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    • 21. 发明专利
    • Liquid detergent composition
    • 液体洗涤剂组合物
    • JP2008056720A
    • 2008-03-13
    • JP2006231676
    • 2006-08-29
    • Kao Corp花王株式会社
    • TASE YUICHIROMAKI MASATAKAISHIZUKA HITOSHIYAMAGUCHI YUKIYOSHI
    • C11D3/39C11D1/72C11D1/722C11D3/02C11D3/20C11D3/395C11D17/08D06L3/02
    • PROBLEM TO BE SOLVED: To provide a liquid detergent composition which, before being diluted with water, lies in a low pH region where the constituent bleach base can be kept stable and which, after being diluted with water, reaches a high pH region where the composition can exhibit bleaching effect and detergency by virtue of the bleach base.
      SOLUTION: The liquid detergent composition comprises the following components (a) to (c): (a) hydrogen peroxide or a compound which forms hydrogen peroxide in water, (b) germanium or a compound containing germanium, and (c) a compound having at least one site where each of two vicinal carbon atoms has one hydroxy group.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种液体洗涤剂组合物,其在用水稀释之前位于低pH区域,其中组分漂白碱可以保持稳定,并且在用水稀释后达到高pH 其中组合物可以通过漂白基质显示出漂白效果和去污力。 液体洗涤剂组合物包含以下组分(a)至(c):(a)过氧化氢或在水中形成过氧化氢的化合物,(b)锗或含锗化合物,和(c) 具有至少一个位置的化合物,其中两个邻位碳原子中的每一个具有一个羟基。 版权所有(C)2008,JPO&INPIT
    • 23. 发明专利
    • Liquid detergent composition
    • 液体洗涤剂组合物
    • JP2007308592A
    • 2007-11-29
    • JP2006138947
    • 2006-05-18
    • Kao Corp花王株式会社
    • MAKI MASATAKAISHIZUKA HITOSHITASE YUICHIROYAMAGUCHI YUKIYOSHI
    • C11D3/20C11D1/72C11D3/04C11D3/39C11D3/395C11D3/43C11D17/08D06L1/12D06L3/02
    • PROBLEM TO BE SOLVED: To obtain a liquid detergent composition having a high cleaning effect on persistent stain derived from sebum and protein, attached to collar and socks and to provide a cleaning method using the same. SOLUTION: The liquid detergent composition comprises (a) an organic solvent, (b) a polyoxyalkylene alkyl ether type nonionic surfactant containing an oxyethylene group and/or an oxypropylene group, (c) at least one kind of a compound selected from boric acid, borax and a borate, (d) a polyol compound containing three or more hydroxy groups and (e) water and has 45-80 mass% of the total contents of the component (a) and the component (b) in the composition, the mixing ratio of the component (a) and the component (b) of (b)/(a) (mass ratio) of 1/50-50/1 and pH 3-7 at 20°C. The method for cleaning clothes comprises a process for bringing a stock solution of the liquid detergent composition into contact with stains adhered to the clothes. COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:获得一种附着到衣领和袜子上的对由皮脂和蛋白质产生的持久性污渍具有高清洁效果的液体洗涤剂组合物,并提供使用该洗涤剂组合物的清洁方法。 溶液:液体洗涤剂组合物包含(a)有机溶剂,(b)含有氧化乙烯基和/或氧化亚丙基的聚氧化烯烷基醚型非离子表面活性剂,(c)至少一种选自 硼酸,硼砂和硼酸盐,(d)含有三个或更多个羟基的多元醇化合物和(e)水,并且其中组分(a)和组分(b)的总含量为45-80质量% 组成(a)和(b)成分(b)(a)(质量比)的混合比为1/50〜50/1,pH为3-7。 用于清洁衣物的方法包括使液体洗涤剂组合物的原液与附着在衣物上的污渍接触的方法。 版权所有(C)2008,JPO&INPIT
    • 24. 发明专利
    • Liquid bleaching agent composition
    • 液体漂白剂组合物
    • JP2007106904A
    • 2007-04-26
    • JP2005299643
    • 2005-10-14
    • Kao Corp花王株式会社
    • ISHIZUKA HITOSHIMAKI MASATAKATASE YUICHIROYAMAGUCHI YUKIYOSHI
    • C11D3/395C11D1/62C11D1/68C11D1/722C11D3/36C11D17/08D06L3/02
    • PROBLEM TO BE SOLVED: To provide a liquid bleaching agent composition which excels in a bacterium-proofing/mildew-proofing effect, exhibits bleaching/detergency after storage, and does not deteriorate a liquid feeling.
