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    • 22. 发明专利
    • PRODUCTION OF HYDROGEN FOR FUEL CELL
    • JPH02311301A
    • 1990-12-26
    • JP13005089
    • 1989-05-25
    • MITSUBISHI HEAVY IND LTD
    • TAKEUCHI YOSHIYUKIIMAI TETSUYA
    • C01B3/32C01B3/38C01B3/50H01M8/06
    • PURPOSE:To obtain hydrogen for fuel cell in improved equilibrium conversion while recovering heat by placing a hydrogen-separation membrane in a reaction tube and an outer tube outside of the reaction tube, extracting H2 passed through the separation membrane out of the system and supplying to a fuel cell. CONSTITUTION:A hydrogen-containing gas produced by the steam reforming reaction of hydrocarbon or methanol as a raw material is used as a fuel for a fuel cell. The above process is carried out as follows. A separation membrane having hydrogen separating function is placed in a reaction tube filled with a catalyst and an outer tube is placed outside of the reaction tube. The raw material for steam reforming is supplied to the reaction tube filled with the catalyst to generate H2. An inert gas is introduced to the inner side of the separation membrane and the H2 permeated through the separation membrane is extracted together with the inert gas from the system. The H2-containing gas is supplied to a fuel cell, H2 is consumed in the fuel cell and the residual gas having lowered H2 concentration and composed mainly of the inert gas is recycled into the separation membrane.
    • 23. 发明专利
    • ADSORPTION REFRIGERATING DEVICE
    • JPH02176376A
    • 1990-07-09
    • JP32767588
    • 1988-12-27
    • MITSUBISHI HEAVY IND LTD
    • KANEDA HIROAKITAKEUCHI YOSHIYUKI
    • F25B17/08
    • PURPOSE:To adsorb and evaporate refrigerant continuously and improve an operating efficiency jumpingly by a method wherein a cooling chamber is formed at one side of a film having multitude of fine through holes while a heating chamber is formed at the other side of the film. CONSTITUTION:Refrigerant vapor, supplied into a cooling chamber 2, is adsorbed into the fine through holes 8 of a film 1 to liquefy it while latent heat, dissipated upon liquefying, is removed by a cooling pipe 10 arranged in the cooling chamber 2. The liquid of the refrigerant moves through the through holes 8 by a temperature difference between the cooling chamber and a heating chamber as well as capillary phenomenon and enters into the heating chamber 3, heated by a heating tube 11, through a hole 9 so as to be evaporated. The refrigerant vapor in the cooling chamber 2 is made to flow sequentially into the through holes 8 to adsorb it accompanying the evaporation of the refrigerant solution in the through holes 8. The refrigerant vapor in the heating chamber 3 enters into a condenser 4 and is cooled here so as to be condensed and liquefied. Subsequently, the liquefied refrigerant is choked by an expansion valve 5 to effect adiabatic expansion and, thereafter, enters into a heat exchanger 6 so as to be evaporated by cooling a refrigerating load and circulated into the cooling chamber 2 again under this condition.
    • 25. 发明专利
    • Process and apparatus for recovering oil and gas from oil shale
    • 从油层回收油和气的工艺和装置
    • JPS5943091A
    • 1984-03-09
    • JP15177782
    • 1982-09-02
    • Mitsubishi Heavy Ind Ltd
    • TAKEUCHI YOSHIYUKI
    • C10B53/06
    • PURPOSE: To efficiently recover oil and gas by effectively recovering heat of oil shale by dry distilling the oil shale using an apparatus constituted of a combination of a moving grate-type apparatus, crusher and fluidized layer apparatus.
