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    • 22. 发明专利
    • METHOD FOR FORMING SILICON OXIDE FILM
    • JPH09251997A
    • 1997-09-22
    • JP6097296
    • 1996-03-18
    • TOSHIBA CORP
    • NARA AKIKOITO HITOSHI
    • H01L21/31C23C16/40H01L21/316
    • PROBLEM TO BE SOLVED: To reduce a remaining functional base which is a deterioration cause of film quality without giving an adverse influence to an underlayer, by a method wherein a substance which selectively acts on an organic functional base included in a silicon oxide film is added to material gas composed of oxygen source gas and organic system silane gas so that a silicon oxide film is formed on a substrate by a CVD method. SOLUTION: By use of oxygen source gas and organic system silane gas as material gas, a substance which selectively acts on an organic functional base included in a silicon oxide film is further added thereto so that silicon oxide film is formed on a substrate 104 by a CVD method. For this reason, a substrate support pedestal 103 for supporting the substrate 104 such as a silicon substrate etc., is provided in a vacuum bath 101, and the vacuum bath 101 is connected to a pipe 105 for supplying oxygen source gas, a pipe 115 for flowing tetramethylsilane as organic system silane, a pipe 125 for flowing toluene as an additive substance for improving film quality and a pipe 130 for flowing nitrogen gas.
    • 23. 发明专利
    • SEMICONDUCTOR DEVICE AND ITS MANUFACTURE
    • JPH09237785A
    • 1997-09-09
    • JP6883096
    • 1996-03-25
    • TOSHIBA CORP
    • ITO HITOSHINARA AKIKONAGAMINE MAKOTO
    • H01L21/31H01L21/316H01L21/768H01L23/29H01L23/522H01L23/532
    • PROBLEM TO BE SOLVED: To obtain an insulating film which can be buried into a fine region so as to be in a good shape by a method wherein the insulating film which is composed of the compound of silicon, oxygen, carbon and hydrogen and in which the content of carbon is larger than the content of silicon is used for at least one of a layer insulating film and a protective insulating film. SOLUTION: An insulating film which is composed of the compound of silicon, oxygen, carbon and hydrogen and in which the content of carbon is larger than the content of silicon is used for at least one of a layer insulating film and a protective insulating film, and a semiconductor device is obtained. Then, the insulating film is viscous at room temperature, its viscosity is at 100cps or higher and 300000cps or lower, or its relative permittivity is at 1.8 or higher and 3.2 or lower. In addition, the insulating film a structure of - Si(R1 )2 -O-Si(R1 )2 -O-}n as a main chain, and R1 is Cn H2n+1 (where n represents a positive integer). Therefore, it is possible to obtain the semiconductor device comprising the insulating film whose buried shape is good, whose permittivity is low and whose hygoscopicity is low.
    • 24. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPH0936323A
    • 1997-02-07
    • JP18714895
    • 1995-07-24
    • TOSHIBA CORP
    • TAKAHASHI SHINYAITO HITOSHI
    • H01L21/76H01L21/225H01L21/822H01L21/8242H01L27/04H01L27/108
    • PROBLEM TO BE SOLVED: To restrain the etching of an element isolation oxide film or the like, and improve element characteristics, by eliminating an insulating film containing impurities by using heated hydrogen fluoride water vapor. SOLUTION: An element isolation oxide film 11, and a thermal oxidation layer 2 and a nitride film 3 which are used as etching protection films when a trench is formed are formed on a substrate 1. The trench has an aperture in the boundary part between the element isolation oxide film 11 and the oxide film 2 on an element region. A PSG film 6 of an SiO2 film containing phosphorus is deposited. Resist is spread on the PSG film 6, and exposure is performed without interposing a pattern mask. Resist having a specified depth is left in the trench, and the exposed part of the PSG film 6 is eliminated. After the resist is eliminated, an oxide film 8 is formed. By the heat treatment in an N2 atmospher, phosphorus is diffused in the substrate 1 from the PSG film 6 left in the trench, and a diffusion layer 9 is formed. Further by V-HF treatment, the PSG film is eliminated, and a desired impurity diffusion layer 9 is formed on the inner wall of the trench.
    • 26. 发明专利
    • JPH05291148A
    • 1993-11-05
    • JP8696192
    • 1992-04-08
    • TOSHIBA CORP
    • ENDO TAKAYUKIKAJI SHIGEHIKONAKADA RENPEIITO HITOSHI
    • H01L21/205H01L21/68H01L21/683
    • PURPOSE:To enable the title semiconductor substrate to be heated satisfactorily by a method wherein a base substance is provided with an electrode body generating static electricity by power supply for pressing the semiconductor substrate against the base substance, a through hole and a trench leading-in a heating gas. CONSTITUTION:A quartz susceptor 6 is arranged on the bottom part of a reaction chamber 3 while a heater 10 as the base substance for mounting a semiconductor substrate 7 is provided on the susceptor 6. The heater 10 as the base substance is composed of a tungsten wire 8 as a heater for heating the semiconductor substrate 7 as well as an electrode 9 attracting the substrate 7 by electrostatic force while the periphery of the heater 10 is covered with alumina. On the other hand, a trench 12 for leading-in an inert gas via a through hole 11 is provided on the surface part of the heater 10. The through hole 11 is connected to an inert gas leading-in part. That is, the semiconductor substrate 7 is to be heated by heat conduction, radiation and convection when it is heated using the heater 10 and the inert gas.