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11. 发明专利

JP2010097767A Solid oxide fuel battery cell and method of manufacturing the same 审中-公开
标题翻译：固体氧化物燃料电池及其制造方法
公开(公告)号：JP2010097767A
公开(公告)日：2010-04-30
申请号：JP2008266472
申请日：2008-10-15
申请人： Toto Ltd , Toto株式会社
发明人： SHIMAZU MEGUMI , SHIONO MITSUNOBU , HIWATARI KENICHI , MURAKAMI HIRONOBU , FURUYA MASANORI , TAKASHIO MINORU , ANDO SHIGERU
IPC分类号： H01M4/86 , H01M4/88 , H01M8/02 , H01M8/12
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To suppress powderization of a solid electrolyte of a solid oxide fuel cell. SOLUTION: A solid oxide fuel battery cell includes: an air electrode which is a perovskite-type oxide containing Mn; an air electrode catalyst layer disposed on the air electrode; the solid electrolyte disposed on the air electrode catalyst layer; and a fuel electrode disposed on the solid electrolyte. The air electrode catalyst layer has the perovskite-type oxide that contains at least Mn, and the solid electrolyte contains at least YSZ. The solid electrolyte includes an exposed part that does not have an air electrode. ScSZ is contained in the exposed part, and the exposed part includes a portion having a lattice constant of YSZ that exceeds 0.512488 nm, when the constant is measured by the Rietveld method. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：抑制固体氧化物燃料电池的固体电解质的粉化。解决方案：固体氧化物燃料电池单元包括：空气电极，其是含有Mn的钙钛矿型氧化物; 设置在空气电极上的空气电极催化剂层; 所述固体电解质设置在所述空气电极催化剂层上; 和设置在固体电解质上的燃料电极。空气电极催化剂层具有含有至少Mn的钙钛矿型氧化物，固体电解质至少含有YSZ。固体电解质包括不具有空气电极的暴露部分。当通过Rietveld方法测量常数时，暴露部分包含ScSZ，并且暴露部分包括YSZ的晶格常数超过0.512488nm的部分。版权所有（C）2010，JPO＆INPIT

12. 发明专利

JP2009140800A Air pole support for solid oxide fuel cell, and solid oxide fuel cell body using the same 有权
标题翻译：用于固体氧化物燃料电池的空气支撑和使用其的固体氧化物燃料电池体
公开(公告)号：JP2009140800A
公开(公告)日：2009-06-25
申请号：JP2007316932
申请日：2007-12-07
申请人： Toto Ltd , Toto株式会社
发明人： SHIMAZU MEGUMI , SHIONO MITSUNOBU , HIWATARI KENICHI , MURAKAMI HIRONOBU , FURUYA MASANORI , TAKASHIO MINORU
IPC分类号： H01M8/02 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To provide an air pole support for a solid oxide fuel cell, having improved strength when using La 1-y Sr y Ni 1-x Fe x O 3 . SOLUTION: Using La 1-y Sr y Ni 1-x Fe x O 3 (0 COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种用于固体氧化物燃料电池的空气极支撑，当使用La 1-y Ni 时具有改善的强度 1-x＆lt; SB＆gt; x＆lt; SB＆gt; 3＆lt; SB＆gt; 3＆lt; SB＆gt;
解决方案：使用La Ni 1-x Fe x 3 （0

