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    • 22. 发明专利
    • High strength steel having excellent delayed fracture resistance, high strength bolt, and method for producing the same
    • 具有优异延长耐断裂性,高强度螺栓的高强度钢及其制造方法
    • JP2009299180A
    • 2009-12-24
    • JP2009061544
    • 2009-03-13
    • Nippon Steel Corp新日本製鐵株式会社
    • HIRAGAMI DAISUKESENDA TETSUSHITARUI TOSHIZO
    • C22C38/00C21D1/06C21D8/06C21D9/00C22C38/58F16B35/00
    • PROBLEM TO BE SOLVED: To provide a high strength steel having excellent delayed fracture resistance even in an environment where corrosion is severe, and to provide a method for producing the high strength steel.
      SOLUTION: The high strength steel having excellent delayed fracture resistance is characterized in that the depth of a nitrided layer in the surface is ≥200 μm. Particularly, in the case the compressive residual quantity of the surface is ≥200 MPa, its delayed fracture resistance improves. The steel comprises proper amounts of C, Si and Mn, comprises one or two kinds selected from V and Mo, also satisfies the relation of V+Mo/2>0.4%, and further comprises one or more kinds selected from Cr, Nb, Cu, Ni and B. By increasing the nitrogen concentration by ≥0.02% than the average nitrogen concentration to a depth of at least ≥200 μm from the surface of the steel, the intrusion of diffusible hydrogen is remarkably suppressed, and its delayed fracture resistance improves. Further, since the carbides, nitrides and carbonitrides of V and Mo are finely precipitated, intruded diffusible hydrogen is made harmless, so as to increase a limit diffusible hydrogen content.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:即使在腐蚀严重的环境中也提供具有优异的延迟断裂性的高强度钢,并且提供一种高强度钢的制造方法。 解决方案:具有优异的耐延迟断裂性的高强度钢的特征在于,表面中的氮化层的深度≥200μm。 特别地,在表面的压缩残留量≥200MPa的情况下,其延迟断裂阻力提高。 该钢包含适量的C,Si和Mn,包括选自V和Mo中的一种或两种,也满足V + Mo / 2> 0.4%的关系,并且还包括选自Cr,Nb, Cu,Ni和B.通过从钢表面将氮浓度比平均氮浓度提高至至少≥200μm深度的≥0.02%,可扩散氢的侵入被显着抑制,并且其延迟的抗断裂性 改善 此外,由于V和Mo的碳化物,氮化物和碳氮化物被精细地沉淀,所以侵入的扩散氢变得无害,从而增加极限扩散的氢含量。 版权所有(C)2010,JPO&INPIT
    • 24. 发明专利
    • High strength bolt having excellent delayed fracture resistance and method for improving its delayed fracture resistance
    • 具有优异延迟耐断裂性的高强度螺栓及其延迟抗断裂性的方法
    • JP2006131990A
    • 2006-05-25
    • JP2005246973
    • 2005-08-29
    • Nippon Steel Corp新日本製鐵株式会社
    • TARUI TOSHIZOFUJITA TAKASHIYOSHIDA TAKUSENDA TETSUSHI
    • C22C38/00C21D7/06C21D9/00C22C38/14C22C38/58F16B31/06F16B35/00
    • Y02P10/212