      SOLUTION: The liquid bleaching agent composition comprises a nonionic surface active agent (a), a quaternary ammonium salt (b) represented by formula (1) (wherein one or two of R
      11 to R
      14 are hydrocarbon groups having one phenol group or 8-36C aliphatic hydrocarbon groups and the remaining are 1-5C alkyl groups, and the total carbon number of R
      11 to R
      14 is 19 or more, and X
      - is a halogen ion or a 1-3C alkyl sulfate ion), and the content of the component (a) in the composition is 1-50 mass% and the content of the component (b) is 0.1-10 mass%.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种防细菌防霉效果优异的液体漂白剂组合物,在保存后显示漂白/去污力,不会使液体感觉劣化。 解决方案:液体漂白剂组合物包含非离子表面活性剂(a),由式(1)表示的季铵盐(b)(其中R 11和R 12中的一个或两个 14 是具有一个酚基或8-36C脂族烃基的烃基,剩余的是1-5C烷基,并且R 11的总碳数< SP> 14 为19以上,X - 为卤素离子或1-3C烷基硫酸根离子),组合物(a)的含量为1 -50质量%,成分(b)的含量为0.1〜10质量%。 版权所有(C)2007,JPO&INPIT
    • 25. 发明专利
    • Liquid bleaching detergent composition
    • 液体漂白剂洗涤剂组合物
    • JP2007106903A
    • 2007-04-26
    • JP2005299642
    • 2005-10-14
    • Kao Corp花王株式会社
    • ISHIZUKA HITOSHIMAKI MASATAKATASE YUICHIROYAMAGUCHI YUKIYOSHI
    • C11D3/395C11D1/62C11D1/722C11D3/04C11D3/36C11D17/08D06L3/02
    • PROBLEM TO BE SOLVED: To provide a liquid bleaching detergent composition which has a pH jump effect to the extent satisfying bleaching effect and detergent effect, remarkably improves the storage stability of hydrogen peroxide and a bleaching activator, and further inhibits the odor of the composition after storage.
      SOLUTION: The liquid bleaching detergent composition comprises a nonionic surface active agent (a), a bleaching activator (b), hydrogen peroxide or the like (c), a quaternary ammonium salt (d) represented by formula (1) wherein one or two of R
      11 to R
      14 are hydrocarbon groups having one phenyl group or 8-36C aliphatic hydrocarbon groups and the remaining are 1-5C alkyl groups, and the total carbon number of R
      11 to R
      14 is not less than 19, and X
      - is a halogen ion or a 1-3C alkyl sulfate ion, boric acid, borax or a borate (e), and a compound (f) having at least one site where both of the adjacent carbon atoms have one hydroxyl group, respectively, and the content of the compound (d) in the composition is 0.1-10 mass%, and the molar ratio of the compound (f) to the compound (e) is 1.5-2.7, and the composition has a pH at 20°C of 4.0-7.0.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决问题的方法为了提供具有达到满足漂白效果和洗涤效果的程度的pH跳跃效果的液体漂白洗涤剂组合物,显着提高过氧化氢和漂白活化剂的保存稳定性,进一步抑制 储存后的组成。 液体漂白洗涤剂组合物包含非离子表面活性剂(a),漂白活化剂(b),过氧化氢等(c),由式(1)表示的季铵盐(d),其中 R 14和R 16中的一个或两个是具有一个苯基或8-36C脂族烃基的烃基,剩余的是1-5C烷基,总共 R 11 至R 14的碳数不小于19,X - 是卤素离子或1-3C烷基硫酸根离子 ,硼酸,硼砂或硼酸盐(e)的化合物(e)和具有至少一个相邻碳原子具有一个羟基的位置的化合物(f),组合物中化合物(d)的含量分别为 0.1-10质量%,化合物(f)与化合物(e)的摩尔比为1.5-2.7,组合物的pH在20℃为4.0〜7.0。 版权所有(C)2007,JPO&INPIT
    • 26. 发明专利
    • Liquid bleaching agent article contained in container
    • 集装箱内装有液体漂白剂
    • JP2007039599A
    • 2007-02-15
    • JP2005227369
    • 2005-08-05
