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    • 25. 发明专利
    • Combustion control
    • 燃烧控制
    • JPS6189414A
    • 1986-05-07
    • JP21095884
    • 1984-10-08
    • Fuigaro Giken Kk
    • MURAKAMI NOBUAKIITO MUNEHIRO
    • F23N5/24G01N27/12
    • G01N27/12
    • PURPOSE:To increase adaptability of a gas sensor to the change in the type of a burner, in the temperature, and to the change in the heating power of a burner, by expanding the range of operating temperature for a gas sensor. CONSTITUTION:A gas sensor 2 is constituted by providing electrodes 22 and 24 of below several mum thick on an insulated printed circuit board 20, and by providing a gas sensor region 10 of about 50mum thick, a gas sensor region 12 of about 300mum thick, and a gas sensor region 14 of which thickness is about 1mm on the printed circuit board so as to cover the electrodes 22 and 24: 0.5 weight quantity of Pd per 100 weight quantity in metal equivalent can be added to SnO2 in the region 12 of the same composition, or 2.0 weight quantity of Pd is to be added to the region 18 of the same composition. With such an arrangement, the range of operating temperature for a gas sensor can be expanded, and adaptability of a gas sensor to the change in the type of a burner, in the temperature, and to the change in the heating power of a burner can be increased.
    • 目的:通过扩大气体传感器的工作温度范围,增加气体传感器对燃烧器类型,温度和燃烧器加热功率变化的适应性。 构成:气体传感器2通过在绝缘印刷电路板20上设置几个厚度的几个厚度的电极22和24,并且通过提供约50μm厚的气体传感器区域10,大约300μm厚的气体传感器区域12, 以及在印刷电路板上厚度为约1mm的气体传感器区域14,以覆盖电极22和24:可以在金属当量的每个100重量的量的0.5重量的Pd中添加0.5重量的金属当量的SnO 2 相同的组成或2.0重量的Pd被加入到相同组成的区域18中。 通过这样的布置,可以扩大气体传感器的工作温度范围,气体传感器对燃烧器类型的变化,温度的变化以及燃烧器的加热功率变化的适应性 增加。
    • 26. 发明专利
    • Gaseous component detector
    • 气体元件检测器
    • JPS59212760A
    • 1984-12-01
    • JP8878883
    • 1983-05-19
    • Fuigaro Giken Kk
    • ODA KOUICHI
    • G01N29/02G01N29/024G01N29/036G01N29/00
    • G01N29/036G01N29/024G01N2291/02809G01N2291/02881G01N2291/0289
    • PURPOSE:To detect exactly a gaseous component in accordance with the antiresonance compensated of a temp. fluctuation by changing an oscillation frequency according to temp. and eliminating the influence of the temp. on the antiresonance. CONSTITUTION:An oscillating body 8 of a resonance vessel 4 of a Helmholtz type is driven by the oscillation frequency corresponding to the antiresonance frequency having temp. dependency according to the temp. by an oscillating circuit such as free running multivibrator or the like using a thermistor, etc. If the position of an interferring body 10 is adjusted in such a way that the acoustic wave through a sound releasing hole 6 by said driving is antiresonated and the sound is thus eliminated, a gaseous component is exactly detected in accordance with the antiresonance compensated of a temp. fluctuation.
    • 目的:根据温度补偿的反共振,精确检测气体成分。 根据温度改变振荡频率的波动 消除温室的影响。 在反共振。 构成:亥姆霍兹型谐振容器4的振荡体8由对应于具有温度的反谐振频率的振荡频率驱动。 依赖温度 通过诸如使用热敏电阻等的自由运行的多谐振荡器等的振荡电路等。如果干扰体10的位置被调整为使得通过所述驱动的通过声音释放孔6的声波被反谐振并且声音 因此,根据对温度补偿的反谐振,精确地检测气体成分。 波动。
    • 27. 发明专利
    • Detection of gas
    • 检测气体
    • JPS59160752A
    • 1984-09-11
    • JP3620683
    • 1983-03-04
    • Fuigaro Giken Kk
    • ODA KOUICHI
    • G01H3/00G01N29/036
    • G01N29/036
    • PURPOSE:To enable effective detection of gas by utilizing the antiresonance phenomenon generated by a resonance vessel of a Helmholtz type and an interference body of sound. CONSTITUTION:A Helmholtz type resonance vessel 2 has a sound releasing hole 4, and is provided internally with a piezoelectric type oscillator 6. An interference body 12 such as a metallic plate which reflects acoustic waves is provided above the hole 4 at the distance at which antiresonance is most sharply generated in air. If there is no gas, the oscillation ceases entirely and the sound pressure from the vessel 2 is below the ambient noise level and is not detectable. When gas is generated, the oscillator 6 oscillates and the generation of the gas is announced by the sound itself. The sound pressure increases with an increase in the concn. of the gas. The oscillating state is also detected from the circuit current in the oscillating circuit which drives the oscillator 6. A sound absorbing material layer 16 and a silica gel filter 18 for preventing condensation are attached in a case 14.