      CONSTITUTION: Dry distillation is carried out by heating a granular oil shale layer 2 on a moving grate 1 to 300W900°C in a preheating/dry distillation section A. A part of the dry distillation product gas obtd. by cooling and separating, as hereinafter described, the produced dry distillation product is heated in a furnace F and used for the above heating. After crushed and adjusted by a crusher C, the residual granule is formed into a fluidized layer with an oxygen-contg. gas stream 15 in a combustion apparatus D and the residual combustible material is burned to recover heat. The remaining coarse powder is primarily cooled with a cooling gas stream 9 in a primary cooling tower E while forming the state of a fluidized layer, and further secondarily cooled by a secondary cooling tower T, and the cooled waste solid is discharged out of the system. Oil and gas are efficiently recovered by recovering heat from both the primary and secondary cooling processes.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过使用移动炉排式设备,破碎机和流化层设备组合的设备干馏油页岩,有效回收油页岩热量,有效回收油气。 构成:通过在预热/干馏段A中在移动的炉排1至300-900℃上加热颗粒状油页岩层2进行干馏。一部分干馏产物气体得到。 通过冷却和分离,如下所述,将生产的干馏产物在炉F中加热并用于上述加热。 经破碎机C粉碎并调整后,将残留的颗粒形成为具有耐氧性的流化层。 在燃烧装置D中的气流15和残留的可燃材料被燃烧以回收热量。 剩余的粗粉末主要在主冷却塔E中用冷却气流9冷却,同时形成流化层的状态,并进一步由二次冷却塔T二次冷却,将冷却的废弃物固体排出系统 。 通过从一次和二次冷却过程中回收热量来有效地回收油和气。
    • 26. 发明专利
    • FLASH VAPORIZER
    • JPS5889980A
    • 1983-05-28
    • JP18778481
    • 1981-11-25
    • MITSUBISHI HEAVY IND LTD
    • TAKEUCHI YOSHIYUKITANIZAKI KEIJIONO MASAONORIMATSU YASUFUMIHASHIMOTO RITSUO
    • B01D3/06
    • PURPOSE:To make speed of flash vaporization higher than that by a conventional device, by implanting strip-shaped weirs in the colliding direction of brine at the bottom of a flash vaporizing chamber where the brine communicates horizontally. CONSTITUTION:An evaporizing chamber 1 is partitioned with interstage bulkheads 2, and has specified interstage pressure difference between a low-pressure vaporizing chamber 1b and an adjoining high pressure vaporizing chamber 1a through the adjustment of an orifice plate 4 provided to an orifice slit 3 at the lower part of the interstage bulkhead 2. Further, weirs 6 are provided in zigzag at the bottom 5 of the vaporizing chamber. Namely, brine 7 communicating in the chamber 1a flows into the chamber 1b through the slit 3 adjusted in opening area by the plate 4. At this time, part of the brine is flash-vaporized. The brine is stirred repeatedly to proper extents when passing through the weirs 6 and thus the flash vaporization is carried on in renewing the liquid surface, thereby allowing the unvaporized brine to flow out to the low pressure vaprizing chamber 1c.
    • 29. 发明专利
    • DRY DISTILLATION OF OIL SHALE
    • JPS57207682A
    • 1982-12-20
    • JP9082081
    • 1981-06-15
    • MITSUBISHI HEAVY IND LTD
    • TOKUDA MASAHIROTAKEUCHI YOSHIYUKIUGAWA NAOHIKONAKAMURA TSUMORU
    • C10B53/06
    • PURPOSE:To obtain a product gas having high calorific value with suppressing the formation or powder or granules, by loading a transfer lattice with crushed oil shale from which almost all water is removed by preheating it at a specific temperature, subjecting it to dry distillation with a hot gas, exposing the oil shale to an oxygen-containing gas flow, followed by cooling it with a gas flow. CONSTITUTION:The raw material oil shale F is fed to the hopper 1, it is preheated at a temperature >= the dry distillation temperature of hydrocarbon compounds in the oil shale and >=150 deg.C by a hot gas flow from the pipe 3 while being formed into the layer a and made to flow downward in the device 2 of the mobile layer type, so almost all water in the oil shale is removed and it is dried, and the oil shale is fed to theIsection on the transfer lattice 4, to form the layer b. It is then heated and subjected to dry distillation in the II section by a hot gas flow, exposed to an oxygen-containing gas flow in the III section, and it is cooled by a has flow in the IV and the V sections. The efflux in the section for heating and dry distillation is taken out from the pipe 5, sent through the cooler 6 and the separator 7 and taken out as the product gas PG from the pipe 10.