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11. 发明专利

JP2005050321A Program, and calculation method using same 有权
标题翻译：程序和计算方法
公开(公告)号：JP2005050321A
公开(公告)日：2005-02-24
申请号：JP2004198886
申请日：2004-07-06
申请人： Toray Ind Inc , 東レ株式会社
发明人： KAWAKAMI TOMOKAZU
IPC分类号： C07B61/00 , G06F19/00
摘要： PROBLEM TO BE SOLVED: To provide a highly accurate and efficient calculation method in calculating a diffusion coefficient of protons in a macromolecule. SOLUTION: This program comprises: a procedure for storing information concerned with sorts, coordinates, coupling information, potential parameter types, charge and mass of atoms in a memory; a 1st registration procedure for registering the numbers of atoms in a pair of atoms in a table; a 2nd registration means for registering the number of a proton and that of a water molecule in the table; a 3rd registration procedure for registering a coupling pattern of protons and water in the table; a 1st calculation procedure for calculating classic interaction applied among atoms; a 2nd calculation procedure for calculating semi-quantum-like interaction; a 3rd calculation means for updating the coordinates of all atoms from the results of the 1st and 2nd calculation procedures; a 4th calculation procedure for distinguishing a proton from hydrogens in a water molecule and determining the coordinates of the proton; and a 5th calculation procedure for calculating a diffusion coefficient. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了在计算大分子中质子的扩散系数时提供高精度和高效的计算方法。解决方案：该程序包括：存储与存储器中的种类，坐标，耦合信息，潜在参数类型，原子的电荷和质量有关的信息的过程; 用于记录表中一对原子中的原子数的第一注册步骤; 用于在表中记录质子数和水分子数的第二登记装置; 用于在表中注册质子和水的耦合图案的第三注册程序; 用于计算原子之间应用的经典相互作用的第一计算程序; 计算半量子样相互作用的第二计算程序; 第三计算装置，用于从第一和第二计算程序的结果更新所有原子的坐标; 用于区分水分子中的质子和氢的第四计算步骤，并确定质子的坐标; 以及用于计算扩散系数的第五计算步骤。版权所有（C）2005，JPO＆NCIPI

12. 发明专利

JP2011038082A Polymerization method for polymer 有权
标题翻译：聚合物聚合方法
公开(公告)号：JP2011038082A
公开(公告)日：2011-02-24
申请号：JP2010144708
申请日：2010-06-25
申请人： Toray Ind Inc , 東レ株式会社
发明人： TOMOKUNI MAYUMI , ADACHI MASAYA , KIDAI MASAYUKI , KAWAKAMI TOMOKAZU
IPC分类号： C08G85/00 , C08G65/38
CPC分类号： Y02E60/522
摘要： PROBLEM TO BE SOLVED: To bring an introduction rate of a monomer unit containing a metal salt of an ionic group close to a stoichiometric value of charge and to achieve a high molecular weight and further to suppress decomposition of the polymer in the polymerization method for a polymer, which method performs desalting polycondensation of the monomer containing a metal salt of an ionic group. SOLUTION: A cyclic metal scavenger is added when desalting polycondensation of the monomer containing a metal salt of an ionic group is performed. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：为了使含有离子基团的金属盐的单体单元的引入速率接近电荷的化学计量值并且实现高分子量并进一步抑制聚合物中聚合物的分解聚合物的方法，该方法进行含有离子性基团的金属盐的单体的脱盐缩聚。解决方案：当进行含有离子性基团的金属盐的单体的脱盐缩聚时，添加环状金属清除剂。版权所有（C）2011，JPO＆INPIT

13. 发明专利

JP2006049303A Polymer electrolyte membrane 有权
标题翻译：聚合物电解质膜
公开(公告)号：JP2006049303A
公开(公告)日：2006-02-16
申请号：JP2005195840
申请日：2005-07-05
申请人： Toray Ind Inc , 東レ株式会社
发明人： KAWAKAMI TOMOKAZU , IZUHARA DAISUKE , SHIMOYAMA NAOKI
IPC分类号： H01M8/02 , C08J5/22 , C08L101/00 , H01B1/06 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a polymer electrolyte membrane having water resistance, methanol resistance, high proton conductivity and low methanol permeability.
SOLUTION: This electrolyte membrane is formed of a sulfonated proton-conducting polymer. In the electrolyte membrane, water-absorbing membrane sulfonate group volume density of the proton-conducting polymer, defined by mathematical Equation (1), is 1.45-6.0 mmol/cm
3 . The mathematical Equation (1): (water-absorbing membrane sulfonate group volume density)=(absolute dry membrane sulfonate group volume density)/{1+(water absorption coefficient)/100×(absolute dry membrane density)}. In the mathematical Equation (1), absolute dry membrane sulfonate group weight density, the absolute dry membrane sulfonate group volume density and the water absorption coefficient are defined by mathematical Equations (2)-(4), respectively. The mathematical Equation (2): (absolute dry membrane sulfonate group weight density)=(number of moles of sulfonate group)/(absolute dry membrane weight). The mathematical Equation (3): (absolute dry membrane sulfonate group volume density)=(absolute dry membrane sulfonate group weight density)×(absolute dry membrane density). The mathematical Equation (4): (water absorption coefficient)=(water weight in membrane)/(absolute dry membrane weight)×100.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供具有耐水性，耐甲醇性，高质子传导性和低甲醇透过性的高分子电解质膜。解决方案：该电解质膜由磺化质子传导性聚合物形成。在电解质膜中，由数学式（1）定义的质子传导性聚合物的吸水膜磺酸盐体积密度为1.45〜6.0mmol / cm 3。数学式（1）:(吸水膜磺酸盐体积密度）=（绝对干膜磺酸盐体积密度）/ä1+（吸水系数）/ 100×（绝对干膜密度）}。在数学方程（1）中，绝对干膜磺酸盐组重量密度，绝对干膜磺酸盐体积密度和吸水系数分别由数学方程（2） - （4）定义。数学式（2）:(绝对干膜磺酸盐基重量密度）=（磺酸盐基的摩尔数）/（绝对干膜重量）。数学式（3）:(绝对干膜磺酸盐基体积密度）=（绝对干膜磺酸盐基重量密度）×（绝对干膜密度）。数学式（4）:(吸水系数）=（膜中的水重量）/（绝对干膜重量）×100。版权所有（C）2006，JPO＆NCIPI

14. 发明专利

JP2004099658A Polylactic acid molded article and method for predicting microstructure of polylactic acid 审中-公开
公开(公告)号：JP2004099658A
公开(公告)日：2004-04-02
申请号：JP2002260071
申请日：2002-09-05
申请人： Toray Ind Inc , 東レ株式会社
发明人： KAWAKAMI TOMOKAZU , KIMURA TOSHIAKI
IPC分类号： C08J5/00 , B29C55/00
摘要： PROBLEM TO BE SOLVED: To provide a heretofore unknown molded article of a polylactic acid exhibiting excellent high-temperature mechanical characteristics.
SOLUTION: The polylactic acid molded article has a density of at least 1.265 (g×cm
-3 ) and at most 1.280 (g×cm
-3 ) in an amorphous part. The molded article has a relaxation time of a carbonyl carbon of at least 42 sec and at most 47 sec as measured by the
13 C nucleus T1 (MAS)-NMR.
COPYRIGHT: (C)2004,JPO

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