13. 发明专利

JP2008226762A Solid oxide type fuel battery cell and solid oxide type fuel battery 审中-公开
标题翻译：固体氧化物型燃料电池和固体氧化物型燃料电池
公开(公告)号：JP2008226762A
公开(公告)日：2008-09-25
申请号：JP2007066717
申请日：2007-03-15
申请人： Toto Ltd , Toto株式会社
发明人： HIWATARI KENICHI , SHIONO MITSUNOBU , MURAKAMI HIRONOBU , TAKASHIO MINORU , FURUYA MASANORI , SHIMAZU MEGUMI
IPC分类号： H01M4/86 , H01M4/90 , H01M8/02 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To provide a solid oxide type fuel cell unit capable of restraining generation of warp and generating no exfoliation of an inter-connector and a fuel electrode despite repetition of temperature rise and fall between an operating temperature and a room temperature and retaining high output performance. SOLUTION: In the SOFC unit, the inter-connector has a lanthanum chromite perovskite type oxide as a principal component, and further, includes a Ti element and an Ni element. The fuel electrode has at least a first fuel electrode layer and a second fuel electrode layer. The first electrode layer lies between a solid electrolyte and the second fuel electrode layer. The first fuel electrode layer and the second fuel electrode layer include nickel and/or nickel oxide, and zirconia containing a rare-earth element as a solid-solution, and also include the Ti element, existing at least at an interface between the first fuel electrode layer and the second fuel electrode layer as well as between the first fuel electrode layer and the solid electrolyte. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种固体氧化物型燃料电池单元，其能够抑制翘曲的产生，并且尽管重复温度升高和工作温度和室间的下降而不会发生连接器和燃料电极的剥离温度和保持高输出性能。解决方案：在SOFC单元中，相互连接器具有钙钛矿型氧化镧作为主要成分，并且还包括Ti元素和Ni元素。燃料电极具有至少第一燃料电极层和第二燃料电极层。第一电极层位于固体电解质和第二燃料电极层之间。第一燃料电极层和第二燃料电极层包括镍和/或氧化镍，以及含有稀土元素作为固溶体的氧化锆，还包括至少存在于第一燃料电极层和第二燃料电极层以及第一燃料电极层和固体电解质之间。版权所有（C）2008，JPO＆INPIT

14. 发明专利

JP2007305319A Solid oxide fuel cell 审中-公开
标题翻译：固体氧化物燃料电池
公开(公告)号：JP2007305319A
公开(公告)日：2007-11-22
申请号：JP2006129766
申请日：2006-05-09
申请人： Toto Ltd , Toto株式会社
发明人： HIWATARI KENICHI , SHIONO MITSUNOBU , MURAKAMI HIRONOBU , TAKASHIO MINORU , FURUYA MASANORI
IPC分类号： H01M8/02 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To provide a solid oxide fuel cell generation capable of keeping high output performance without peeling off of an interconnector even if rising and falling of temperature are repeated between working temperature (700-1,000°C) and room temperature. SOLUTION: The solid oxide fuel cell includes an air electrode, an electrolyte, a fuel electrode, and an interconnector and has a dense oxidation resistant ceramic layer between the air electrode and the interconnector, and the interconnector contains a lanthanum chromite system perovskite oxide as a main component, and furthermore contains Ti and Ni. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：即使在工作温度（700-1,000℃）和室温（700-1000℃）之间重复温度的升高和降低，提供能够保持高输出性能而不会断开互连器的固体氧化物燃料电池产生。解决方案：固体氧化物燃料电池包括空气电极，电解质，燃料电极和互连器，并且在空气电极和互连器之间具有致密的耐氧化陶瓷层，并且互连器含有铬酸镧系钙钛矿氧化物作为主要成分，并且还含有Ti和Ni。版权所有（C）2008，JPO＆INPIT