    • PROBLEM TO BE SOLVED: To provide a high strength bolt having satisfactory delayed fracture resistance, and having a strength of ≥1,500 MPa, and to provide a method for improving its delayed fracture resistance. SOLUTION: The high strength bolt having excellent delayed fracture resistance is composed of a steel having a composition comprising, by mass, 0.3 to 0.6% C, 0.05 to 2% Si, 0.1 to 2% Mn, 0.002 to 0.1% Al and 1 to 3% Mo, and further comprising one or more kinds of metals selected from 0.05 to 1% V, 0.01 to 1% Ti and 0.01 to 1% Nb, and the balance Fe with inevitable impurities, and in which the mass% ratio of the C also satisfies the inequality (A) 0.2≤(0.06Mo+0.18V+0.25Ti+0.13Nb)/C, and having a tensile strength of ≥1,500 MPa. The compressive residual stress of the surface layer in the under head part of the bolt is 20 to 90% the tensile strength of the steel. Further, the invention relates to a method for improving its delayed fracture resistance. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供具有令人满意的耐延迟断裂性并且具有≥1,500MPa的强度的高强度螺栓,并且提供一种提高其延迟抗断裂性的方法。 解决方案:具有优异的耐延迟断裂性的高强度螺栓由具有以质量计含有0.3-0.6%C,0.05-2%Si,0.1-2%Mn,0.002-0.1%Al 和1〜3%的Mo,还含有选自0.05〜1%V,0.01〜1%Ti,0.01〜1%Nb,余量为Fe和不可避免的杂质的一种或多种金属,其中质量% C的比例也满足不等式(A)0.2≤(0.06Mo + 0.18V + 0.25Ti + 0.13Nb)/℃,拉伸强度≥1,500MPa。 螺栓下头部表面层的压缩残余应力为钢的拉伸强度的20〜90%。 此外,本发明涉及一种提高其耐断裂性的方法。 版权所有(C)2006,JPO&NCIPI
    • 27. 发明专利
    • High strength pc steel bar having excellent hydrogen embrittlement resistance and production method therefor
    • 高强度PC钢棒具有优异的耐腐蚀性及其生产方法
    • JP2005298916A
    • 2005-10-27
    • JP2004117892
    • 2004-04-13
    • Nippon Steel Corp新日本製鐵株式会社
    • TARUI TOSHIZOFUJITA TAKASHIHIRANO KOJI
    • B23K26/00B23K103/04C21D1/09C22C38/00C22C38/06C22C38/58
    • Y02P10/212
    • PROBLEM TO BE SOLVED: To provide a high strength PC (prestressed concrete) steel bar having satisfactory hydrogen fatigue resistance and delayed fracture resistance which has satisfactory strength of ≥1,450 MPa. SOLUTION: The steel bar has a composition comprising, by mass, 0.2 to 0.6% C, 0.05 to 3% Si, 0.3 to 2% Mn and 0.002 to 0.1% Al, and, when necessary, comprising one or more kinds of metals selected from 0.05 to 3% Ni, 0.05 to 2% Cr, 0.05 to 2% Mo, 0.02 to 1% V, 0.005 to 0.1% Nb, 0.003 to 0.1% Ti and 0.003 to 0005% B, and the balance Fe with inevitable impurities. Its tensile strength is ≥1,450 MPa, and the residual stress of the surface layer is -100 to -1,200 MPa. In the production method therefor, a PC steel bar is subjected to quenching-tempering treatment, and is thereafter immersed into a liquid, or a liquid film is formed on the steel surface, and laser irradiation in the injection heating value of ≥0.3 J/mm 2 is carried out with a laser having a peak power density of 0.1 to 10 GW/cm 2 . COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供具有令人满意的耐氢疲劳性和延迟抗断裂性的高强度PC(预应力混凝土)钢筋,其具有令人满意的强度≥1,450MPa。 解决方案:钢棒具有以质量计包含0.2-0.6%C,0.05-3%Si,0.3-2%Mn和0.002-0.1%Al的组合物,并且根据需要包含一种或多种 的金属,选自0.05〜3%的Ni,0.05〜2%的Cr,0.05〜2%的Mo,0.02〜1%的V,0.005〜0.1%的Nb,0.003〜0.1%的Ti和0.003〜0005%的B, 有不可避免的杂质。 其拉伸强度≥1,450MPa,表面层的残余应力为-100〜-1200MPa。 在其制造方法中,对PC钢棒进行淬火回火处理,然后浸入液体中,或者在钢表面上形成液膜,并且注射热值的激光照射≥0.3J/ 使用峰值功率密度为0.1〜10GW / cm 2的激光进行mm 2 。 版权所有(C)2006,JPO&NCIPI
    • 29. 发明专利