    • 目的:通过利用亥姆霍兹型共振容器和声音干扰体产生的反共振现象,有效地检测气体。 构成:亥姆霍兹型共振容器2具有释放孔4,并且内部设置有压电振荡器6.反射声波的金属板等干涉体12设置在孔4的上方,距离为 反共振在空气中最为剧烈地产生。 如果没有气体,则振荡完全停止,并且来自容器2的声压低于环境噪声水平,并且不可检测。 当产生气体时,振荡器6振荡并且声音本身宣布产生气体。 声压随着浓度的增加而增加。 的气体。 振荡状态也可以从驱动振荡器6的振荡电路中的电路电流中检测出来。在壳体14中安装有用于防止冷凝的吸声材料层16和硅胶过滤器18。
    • 28. 发明专利
    • Gas detection element
    • 气体检测元件
    • JPS5926044A
    • 1984-02-10
    • JP13607182
    • 1982-08-04
    • Fuigaro Giken Kk
    • TANAKA KATSUYUKI
    • G01N27/12
    • G01N27/12
    • PURPOSE:To eliminate thermal stress between a substrate and a gas sensing part made of a gas-sensitive metal oxide semiconductor, by constituting an heat- resistant insulating cylinder using a sintered material contg. said semiconductor and a contracting agent. CONSTITUTION:The gas sensing part 2 made of SnO2 is formed in the hollow of the substrate of a heat-resistant insulating cylinder 1 prepd. by adding 0.5pt. (by weight basis) CuO as a contracting agent to 10pts. of a gas-sensitive metal oxide of SnO2. Electrodes 3, 4 prepd. by adding 25pts. Pt to 100pts. are formed on the cylinder 1. 0.5pt of the CuO contracting agent is added onto the electrodes 3, 4 only to the depth same as that of the cylinder 1 to improve contact between the part 2 and the electrodes 3, 4. A heater 4 prepd by adding 0.5pt. CuO and 15pts. Pt to SnO2 is formed on the surface of the cylinder 1, and insulated from the part 2. The electrodes 3, 4 and the heater 5 are connected to lead wires 6, 7, and 8, 9, respectively, thus eliminating thermal stress between the substrate 1 and the part 2.
    • 目的:通过构成使用烧结材料的耐热绝缘筒,消除由气敏金属氧化物半导体制成的基板和气体检测部之间的热应力。 半导体和承包商说。 构成:由耐热绝缘筒1的基材的中空部形成由SnO 2构成的气体检测部2。 加0.5pt。 (以重量计)CuO作为收缩剂至10pts。 的SnO2气敏金属氧化物。 电极3,4制备 加25pts。 到100pts。 形成在圆筒1上。将0.5pt的CuO收缩剂添加到电极3,4上,仅与圆筒1的深度相同,以改善部分2和电极3,4之间的接触。加热器4 准备加0.5pt。 CuO和15pts。 在气缸1的表面上形成Pt至SnO 2,并与部件2绝缘。电极3,4和加热器5分别连接到引线6,7和8,9,从而消除了 基板1和部分2。
    • 29. 发明专利
    • Gas detection element
    • 气体检测元件
    • JPS5926043A
    • 1984-02-10
    • JP13607082
    • 1982-08-04
    • Fuigaro Giken Kk
    • TANAKA KATSUYUKI
    • G01N27/12
    • G01N27/12
    • PURPOSE:To eliminate thermal stress between a gas sensing part made of a gas sensitive semiconductor and a substrate, by using the substrate made of a gas sensitive metallic oxide semiconductor and the oxide of one of prescribed elements as a contracting material for the substrate. CONSTITUTION:The substrate 1 is formed by adding one of oxides of Ti, Zr, Si, Ge, V, Nb, Ta, W, Mo, and Hf as a contracting material to one of the gas sensitive metallic oxide semiconductors of SnO2, TiO2, In2O3, and ZnO, e.g. 10pts.wt. to 100pts.wt. SnO2, and heat treating them at 1,250 deg.C. A heater 2 made to an Fe- Cr alloy wire coil is buried in the central part of the substrate 1, electrodes 3, 4 prepd. by adding 10pts.wt. TiO2 and 30pts.wt. Pt to said SnO2 are formed on the circumference of the substrate 1. The gas sensing part 7 prepd. by adding 0.3pt.wt. Pd to SnO2 is formed on the surface of the substrate 1, thus eliminating thermal stress between the substrate 1 and the part 7.