    • Kao Corp花王株式会社
    • YAMAGUCHI YUKIYOSHIMAKI MASATAKAISHIZUKA HITOSHINISHIMURA HIROSHI
    • C11D3/395B65D30/02B65D65/40B65D77/00C11D1/72C11D3/36C11D3/39C11D17/04C11D17/08
    • PROBLEM TO BE SOLVED: To provide a liquid bleaching agent article contained in a container that is prevented from breakage of the container caused by an oxygen gas generated by decomposition of hydrogen peroxide. SOLUTION: The liquid bleaching agent article contained in a container comprises a container and, filled therein, a liquid bleaching agent composition that comprises (a) hydrogen peroxide, (b) a nonionic compound represented by general formula (I): Y-(R 2 -O) m -R 3 (wherein Y is H or R 1 -O-; R 1 and R 3 are each H or a 1-20C alkyl group or the like; R 2 is a 2-6C alkylene group; and m is a numerical value of 2-500) and (c) water at a specific ratio, contains 10-50 mass% of equivalents of the surfactant prescribed in JIS K 3362:1998 and has a pH of 4-8 as measured at 20°C according to JIS K 3362:1998, where the container is a bag-like container composed of a composite film base material comprised of at least two laminated layers of plastic films. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供容纳在容器中的液体漂白剂制品,其防止由于过氧化氢分解产生的氧气引起的容器破裂。 包含在容器中的液体漂白剂制品包括容器,并且填充有液体漂白剂组合物,其包含(a)过氧化氢,(b)由通式(I)表示的非离子化合物:Y - (R 2 -O) -R 3其中Y是H或R ; R 1 和R 3 分别为H或1-20C烷基等; R 2 SP 2为2-6C亚烷基 ; m为2-500的数值),(c)特定比例的水含有JIS K 3362:1998中规定的10-50质量%的表面活性剂当量,pH值为4-8 根据JIS K 3362:1998的20℃,其中容器是由至少两层塑料膜组成的复合膜基材组成的袋状容器。 版权所有(C)2007,JPO&INPIT
    • 27. 发明专利
    • Liquid detergent composition
    • 液体洗涤剂组合物
    • JP2006169517A
    • 2006-06-29
    • JP2005333839
    • 2005-11-18
    • Kao Corp花王株式会社
    • ISHIZUKA HITOSHIMAKI MASATAKATASE YUICHIROYAMAGUCHI YUKIYOSHI
    • C11D3/395C11D1/02C11D1/66C11D3/04C11D3/20C11D3/34C11D17/08D06L3/02
    • PROBLEM TO BE SOLVED: To provide a liquid detergent composition having a pH jump effect on a level where a bleaching effect is satisfied, remarkably improved in stability of a bleaching activator, and exhibiting an excellent performance of cleaning sebum and an oil stain.
      SOLUTION: This liquid detergent composition contains (a) a hydrogen peroxide or a compound forming the hydrogen peroxide in water, (b) a nonionic surfactant (b1) and an anionic surfactant (b2) as surfactants, (c) a compound selected from boric acid, borax, and a boric acid salt, (d) a compound having not less than one site in which carbon atoms adjoining each other each have one hydroxy group, and (e) the bleaching activator which contains an 8-11C straight-chain or branched-chain alkanoyl group and has a group selected from -COOM (M is a cation), -SO
      3 M, and -OSO
      3 M in its molecule, wherein the composition has a weight ratio of the component (b1) to the component (b2) of 5-300, a mol ratio of the component (d) to the component (c) of 1.5 to 2.7, and a pH of 4.6 to 7.0 at 20°C.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:为了提供一种具有pH跳跃效应的液体洗涤剂组合物在达到漂白效果的水平上,显着提高了漂白活化剂的稳定性,并表现出优异的清洁皮脂和油渍性能 。 该液体洗涤剂组合物含有(a)过氧化氢或水中形成过氧化氢的化合物,(b)作为表面活性剂的非离子表面活性剂(b1)和阴离子表面活性剂(b2),(c)化合物 选自硼酸,硼砂和硼酸盐,(d)具有不少于一个碳原子相邻的位置的化合物各自具有一个羟基,和(e)含有8-11C的漂白活化剂 具有选自-COOM(M为阳离子),-SO 3 M和-OSO 3
