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    • 12. 发明专利
    • Treatment of polymer molding containing zeolite particle
    • 包含沸石颗粒的聚合物模塑的处理
    • JPS61136530A
    • 1986-06-24
    • JP25891484
    • 1984-12-06
    • Kanebo LtdKanebo Synthetic Fibers Ltd
    • ITONAGA KOJIMURATA TAROICHIHASHI KUNIOYAMANAKA TAKAO
    • A01N25/10A01N59/00A01N59/16C08J7/12C08K3/00C08K3/34
    • PURPOSE: To treat an organic polymer molding containing solid zeolite particles carrying metallic ions having a sterilizing action to stabilize that part of the metallic ions which is made vulnerable to deactivation by heat.
      CONSTITUTION: A molding comprising an organic polymer (a synthetic polymer which undergoes heat hysteresis during molding, e.g., polyethylene) having solid zeolite particles carrying sterilizing metallic ions (e.g., one or more metallic ions selected from the group consisting of silver, copper and zinc) is treated with an aqueous solution of hydrochlorite and/or hydrogen peroxide. As said zeolite particles, those having a specific surface area ≥150m
      2 /g and a SiO
      2 /Al
      2 O
      3 molar ratio ≤14 or those composed of zeolite A, zeolite X, zeolite Y or mordenite are desirable.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:处理含有固体沸石颗粒的有机聚合物成型体,其带有具有消毒作用的金属离子,以稳定易受热失活的部分金属离子。 构成:包含有机聚合物(在模制期间经历热滞后的合成聚合物,例如聚乙烯),其具有携带灭菌金属离子的固体沸石颗粒(例如,一种或多种选自银,铜和锌的金属离子) )用氢氯酸盐和/或过氧化氢水溶液处理。 作为所述沸石颗粒,比表面积> 150m 2 / g,SiO 2 / Al 2 O 3摩尔比<14或沸石A,沸石X,沸石Y或丝光沸石组成的沸石颗粒是理想的。
    • 20. 发明专利
    • Light-resistant polyamide molding
    • 耐光聚酰胺模塑
    • JPS619457A
    • 1986-01-17
    • JP12988284
    • 1984-06-22
    • Kanebo LtdKanebo Synthetic Fibers Ltd
    • YAMANAKA TAKAOITONAGA KOUJIICHIHASHI KUNIOMURATA TAROUNOHARA SABUROU
    • C08L77/00C08K3/34C08K5/10C08K13/02C08L71/02
    • PURPOSE:A polyamide molding which maintains light resistance persistently for a long time and comprises solid particles of a zeolite retaining copper ions, a vehicle, and a polyamide. CONSTITUTION:0.005-10wt% solid particles of a zeolite (a) consisting of, for example, a powdered A-type zeolite having a specific surface of 150m /g or greater, a mol ratio SiO2/Al2O3 of 14 or greater, and the particle diameter of 20mum or smaller are allowed to undergo ion exchange with a solution of CuSO4, etc. (b) to produce a copper-zeolite (A) retaining 0.001-0.5wt%, based on a molding, copper ions. Component A is kneaded with a vehicle (B) having a viscosity of 500-900cP (at 75 deg.C) and little reactivity with component C (e.g. diethylene glycol adipate) to give a slurry, which is added to a melted polyamide (C) (e.g. nylon 6) and mixed to disperse uniformly. This mixture is molded to give the titled molding in the form of particle, film, fiber, pipe, etc.
    • 目的:长时间保持耐光性的聚酰胺成型体,其包含保持铜离子,载体和聚酰胺的固体颗粒。 构成:0.005〜10重量%的由例如比表面积为150m 2 / g以上的粉末状A型沸石,SiO 2 / Al 2 O 3的摩尔比为14以上的沸石(a)的固体颗粒 ,并使20μm以下的粒径与CuSO 4等的溶液进行离子交换。(b)以铜离子为基准制备保持0.001-0.5重量%的铜 - 沸石(A)。 将组分A与粘度为500-900cP(75℃)的载体(B)捏合,与组分C(例如二甘醇己二酸酯)几乎没有反应性,得到浆料,将其加入熔融的聚酰胺(C )(例如尼龙6)并混合均匀分散。 将该混合物成型为以颗粒,膜,纤维,管等形式的标题模制品