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    • 23. 发明专利
    • FORMATION OF RESIST PATTERN
    • JP2000347420A
    • 2000-12-15
    • JP15747099
    • 1999-06-04
    • HITACHI LTD
    • TANAKA TOSHIHIKO
    • G03F7/038G03F7/26G03F7/30
    • PROBLEM TO BE SOLVED: To form a resist pattern having desired apertures so that a resist does not remain in grooves and pores surrounded by light shielding materials which hardly transmit the exposure light by making a part to form the resist apertures into an exposure light shielding part using a negative resist. SOLUTION: Such a Si substrate 10 is formed by a regular method, that is covered by an oxide film 11 on the surface and is provided with pores each having 0.25 μm width and 1.25 μm depth. Si is opaque to the light of 365 nm. A negative resist 12 is applied onto the Si substrate 10, which is then irradiated with the exposure light 14 through a lens using a mask 13 which makes the part to be implanted into the light shielding part and subsequently developed to form a resist aperture part 15. Since the pores are so small as to have 0.25 μm width and 1.25 μm depth, i.e., 5 aspect ratio, the resist does not remain in the pores so that the resist aperture can easily be formed. The implantation is then performed. By this method, the impurities can be diffused into the desired pore parts.
    • 24. 发明专利
    • FORMING METHOD OF FILM AND PATTERN
    • JPH09134867A
    • 1997-05-20
    • JP29246695
    • 1995-11-10
    • HITACHI LTD
    • YAMANAKA RYOKOASAI NAOKOMINE TOSHIYUKITANAKA TOSHIHIKO
    • G03F7/004G03F7/11H01L21/027
    • PROBLEM TO BE SOLVED: To enable an excellent resist pattern to be formed on a film work by a method wherein inert gas such as nitrogen gas or the like is introduced so as to form an oxide film of polyatomic layer on the surface of the film work to modify hydroxyl group on the surface of a ground film such as a nitride film. SOLUTION: A film work 1 is introduced into a sputtering device where a silicon piece is used as a target, nitrogen gas or a mixed gas of nitrogen and other is introduced as buffer gas into the device, a sputtering process is started. A silicon nitride film 2 made up with silicon atoms 8 emitted from the silicon target and nitrogen atoms 9 contained in buffer gas is formed on the surface of the substrate work 1. After the film 2 is formed as thick as required, buffer gas is replaced with argon gas, and a film forming process is carried on. At this point, buffer gas may be gradually varied in composition. As a result, a polyatomic silicon layer 12 is formed on the silicon nitride film 2. Thereafter, when the substrate work 1 is unloaded from the sputtering device, a natural oxide film is formed on the surface of the substrate work 1. By this setup, an excellent resist pattern can be obtained.
    • 30. 发明专利
    • ION IMPLANTATION METHOD
    • JPH06349765A
    • 1994-12-22
    • JP13431493
    • 1993-06-04
    • HITACHI LTD
    • TANAKA TOSHIHIKO
    • H01L21/265H01L21/027
    • PURPOSE:To avoid halation and realize highly accurate ion implantation to form a fine pattern by a method wherein an organic film which absorbs an exposure light is formed on a substrate, a resist pattern is formed on the organic film and required ions are implanted without processing the organic film. CONSTITUTION:An element isolation oxide film 2, an oxide film 3 and a polycrystalline silicon film 4 which is a gate are formed on an Si substrate 1 to obtain an MDS-FET structure. Then an organic film 5 which absorbs an exposure light for pattern exposure is formed by coating and heat treatment. Then a resist pattern 6 is formed by resist coating, exposure and development. After that, ions are implanted 7 to form an ion implantaion layer 8. After that, an ordinary plasma treatment is performed and the light absorbing organic film 5 is removed with the resist to form an offset gate MOS-FET. As the ions are implanted into the required positions of the obtained MOS-FET, required electrical characteristics can be obtained. With this constitution, halation can be avoided, so that this ion implantation method can be applied to the formation of a fine pattern.