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    • 13. 发明专利
    • Carbon nanotube solidified body connected with silicon carbide and its producing method
    • 碳化硅与碳化硅连接的碳纳米管固化体及其生产方法
    • JP2006312569A
    • 2006-11-16
    • JP2005135995
    • 2005-05-09
    • Tohoku Univ国立大学法人東北大学
    • OMORI MAMORUTAJI KAZUYUKIHASHIDA TOSHIYUKI
    • C01B31/36C01B31/02
    • PROBLEM TO BE SOLVED: To provide a carbon nanotube solidified body connected with silicon carbide where wearing resistance and anti-oxidation property are enhanced by utilizing the high strength and high Young's modulus of carbon nanotubes and to provide its producing method.
      SOLUTION: The method comprises a coating step to produce coated carbon nanotubes by mixing a polycarbosilane of 8-80 wt.% with carbon nanotubes of 92-20 wt.%, a cross-linking reaction step to cross-link the surface of a polycarbosilane coating film and a firing step to heat-treat the cross-linked coated carbon nanotubes at 800-1,600°C and in a non-oxidizing atmosphere. The carbon nanotube solidified body connected with silicon carbide consisting of carbon nanotubes C
      1 -C
      N of 96-30 wt.% and silicon carbide S
      1 -S
      (N-1) of 4-70 wt.% and having a bulk density of 1.3 g/cm
      3 or more is obtained.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决问题:提供一种通过利用碳纳米管的高强度和高杨氏模量来提高耐磨性和抗氧化性能的碳化硅连接的碳纳米管凝固体,并提供其制造方法。 解决方案:该方法包括通过将8-80重量%的聚碳硅烷与92-20重量%的碳纳米管混合来制备涂覆的碳纳米管的涂覆步骤,交联反应步骤以交联表面 的聚碳硅烷涂膜和在800-1,600℃和非氧化气氛下热处理交联的涂覆的碳纳米管的焙烧步骤。 碳纳米管凝固体与碳纳米管(碳纳米管)组成,碳化硅由96〜30重量%构成,碳化硅S SB = 1 / > -S (N-1)为4-70重量%,体积密度为1.3g / cm 3以上。 版权所有(C)2007,JPO&INPIT
    • 15. 发明专利
    • Method for producing formic acid by wet oxidation of biomass
    • 通过生物质氧化生产酸性的方法
    • JP2008273915A
    • 2008-11-13
    • JP2007122674
    • 2007-05-07
    • Hitachi Zosen CorpTohoku Electric Power Co IncTohoku Univ国立大学法人東北大学日立造船株式会社東北電力株式会社
    • TAJI KAZUYUKIENOMOTO HEIJIKINOSHITA MUTSUMIKIN HOUMEIMORIYA TAKEHIKOKISHIDA HISANORI
    • C07C51/21C07B61/00C07C53/02
    • Y02P20/544
    • PROBLEM TO BE SOLVED: To provide a method for producing formic acid by wet oxidation of biomass with which the biomass abundantly present in the natural world is converted into the formic acid in a high yield by utilizing actions of high-temperature and high-pressure water and the biomass can be converted into formic acid under relatively mild conditions as compared with the conventional water in the supercritical state without requiring an expensive noble metal catalyst etc., during the reaction with a result that the method is inexpensive with little load even on the environment because only the water is used as a reaction solvent. SOLUTION: The method for producing formic acid by the wet oxidation of the biomass comprises oxidizing the biomass in alkaline high-temperature and high-pressure water at ≥0.3 M concentration of an alkali substance, thereby selectively degrading the biomass into formic acid and producing formic acid. The biomass is preferably vegetable biomass such as starch, cellulose and wood flour. The temperature of the wet oxidation reaction is preferably 130-350°C and the pressure of the wet oxidation reaction is preferably pressure not lower than the saturated vapor pressure in which hydration can be held for each reaction temperature. COPYRIGHT: (C)2009,JPO&INPIT