15. 发明专利

JP2011146366A Solid oxide fuel cell 有权
标题翻译：固体氧化物燃料电池
公开(公告)号：JP2011146366A
公开(公告)日：2011-07-28
申请号：JP2010207010
申请日：2010-09-15
申请人： Toto Ltd , Toto株式会社
发明人： KAKINUMA YASUO , SHIMAZU MEGUMI , SHIONO MITSUNOBU , HIWATARI KENICHI , FURUYA MASANORI , TAKASHIO MINORU , ANDO SHIGERU
IPC分类号： H01M8/02 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To provide a solid oxide fuel cell which can prevent powderization of a solid electrolyte region. SOLUTION: The solid oxide fuel cell FC1 includes a solid electrolyte 3 having a first region sandwiched by a fuel electrode 4 and an air electrode 1, and a second region formed between an interconnector 2 and the first region. The first region is formed of material having oxygen-ion conductivity, and is so structured that oxygen ions are conducted from the air electrode 1 to the fuel electrode 4 without transmitting fuel gas and oxidant gas. The second region includes a part which is formed of material having oxygen ion conductivity, and the second region is so structured that oxygen ions and water do not coexist. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种可以防止固体电解质区域粉化的固体氧化物燃料电池。解决方案：固体氧化物燃料电池FC1包括具有被燃料电极4和空气电极1夹持的第一区域的固体电解质3和形成在互连器2和第一区域之间的第二区域。第一区域由具有氧离子传导性的材料形成，并且结构使得氧离子从空气电极1传导到燃料电极4而不传输燃料气体和氧化剂气体。第二区域包括由具有氧离子传导性的材料形成的部分，并且第二区域的结构使得氧离子和水不共存。版权所有（C）2011，JPO＆INPIT

16. 发明专利

JP2010092645A Solid oxide fuel battery cell body 审中-公开
标题翻译：固体氧化物燃料电池组体
公开(公告)号：JP2010092645A
公开(公告)日：2010-04-22
申请号：JP2008259314
申请日：2008-10-06
申请人： Toto Ltd , Toto株式会社
发明人： SHIONO MITSUNOBU , SHIMAZU MEGUMI , HIWATARI KENICHI , MURAKAMI HIRONOBU , TAKASHIO MINORU , FURUYA MASANORI , ANDO SHIGERU
IPC分类号： H01M8/02 , H01M4/86 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To provide a solid oxide fuel battery cell body with deformation and warping of an air electrode itself restrained, by obtaining a pre-coat densified by low-temperature calcination. SOLUTION: Of the solid oxide fuel battery cell body provided with an air electrode and an interconnector, as well as a pre-coat between the air electrode and the interconnector, the pre-coat is a Mn system perovskite oxide and includes sintering aids by way of aluminum. As a content of the Al is set at 1 mol% or more and less than 20 mol%, the pre-coat densified through low-temperature calcination is obtained, which enables to provide the solid oxide fuel battery cell body with deformation and warping of the air electrode itself restrained. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：通过获得通过低温煅烧致密化的预涂层来提供固体氧化物燃料电池单元体，其具有由限制的空气极本身的变形和翘曲。解决方案：在设置有空气电极和互连器的固体氧化物燃料电池体中，以及在空气电极和互连器之间的预涂层，预涂层是Mn系钙钛矿氧化物，包括烧结通过铝的方式。当Al的含量设定为1摩尔％以上且小于20摩尔％时，通过低温煅烧而致密化的预涂层，能够提供固体氧化物燃料电池单元体的变形和翘曲空气电极本身受到限制。版权所有（C）2010，JPO＆INPIT

17. 发明专利

JP2009164031A Solid oxide type fuel battery cell body 有权
标题翻译：固体氧化物型燃料电池电池体
公开(公告)号：JP2009164031A
公开(公告)日：2009-07-23
申请号：JP2008002031
申请日：2008-01-09
申请人： Toto Ltd , Toto株式会社
发明人： SHIONO MITSUNOBU , SHIMAZU MEGUMI , HIWATARI KENICHI , MURAKAMI HIRONOBU , TAKASHIO MINORU , FURUYA MASANORI
IPC分类号： H01M4/86 , H01M8/02 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To provide a solid oxide type fuel battery cell body having a pre-coat layer in which durability against reducing gas is improved. SOLUTION: This is a solid oxide type fuel battery cell body having an air electrode and an interconnector. The pre-coat layer is formed between the air electrode and the interconnector. The pre-coat layer is represented by La 1-y Sr y Ni 1-x Fe x O 3 , and by making its composition range 0≤y≤0.3, 0.7≤x≤1, the solid oxide type fuel battery cell body having the pre-coat layer in which the durability against the reducing gas is improved can be provided. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种固体氧化物型燃料电池单体体，其具有改善耐还原气体耐久性的预涂层。解决方案：这是具有空气电极和互连器的固体氧化物型燃料电池单体体。预涂层形成在空气电极和互连器之间。预涂层由La 1-y Sb / SiO 2，SB 1，X 3，X 3， SB> 3 ，通过使其组成范围为0≤y≤0.3,0.7≤x≤1，具有改善对还原气体的耐久性的预涂层的固体氧化物型燃料电池体可以提供。版权所有（C）2009，JPO＆INPIT