    • 目的:通过使用由气敏金属氧化物半导体制成的基板和规定要素之一的氧化物作为基板的收缩材料,消除由气体敏感半导体构成的气体检测部件与基板之间的热应力。 构成:通过将Ti,Zr,Si,Ge,V,Nb,Ta,W,Mo和Hf的氧化物之一作为收缩材料添加到SnO 2,TiO 2的气敏金属氧化物半导体之一中而形成基板1 ,In2O3和ZnO,例如 10pts.wt。 至100pts.wt SnO2,并在1,250℃热处理。 对Fe-Cr合金线圈制成的加热器2埋设在基板1的中心部分,电极3,4准备好。 加入10pts.wt。 TiO2和30pts.wt。 在基板1的圆周上形成有对所述SnO 2的Pt。 加0.3pt.wt. 在基板1的表面上形成Pd至SnO 2,从而消除了基板1和部件7之间的热应力。
    • 30. 发明专利
    • Addition of reaction promotor to combustion state detecting element
    • 反应促进剂添加到燃烧状态检测元件
    • JPS58180940A
    • 1983-10-22
    • JP6421382
    • 1982-04-17
    • Fuigaro Giken Kk
    • MURAKAMI NOBUAKITANAKA KATSUYUKIIOKURA HIRONORI
    • G01N27/12
    • G01N27/12
    • PURPOSE:To enhance low temp. activity and the responsive characteristics in the detection of an air/fuel ratio at high temp., by a method wherein a transition metal, a noble metal or a compound thereof is added to an SnO2 and the resulting mixture is baked to reduce the surface area of SnO2 within a specific % range. CONSTITUTION:Transition metal oxide, a noble metal or a noble metal compound is added to SnO2 with a surface area of 1.0-1.5m /g and an average crystal size of 400- 2,000Angstrom obtained under a specific baking condition as a reaction promotor and the resulting mixture is baked to reduce 20-70% of the surface area to obtain a gas sensor with a surface area of 1-5m /g and an average crystal size of 3,200-800Angstrom . For examle, Rh or Rh-chloride is added to SnO2 in an amount of 0.3-5pts.wt. as metal Rh to 100pts.wt. SnO2 as a reaction promotor. The addition amount of Pt may be similarily adjusted to 0.3-5pts.wt. while that of Ru to 0.4-9pts.wt. By the addition of the reaction promortor, low temp. activity is enhanced while, by reducing the surface area in a specific %, responsive characteristics in the detection of an air/fuel ratio at a high temp. is enhanced and, therefor, a combustion state detecting element having high sensitivity over a wide range of temp. is obtained.
    • 目的:提高低温 活性和在高温下检测空气/燃料比的响应特性,通过其中向SnO 2中加入过渡金属,贵金属或其化合物的方法,并将所得混合物烘烤以降低表面积 的SnO2在特定的%范围内。 构成:在特定的烘烤条件下得到的表面积为1.0-1.5m 2 / g,平均晶体尺寸为400〜2000埃的SnO 2中添加过渡金属氧化物,贵金属或贵金属化合物作为 反应促进剂,并将所得混合物烘烤以减少20-70%的表面积,得到表面积为1-5m 2 / g,平均晶体尺寸为3,200-800埃的气体传感器。 例如,将Rh或Rh-氯化物以0.3-5pts.wt的量添加到SnO 2中。 作为金属Rh至100pts.wt。 SnO2作为反应促进剂。 Pt的添加量可以相似地调整为0.3-5pts.wt。 而Ru为0.4-9pts.wt。 通过加入反应促进者,低温。 活性增强,而通过在高温下检测空气/燃料比来减小特定%的响应特性的表面积。 因此,在宽范围的温度下具有高灵敏度的燃烧状态检测元件。 获得。