01M4/62H01M10/05
    • Y02E60/122
    • PROBLEM TO BE SOLVED: To solve problems that for suppressing deterioration in a lithium metal battery, technology forming a pretreatment layer and a protection layer such as lithium phosphate or LIPON (lithium phosphorus oxynitride) on the surface of a lithium negative electrode is well known, but the protection layer is deteriorated when exposed to wet environment such as an electrolyte solution containing trace moisture, and characteristics are decreased during use.
      SOLUTION: The protection layer comprising Li
      x PT
      y O
      z (T is at least one element selected from the element group comprising Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Nb, Mo, Ru, Ag, Ta, W, Pt, and Au) or Li
      x MO
      y N
      z (M is at least one element selected from the element group comprising Si, B, Ge, Al, C, Ga, and S) is formed on the pretreatment layer 2 formed on lithium metal 1, to improve cycle characteristics and increase energy density.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决的问题为了解决锂离子电池的劣化的问题,在锂负极的表面上形成预处理层和形成预处理层的技术和诸如磷酸锂或LIPON(锂磷氮氧化物)的保护层的技术是 但是当暴露于潮湿的环境例如含有微量水分的电解质溶液时,保护层劣化,并且在使用过程中特性降低。

      解决方案:包含LiS保护层的保护层(T是选自包含Ti的元素组中的至少一种元素 ,V,Cr,Mn,Fe,Co,Ni,Cu,Zr,Nb,Mo,Ru,Ag,Ta,W,Pt和Au)或Li x SB < 在形成于锂的预处理层2上形成(M为选自包含Si,B,Ge,Al,C,Ga和S的元素组中的至少一种元素) 金属1,提高循环特性,增加能量密度。 版权所有(C)2006,JPO&NCIPI

    • 37. 发明专利
    • Solid battery
    • JP2004303718A
    • 2004-10-28
    • JP2004041657
    • 2004-02-18
    • Matsushita Electric Ind Co Ltd松下電器産業株式会社
    • MINO TATSUJIISHII HIRONORI
    • H01M2/30H01M10/0562H01M10/058H01M10/38
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a solid battery capable of eliminating the need for considering the thickness of a protection layer because it does not affect on the total thickness of the battery, preventing a protection layer from generating crack, and assuring reliability even if wiring is done freely on the protection layer.
      SOLUTION: The solid battery comprises a substrate 11, a lower collecting body layer 12 sequentially laminated on the substrate, a lower electrode layer 13, an electrolyte layer 14, a power generating element having an upper electrode layer 15 and an upper collecting body layer, and the protection layer 17 for covering at least side surfaces of the power generating element. At least a portion of the protection layer has a smooth surface without steps, extending from the upper part covering the side surface of the upper collecting body layer toward the skirt part abutting the substrate. An angle of θ formed by the surface of the substrate and a shortest slant line connecting a point of the edge of the upper collecting body layer abutting the portion having a smooth surface and a point on the circumference of the contact surface of the substrate and the protection layer is 70° or less.
      COPYRIGHT: (C)2005,JPO&NCIPI