    • 29. 发明专利
    • Liquid detergent composition
    • 液体洗涤剂组合物
    • JP2012087228A
    • 2012-05-10
    • JP2010235761
    • 2010-10-20
    • Kao Corp花王株式会社
    • ISHIZUKA HITOSHIINOUE KATSUHISAKOSAKA HARUKAKOMATSU YOSHIYUKI
    • C11D17/08C11D1/04C11D1/12C11D1/62C11D1/722C11D1/74C11D3/37C11D3/43C11D3/50
    • PROBLEM TO BE SOLVED: To provide a liquid detergent composition that has a highly-concentrated surfactant, and is excellent in detergency and adsorptivity of a flavor ingredient to a clothing material, wherein: its stock solution is excellent in low foamability and anti-foaming properties; a diluted solution of wash concentration has high foamability in the meantime; and solubility is prevented from degrading when the composition is diluted with water.SOLUTION: The liquid detergent composition contains each of the followings (a) to (f) at predetermined rate: (a) a predetermined nonionic surfactant that contains under a predetermined condition an ethyleneoxy group and 3-5C alkyleneoxy group, (b) an anionic surfactant, (c) a cationic surfactant, (d) silicone, (e) a perfume compound having LogP of ≥3, and (f) a water-miscible solvent.
    • 要解决的问题:提供一种具有高浓缩表面活性剂的液体洗涤剂组合物,并且对衣物材料的香味成分的去污力和吸附性优异,其中:其原液具有优异的低发泡性和抗反射性 发泡属性; 洗涤浓度的稀释溶液同时具有高泡沫性; 并且当用水稀释组合物时,防止溶解度降低。 溶液:液体洗涤剂组合物以预定速率包含以下各项(a)至(f):(a)在预定条件下含有乙烯氧基和3-5C亚烷基氧基的预定非离子表面活性剂,(b )阴离子表面活性剂,(c)阳离子表面活性剂,(d)硅氧烷,(e)LogP≥3的香料化合物,和(f)水混溶性溶剂。 版权所有(C)2012,JPO&INPIT
    • 30. 发明专利
    • Detergent composition for application
    • 洗涤剂组合物应用
    • JP2012087227A
    • 2012-05-10
    • JP2010235760
    • 2010-10-20
    • Kao Corp花王株式会社
    • MATOBA MIKIISHIZUKA HITOSHIHIROSHIMA MASAFUMI
    • C11D1/94C11D1/62C11D1/722
    • PROBLEM TO BE SOLVED: To provide a detergent composition for application that has high cleaning effect on stubborn sebum stains, such as stains on collars and cuffs of clothing.SOLUTION: The detergent composition for application contains (a) a nonionic surfactant represented by the following general formula (a1), (b) an anionic surfactant, and (c) a cationic surfactant, wherein (a)+(b)+(c)=40-90 mass%, a mass ratio (a)/[(b)+(c)] is 0.5-5, and a mass ratio (b)/(c) is 0.3-2.5. R-O-[(EO)m/(PO)n]-H (a1), wherein R is an 8-20C hydrocarbon group; EO is an ethyleneoxy group; PO is a propyleneoxy group; m and n are average addition mole numbers, m is 14-22, and n is 1-5; and "/" means that EO and PO may either a random adduct or a block adduct, and that the addition order of EO and PO is inconsequential.
    • 要解决的问题:提供一种对顽固性皮脂污渍具有高清洁效果的涂抹用洗涤剂组合物,例如衣服的衣领和袖口上的污渍。 解决方案:应用的洗涤剂组合物包含(a)由以下通式(a1)表示的非离子表面活性剂,(b)阴离子表面活性剂和(c)阳离子表面活性剂,其中(a)+(b) +(c)= 40〜90质量%,质量比(a)/ [(b)+(c)]为0.5〜5,质量比(b)/(c) R-O - [(EO)m /(PO)n] -H(a1),其中R为8-20C烃基; EO是乙烯氧基; PO是丙烯氧基; m和n是平均加成摩尔数,m是14-22,n是1-5; 和“/”表示EO和PO可以是随机加合物或嵌段加合物,EO和PO的加成顺序是无关紧要的。 版权所有(C)2012,JPO&INPIT