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    • 12. 发明专利
    • Invariable-layer-spacing laminar inorganic/organic composite, method for manufacturing the same, and humidity observing system
    • 不可分层间距层压无机/有机复合材料,其制造方法和湿度观测系统
    • JP2014172777A
    • 2014-09-22
    • JP2013045911
    • 2013-03-07
    • National Institute For Materials Science独立行政法人物質・材料研究機構
    • FUJII KAZUKOHASHIZUME HIDEOSHIMOMURA SHUICHIANDO HISAHIRO
    • C01B33/44G01N23/20
    • PROBLEM TO BE SOLVED: To provide an invariable-layer-spacing laminar inorganic/organic composite capable of maintaining an invariable layer spacing even if the relative humidity varies; a method for manufacturing the same; and a simple humidity observing system.SOLUTION: The problem-solving invariable-layer-spacing laminar inorganic/organic composite 21 is furnished with: an organic group 41 for hydrophobicizing the interlayer space of multiple inorganic compound layers 31 and 32 wherein the respective layer surfaces 31a and 32b thereof are arrayed in parallel; and a water-adsorbent organic molecule 51, whereas one terminal side 41a of the hydrophobicizing organic group 41 is fixed to the layer surface 31a, whereas the other terminal side 41b of the same interacts 61 with one terminal side 42b of another hydrophobicizing organic group 42 wherein the other terminal side 42a thereof is fixed to the side of the surface 32b opposing the layer surface 31a so as to maintain an invariable layer spacing d even if the relative humidity varies.
    • 要解决的问题:提供即使相对湿度变化也能够保持不变层间距的不变层间隔层状无机/有机复合材料; 其制造方法; 和简单的湿度观测系统。解决方案:解决问题的不变层间隔层状无机/有机复合材料21具有:用于疏水多层无机化合物层31和32的层间空间的有机基团41,其中各层表面 31a和32b平行排列; 和吸水有机分子51,而疏水性有机基团41的一个末端侧41a固定在层表面31a上,而另一个终端侧41b与另一个疏水性有机基团42的一个末端侧42b相互作用 其中,另一个端子侧42a固定在与层表面31a相对的表面32b的侧面,以便即使相对湿度变化也保持不变的层间距d。
    • 13. 发明专利
    • Lamellar clay mineral composite and method of manufacturing the same, film forming composition using the lamellar clay mineral composite, and film
    • LAMELLAR CLAY矿物复合材料及其制造方法,使用LAMELLAR CLAY矿物复合材料制成膜的成膜组合物和膜
    • JP2014051419A
    • 2014-03-20
    • JP2012198177
    • 2012-09-10
    • Kri Inc株式会社Kri
    • SOJO DAISAKUARIMA HIROAKIONAKA JUNKO
    • C01B33/44
    • PROBLEM TO BE SOLVED: To provide a lamellar clay mineral composite having high water resistance and high dispersibility to organic solvent, to provide a film forming composition, and to provide a film.SOLUTION: A lamellar clay mineral composite is a modified lamellar clay mineral having a lamellar structure in which a layer having an octahedral sheet consisting of an octahedral crystal structure including at least aluminum, or aluminum, magnesium and oxygen (hereinafter, referred to as "basic structure layer") is laminated between tetrahedral sheets consisting of a tetrahedral crystal structure including at least silicon and oxygen, wherein the octahedral sheet and/or the tetrahedral sheet contain lithium ion, an interlayer cation of the basic structure layer is replaced by a cation derived from a cationic organic compound. Further, it is possible to form a film having excellent adhesion to various types of base material from the lamellar clay mineral composite with high water resistance.
    • 要解决的问题:提供一种对有机溶剂具有高耐水性和高分散性的层状粘土矿物复合材料,以提供成膜组合物并提供膜。解决方案:层状粘土矿物复合材料是改性层状粘土矿物,其具有 其中由具有至少包含铝或铝,镁和氧的八面体晶体结构的八面体片(以下称为“碱性结构层”)的层叠在由四面体晶体构成的四面体片之间层叠的层状结构 至少包括硅和氧的结构,其中八面体片和/或四面体片含有锂离子,碱性结构层的层间阳离子被来自阳离子有机化合物的阳离子代替。 此外,可以从具有高耐水性的层状粘土矿物复合体形成对各种基材具有优异粘附性的膜。