    • Steel for high strength spring, excellent in hydrogen embrittlement resistance
    • 用于高强度弹簧的钢,具有优异的耐腐蚀性
    • JP2012172247A
    • 2012-09-10
    • JP2011038250
    • 2011-02-24
    • Nippon Steel Corp新日本製鐵株式会社
    • TARUI TOSHIZOSAKAMOTO AKIRAHIRAGAMI DAISUKESENDA TETSUSHI
    • C22C38/00C22C38/24C22C38/54
    • PROBLEM TO BE SOLVED: To provide a steel for a high strength spring, high in strength and excellent in hydrogen embrittlement resistance capable of obtaining excellent delayed fracture resistance and corrosion fatigue fracture resistance.SOLUTION: The steel for a high strength spring, excellent in hydrogen embrittlement resistance includes, by mass%, 0.40-0.65% of C, 1.8-3.0% of Si, 0.1-0.5% of Mn, 0.010% or less of P, 0.015% or less of S, 0.5% or less of Cr and 0.01-0.5% of V, with the remainder being Fe and inevitable impurities. In the steel for a high strength spring, a ratio of a maximum concentration of Mn to a minimum concentration of Mn in a region from a surface to a depth of 1 mm is 1.5 or less, and an amount of non-diffusible hydrogen is less than 0.3 ppm.
    • 要解决的问题:提供一种用于高强度弹簧的钢,强度高,耐氢脆性优异,能够获得优异的延迟断裂性和耐腐蚀疲劳抗断裂性。 解决方案:耐氢脆性优良的高强度弹簧用钢,以质量%计含有C:0.40〜6.65%,Si:1.8〜3.0%,Mn:0.1-0.5%,Mn:0.010%以下 P,0.015%以下的S,0.5%以下的Cr和0.01-0.5%的V,余量为Fe和不可避免的杂质。 在高强度弹簧用钢中,从表面到深度1mm的区域中,Mn的最大浓度与Mn的最小浓度的比例为1.5以下,非扩散性氢的量少 大于0.3ppm。 版权所有(C)2012,JPO&INPIT
    • 30. 发明专利
    • Ultrasonic impact processing apparatus for coil spring and method of ultrasonic impact processing for coil spring
    • 用于线圈弹簧的超声冲击加工装置和用于线圈弹簧的超声冲击加工方法
    • JP2012117119A
    • 2012-06-21
    • JP2010268580
    • 2010-12-01
    • Nippon Steel Corp新日本製鐵株式会社
    • FUJITA TAKASHITARUI TOSHIZONARUMIYA HIROKI
    • C21D7/06C21D1/04
    • PROBLEM TO BE SOLVED: To provide a method of ultrasonic impact processing for a coil spring, reducing processing time while uniformly applying compressive residual stress on an inner circumferential surface of a coil spring and capable of achieving improvement in fatigue characteristics of the coil spring.SOLUTION: In the method of ultrasonic impact processing for a coil spring, a rod-like impact tool 2, which is constituted such that an outer circumferential surface 2a thereof is brought into contact with an inner circumferential surface 4b of a coil spring 4 or the outer circumferential surface 2a is separated from the coil inner circumferential surface 4b with a gap therebetween, is inserted into an coil inside 4a of the coil spring 4, and ultrasonic vibration is applied to the impact tool 2 so that the entire surface of the coil inner circumferential surface 4b is impacted by the outer circumferential surface 2a.
    • 要解决的问题:为了提供一种用于螺旋弹簧的超声波冲击处理方法,减少了在螺旋弹簧的内周面上均匀地施加压缩残余应力并且能够实现线圈的疲劳特性的改善的加工时间 弹簧。 解决方案:在螺旋弹簧的超声波冲击加工方法中,杆状冲击工具2构成为使其外周面2a与螺旋弹簧的内周面4b接触 4或外周面2a与线圈内周面4b间隔开的状态被插入到螺旋弹簧4的内部的线圈4a内,超声波振动被施加到冲击工具2的整个表面 线圈内周面4b受到外周面2a的冲击。 版权所有(C)2012,JPO&INPIT