    • 待解决的问题:提供一种通过湿式氧化生物质生产甲酸的方法,通过利用高温高的作用,将天然世界中大量存在的生物质以高产率转化为甲酸 与常规的超临界状态的水相比,生物质在相对温和的条件下可以转化成甲酸,而不需要昂贵的贵金属催化剂等,反应过程中结果是方便廉价,负荷少 即使在环境中,因为仅使用水作为反应溶剂。 解决方案:通过生物质的湿氧化生产甲酸的方法包括在碱性物质浓度高于0.3M的碱性高温高压水中氧化生物质,从而选择性地将生物质降解成甲酸 并生产甲酸。 生物质优选为植物生物质如淀粉,纤维素和木粉。 湿式氧化反应的温度优选为130〜350℃,湿式氧化反应的压力优选为不低于在每个反应温度下保持水合的饱和蒸气压的压力。 版权所有(C)2009,JPO&INPIT
    • 16. 发明专利
    • Metal magnetic powder for magnetic recording and method of manufacturing the same
    • 用于磁记录的金属磁粉及其制造方法
    • JP2008270300A
    • 2008-11-06
    • JP2007107631
    • 2007-04-16
    • Dowa Electronics Materials Co LtdDowaエレクトロニクス株式会社Tohoku Univ国立大学法人東北大学
    • TAJI KAZUYUKIYOSHIDA TAKAYUKIGOTO TAKASHINAKAYAMA MASATOSHI
    • H01F1/06G11B5/714
    • PROBLEM TO BE SOLVED: To provide metal magnetic powder of low magnetic viscosity in which even fine particles exhibits orientation. SOLUTION: The metal magnetic powder for magnetic recording composed of particles having a particle length of 10-45 nm, an axial ratio of 2 or more, and round distal end is obtained by a step of producing metal magnetic powder for magnetic recording by sequentially performing a step (elution step) of eluting nonmagnetic component in powder particles into liquid by making a reducing agent act on metal magnetic powder having metal magnetism phase principally comprising Fe or Fe and Co and containing at least one kind of rare earth element (Y is also treated as a rare earth element), Al and Si (hereinafter, referred to "nonmagnetic components") in a liquid containing a complexing agent which can form a complex with at least one kind of nonmagnetic component, a step (re-reduction step) for performing heat treatment in reducing gas atmosphere, and a step (stabilization step) of performing heat treatment in oxidizing gas atmosphere. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供低磁性粘度的金属磁性粉末,其中均匀的细颗粒具有取向性。 解决方案:通过制造用于磁记录的金属磁性粉末的步骤获得由粒径为10-45nm,轴比为2以上的粒子和圆形末端构成的磁记录用金属磁性粉末 通过依次进行通过使还原剂作用于主要包含Fe或Fe和Co并且含有至少一种稀土元素的金属磁相的金属磁性粉末上而将粉末颗粒中的非磁性成分洗脱到液体中的步骤(洗脱步骤) 在含有可与至少一种非磁性成分形成络合物的络合剂的液体中,将Y还被视为稀土元素),Al和Si(以下称为“非磁性成分”), 还原气氛中进行热处理的还原工序)和在氧化气体气氛中进行热处理的工序(稳定工序)。 版权所有(C)2009,JPO&INPIT
    • 18. 发明专利
    • Method for producing silver fine powder coated with organic substance and silver fine powder
    • 生产用有机物质和银粉末涂覆的细小粉末的方法
    • JP2008297580A
    • 2008-12-11
    • JP2007143134
    • 2007-05-30
    • Dowa Electronics Materials Co LtdDowaエレクトロニクス株式会社Tohoku Univ国立大学法人東北大学
    • SATO KIMITAKABARACHANDORAN JAYADEWANTAJI KAZUYUKI
    • B22F1/02B22F9/24H01B13/00
    • B22F1/0062B22F9/24B22F2998/00B22F1/0022