18. 发明专利

JP2002317260A PHOTOCATALYTIC THIN FILM 失效
公开(公告)号：JP2002317260A
公开(公告)日：2002-10-31
申请号：JP2001120833
申请日：2001-04-19
申请人： TOTO LTD
发明人： HIRAOKA JUNJI , FUKUSHIMA TETSUYA , TAKASHIO MINORU , DOKE TAKAHIRO
IPC分类号： B01J21/06 , B01J35/02 , B01J37/02 , C23C14/08 , C23C14/34
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a photocatalytic thin film. SOLUTION: In the manufacturing method of depositing the photocatalytic thin film by depositing a titanium dioxide layer exhibiting photocatalytic property on a substrate by sputtering using a titanium(Ti) target, the partial pressure of oxygen in an atmospheric gas is controlled to 0.16-Pa to 1.2 Pa, the pressure of the whole atmospheric gas is controlled to 0.8 Pa to 3.0 Pa and the film thickness of the titanium dioxide layer is controlled to 120 nm to 200 nm. The photocatalytic thin film is manufactured by the manufacturing method.

19. 发明专利

JP2002201045A HYDROPHILIC THIN FILM 失效
公开(公告)号：JP2002201045A
公开(公告)日：2002-07-16
申请号：JP2000397379
申请日：2000-12-27
申请人： TOTO LTD
发明人： HIRAOKA JUNJI , FUKUSHIMA TETSUYA , TAKASHIO MINORU , DOKE TAKAHIRO
IPC分类号： B32B7/02 , B01J21/06 , B01J35/02 , B01J37/02 , B32B9/00 , C03C17/245 , C03C17/34 , C23C14/08
摘要： PROBLEM TO BE SOLVED: To obtain a hydrophilic thin film realizing an anti-fog and stain-proof glass which can be practically used as a mirror of automobile or the like. SOLUTION: This hydrophilic thin film is obtained by laminating on a glass substrate an alkali shut off film of silicon oxide having

20. 发明专利

JP2003105262A PHOTOCATALYTIC THIN FILM 审中-公开
公开(公告)号：JP2003105262A
公开(公告)日：2003-04-09
申请号：JP2001303651
申请日：2001-09-28
申请人： TOTO LTD
发明人： FUKUSHIMA TETSUYA , TAKASHIO MINORU
IPC分类号： C03C17/30 , B01J21/06 , B01J35/02 , C09D5/00 , C09D183/02
摘要： PROBLEM TO BE SOLVED: To provide a method for forming a photocatalytic thin film hardly deteriorating in durability even when a photosemiconductor component is filled in a large amount. SOLUTION: This photocatalytic thin film comprises two liquids of a photosemiconductor dispersion liquid and a binder solution to form a photocatalytic thin film on the surface of a substrate in which total solid content in the binder solution is adjusted as 25 to 5 pts.wt. to 75 to 95 pts.wt. of total solid content in the photosemiconductor dispersion liquid. The photosemiconductor dispersion liquid contains photosemiconductor microparticles with average primary particle size of 5 to 20 nm uniformly dispersed in a dispersant. The binder solution comprises 0 to 500 pts.wt. of silica with average primary particle size of 5 to 30 nm, and 0 to 200 pts.wt. of at least one kind of zirconium compound selected from zirconium oxychloride, zirconyl sulfate, zirconyl carbonate, zirconyl hydroxide or hydrates thereof to 1,000 pts.wt. of a silicon alkoxide comprising a tetraalkoxysilane oligomer and a hydrolyzed compound of a tetraalkoxysilane with 1,000 to 2,000 weight-average molecular weight (Mw).

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