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    • 21. 发明专利
    • Hollow silica particle
    • 中空硅胶颗粒
    • JP2009093876A
    • 2009-04-30
    • JP2007262066
    • 2007-10-05
    • Kao Corp花王株式会社
    • HOSOKAWA KOJIISSHIKI NOBUYUKIYANO AKIHIROYAMASHITA RISAKO
    • H01B3/00C09D7/12C09D163/00C09D201/00H01L21/312H01L21/768
    • PROBLEM TO BE SOLVED: To provide a low-dielectric-constant film having a sufficient low dielectric constant, a manufacturing method thereof, and a coating agent for the low-dielectric-constant film. SOLUTION: (1) The low-dielectric-constant film is formed by dispersing hollow-structured mesoporous silica particles in a matrix resin. (2) The low-dielectric-constant film manufacturing method includes a step in which a dispersion liquid formed by dispersing hollow-structured mesoporous silica particles in the matrix resin forming material is prepared and the obtained dispersion liquid is applied onto a substrate so as to solidify it after the application. (3) The coating agent for the low-dielectric-constant film is formed by dispersing hollow-structured mesoporous silica particles in the matrix resin forming material. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有足够低介电常数的低介电常数膜,其制造方法和用于低介电常数膜的涂层剂。 解决方案:(1)通过将中空结构的介孔二氧化硅颗粒分散在基质树脂中来形成低介电常数膜。 (2)低介电常数膜制造方法包括将基于中空结构的介孔二氧化硅颗粒分散在基体树脂形成材料中形成的分散液,并将得到的分散液涂布在基板上的步骤, 应用后固化。 (3)低介电常数膜用涂布剂是通过在基体树脂形成材料中分散中空结构的介孔二氧化硅颗粒而形成的。 版权所有(C)2009,JPO&INPIT
    • 22. 发明专利
    • Coating composition
    • 涂料组合物
    • JP2011157506A
    • 2011-08-18
    • JP2010021413
    • 2010-02-02
    • Kao Corp花王株式会社
    • HOSOKAWA KOJIYANO AKIHIROYOSHIDA JUNKOMATSU MASAKI
    • C09D201/00C09D5/33C09D7/12
    • PROBLEM TO BE SOLVED: To provide a coating composition forming a coating film having a low refractive index and a low reflectance, to provide a method for producing the same, and to provide the coating film or an antireflection film formed by using the coating composition. SOLUTION: The coating composition includes a matrix-forming material; and mesoporous silica particles containing a shell part having a mesoporous structure containing silica, and having an average primary particle diameter of 10-200 nm. The coating film formed by using the coating composition includes the matrix; and the hollow mesoporous silica particles containing the shell part having the mesoporous structure containing the silica and a hollow part present on the inside of the shell part, and having an average primary particle diameter of 10-200 nm. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:为了提供一种形成具有低折射率和低反射率的涂膜的涂料组合物,以提供其制备方法,并且提供通过使用该涂料形成的涂膜或抗反射膜 涂料组合物。 溶液:涂料组合物包括基体形成材料; 以及含有具有含二氧化硅的介孔结构的壳部的平均一次粒径为10〜200nm的介孔二氧化硅粒子。 通过使用该涂料组合物形成的涂膜包括: 所述中空介孔二氧化硅粒子含有具有含有二氧化硅的中孔结构的壳部分和存在于壳部内部的中空部分,平均一次粒径为10〜200nm。 版权所有(C)2011,JPO&INPIT
    • 23. 发明专利
    • Composite membrane
    • 复合膜
    • JP2010095416A
    • 2010-04-30
    • JP2008268947
    • 2008-10-17
    • Kao Corp花王株式会社
    • KOMATSU MASAKIYANO AKIHIRO
    • C01B37/02B22F9/24C01B33/12G11B5/70G11B5/714G11B5/842H01L35/14H01L35/34H01M4/38
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a composite membrane having metal nanoparticles present in mesopores in a mesoporous silica film oriented in a direction substantially perpendicular to the film, and to provide a method for producing such a composite membrane.