    • PROBLEM TO BE SOLVED: To provide a silver fine powder coated with a protective material by a technique suitable for industrial mass-production, the material having a low molecular weight and enabling the sintering temperature of the silver fine powder to be remarkably reduced than before. SOLUTION: A method for producing the silver fine powder coated with an organic substance has a process where (i) a liquid in which silver grains each coated with a protective material X 1 composed of an organic compound with a molecular weight of 150 to 1,000 and having an unsaturated bond are dispersed into a liquid organic medium A, (ii) a protective material X 2 composed of an organic compound in which the content of carbon in a carbon skeleton is lower than that in the compound composing the protective material X 1 , and (iii) a liquid organic medium B which has the solubility of the protective material 1 thereinhigher than that in the liquid organic medium A are mixed to progress the dissolution of the protective material X 1 into the liquid organic medium B and the sticking of the protective material X 2 to the surface of each silver grain. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了通过适合于工业大规模生产的技术提​​供涂覆有保护材料的银细粉末,具有低分子量且能够显着降低银细粉末的烧结温度的材料 比以前。 < P>解决方案:用有机物涂覆的银细粉末的制造方法具有以下工序:(i)将由有机物构成的保护材料X 1 的银粒子 分子量为150〜1000,具有不饱和键的化合物分散在液体有机介质A中,(ii)由有机化合物构成的保护材料X 2 ,其中碳的含量 碳骨架比构成保护材料X 1 的化合物低,和(iii)具有保护材料 1 的溶解度的液体有机介质B更高 将液体有机介质A混合,使保护材料X 1 溶解到液体有机介质B中,并将保护材料X 2 粘附到 每个银粒的表面。 版权所有(C)2009,JPO&INPIT
    • 19. 发明专利
    • Method for processing hydrogen sulfide, method for producing hydrogen and photocatalytic reactor
    • 加氢硫化氢的方法,生产氢和光催化反应器的方法
    • JP2006307333A
    • 2006-11-09
    • JP2006088477
    • 2006-03-28
    • Nittetsu Mining Co LtdTohoku Univ国立大学法人東北大学日鉄鉱業株式会社
    • MATSUMOTO HIROMICHIKISHIMOTO AKIRATAJI KAZUYUKI
    • C25B11/06B01J19/08B01J19/24B01J27/04B01J33/00B01J35/02C02F1/46C25B1/02
    • Y02P20/135Y02W10/37
    • PROBLEM TO BE SOLVED: To provide a technique capable of decomposing hydrogen sulfide and producing hydrogen efficiently by using a photocatalyst. SOLUTION: In the method for treating hydrogen sulfide and the method for producing hydrogen, a liquid tank having at least a photocatalyst electrode 1 made of photocatalyst and a liquid tank having a metal electrode 2 are separated by a cation exchange film 3, liquid including hydrogen sulfide or organic substance is stored in the liquid tank having the photocatalyst electrode 1, the photocatalyst electrode 1 is electrically connected with the metal electrode 2 and the photocatalyst is exposed to light. An acidic solution is preferably stored in the liquid tank having the metal electrode 2, and the photocatalyst preferably includes metal sulfide and is preferably formed as fine particles having a lamellar nanocapsule structure. A reactor may be an electrolysis cell 11 in which a photoelectrochemical cell is included. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供能够通过使用光催化剂有效地分解硫化氢和产生氢的技术。 解决方案:在硫化氢的处理方法和氢的制造方法中,至少具有由光催化剂构成的光催化剂电极1和具有金属电极2的液体槽的液体槽由阳离子交换膜3分离, 包含硫化氢或有机物质的液体储存在具有光催化剂电极1的液体槽中,光催化剂电极1与金属电极2电连接,光催化剂暴露于光。 酸性溶液优选储存在具有金属电极2的液体罐中,并且光催化剂优选包含金属硫化物,并且优选形成为具有层状纳米胶囊结构的细颗粒。 反应器可以是包含光电化学电池的电解槽11。 版权所有(C)2007,JPO&INPIT