      SOLUTION: (1) The composite membrane has metal nanoparticles present in mesopores in a mesoporous silica film, wherein the mesoporous silica film has a mesoporous structure having an average pore cycle of 1.5-6 nm and the mesopores are oriented in a direction of 75-90° to the film surface. (2) The method for producing such a composite membrane includes bringing a mesoporous silica film into contact with a solution or electrolyte containing a metal species, reducing the metal species, and depositing metal nanoparticles in mesopores in the mesoporous silica film.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种在基本上垂直于膜的方向取向的介孔二氧化硅膜中的介孔中存在金属纳米颗粒的复合膜,并提供一种制备这种复合膜的方法。 解决方案:(1)复合膜在中孔二氧化硅膜中具有存在于介孔中的金属纳米颗粒,其中介孔二氧化硅膜具有平均孔隙周期为1.5-6nm的介孔结构,并且中孔在方向 对于膜表面为75-90°。 (2)这种复合膜的制造方法包括使介孔二氧化硅膜与含有金属的溶液或电解液接触,还原金属物质,并在介孔二氧化硅膜中的中孔中沉积金属纳米粒子。 版权所有(C)2010,JPO&INPIT
    • 25. 发明专利
    • Mesoporous silica particle
    • MESOPOROUS二氧化硅颗粒
    • JP2008174435A
    • 2008-07-31
    • JP2007011776
    • 2007-01-22
    • Kao Corp花王株式会社
    • YANO AKIHIROSAWADA TAKUYA
    • C01B37/02
    • PROBLEM TO BE SOLVED: To provide: composite silica particles each having a mesoporous structure and including a polymer; hollow silica particles each having a mesoporous structure; and the methods for producing them. SOLUTION: (1) The composite silica particles each has an outer shell part having a mesoporous structure with an average pore diameter of 1-10 nm and includes one or more kinds selected from a cationic polymer, a nonionic polymer and an amphoteric polymer at the inside of the outer shell part. (2) The hollow silica particles are obtained by firing the composite silica particles. (3) The methods for producing them are also provided. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供:具有介孔结构且包含聚合物的复合二氧化硅颗粒; 中空二氧化硅颗粒各自具有介孔结构; 及其生产方法。 解决方案:(1)复合二氧化硅颗粒各自具有平均孔径为1-10nm的介孔结构的外壳部分,并且包括选自阳离子聚合物,非离子聚合物和两性的一种或多种 聚合物在外壳部分的内部。 (2)通过烧结复合二氧化硅粒子得到中空二氧化硅粒子。 (3)还提供了生产方法。 版权所有(C)2008,JPO&INPIT
    • 26. 发明专利
    • Hollow silica particles
    • 中空二氧化硅颗粒
    • JP2008110905A
    • 2008-05-15
    • JP2006295958
    • 2006-10-31
    • Kao Corp花王株式会社
    • YANO AKIHIROSAWADA TAKUYA
    • C01B37/02
    • PROBLEM TO BE SOLVED: To provide hollow silica particles whose outer shell has a mesopore structure and composed of a silicon compound having an organic group and to which lipophilicity is imparted, and to provide a method for producing the same. SOLUTION: The outer shell of the hollow silica particles has a mesopore structure. The outer shell is composed of a silicon compound having an organic group. The mesopores have an average pore size of 1-10 nm. Also disclosed is a method for producing the hollow silica particles. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供外壳具有中孔结构并由具有有机基团的硅化合物组成并具有亲油性的中空二氧化硅颗粒,并提供其制备方法。 解决方案:中空二氧化硅颗粒的外壳具有中孔结构。 外壳由具有有机基团的硅化合物组成。 介孔的平均孔径为1-10nm。 还公开了一种中空二氧化硅颗粒的制造方法。 版权所有(C)2008,JPO&INPIT
    • 29. 发明专利
    • Method for producing sugar
    • 生产糖的方法
    • JP2014128234A
    • 2014-07-10
    • JP2012288462
    • 2012-12-28
    • Kao Corp花王株式会社
    • YANO AKIHIROTANOGAMI AKIHIRO
    • C13K1/02
    • PROBLEM TO BE SOLVED: To provide a method for producing sugar by hydrolyzing cellulose raw material, that can efficiently produce sugar from cellulose raw material and that can recover and reuse the acid catalyst used for the hydrolysis, in a simple manner.SOLUTION: The method for producing sugar has the following step (1) and step (2). Step (1): a step to hydrolyze cellulose raw material (A1) in an aqueous solution containing organic acid whose solubility in 100 g of water at 20°C is 25 g or less, to obtain sugar containing reaction mixture (B1). Step (2): a step to recover from the sugar containing reaction mixture (B1) obtained in step (1), the organic acid that precipitated into the reaction mixture.
    • 要解决的问题:提供通过水解纤维素原料生产糖的方法,其可以从纤维素原料高效地生产糖并且可以简单地回收和再利用用于水解的酸催化剂。方法:该方法 制备糖具有以下步骤(1)和步骤(2)。 工序(1):在含有有机酸的水溶液中水解纤维素原料(A1)的步骤(其在20℃下在100g水中的溶解度为25g以下),得到含糖反应混合物(B1)。 步骤(2):从步骤(1)中获得的含糖反应混合物(B1)中回收到沉淀到反应混合物中的有机酸的步骤。
    • 30. 发明专利
    • Method for producing saccharide
    • 生产沙拉的方法
    • JP2013215187A
    • 2013-10-24
    • JP2013018531
    • 2013-02-01
    • Kao Corp花王株式会社
    • YANO AKIHIRO
    • C12P19/14
    • C12P19/14C12P19/02C12P2201/00C13K1/02
    • PROBLEM TO BE SOLVED: To provide a method for producing a saccharide with excellent productivity, capable of efficiently producing the saccharide from a cellulose raw material.SOLUTION: A method for producing a saccharide includes the following steps (1) and (2). In step (1), a treatment product is obtained by heating a cellulose raw material in the presence of at least one additive selected from the group consisting of nonionic surfactant and polyethylene glycol and water under the condition of pH less than 7; and in step (2), the treatment product obtained in step (1) is subjected to saccharification treatment with an enzyme.
    • 要解决的问题:提供一种能够从纤维素原料高效地制造糖的生产率优异的糖类的制造方法。溶液:糖的制造方法,包括以下的工序(1)和(2)。 在步骤(1)中,在pH小于7的条件下,在选自非离子表面活性剂和聚乙二醇和水中的至少一种添加剂的存在下加热纤维素原料,得到处理产物; 在步骤(2)中,将步骤(1)中得到的处理产物用酶进行糖化处理。