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    • 94. 发明专利
    • PRODUCTION OF TRANSPARENT CONDUCTIVE FILM
    • JPH06320661A
    • 1994-11-22
    • JP13700593
    • 1993-05-17
    • TONEN SEKIYUKAGAKU KK
    • ASO JUNICHIARAI YOSHIHIRO
    • B32B7/02B32B9/00B32B27/06
    • PURPOSE:To provide a transparent conductive film having low resistance and high visible light transmissivity by forming the transparent conductive layer on a plastic substrate at the thermal deterioration temp. of the plastic substrate or lower and subsequently applying specific heat treatment to the conductive layer. CONSTITUTION:A transparent conductive layer is provided to a plastic substrate at the thermal deterioration temp. of the substrate or lower. The transparent conductive layer is formed from metal oxide such as Sn added In2O3, Sb added SnO2 or F added SnO2 by a vapor deposition method, a sputtering method, an ion plating method, a CVD method and a spray method. At this time, the transparent conductive layer is formed at the thermal deterioration temp. of the substrate or lower, for example, at temp. of 100 deg.C or lower. Thereafter, the plastic substrate having the transparent conductive layer provided thereto is heat-treated for 15min at temp. of 80 below 150 deg.C under vacuum of 1Torr or less. By this method, the transparent conductive film having low resistance and high transmissivity can be easily obtained.
    • 99. 发明专利
    • REACTIVE POLYPROPYLENE
    • JPH06172422A
    • 1994-06-21
    • JP35251692
    • 1992-12-10
    • TONEN SEKIYUKAGAKU KK
    • KUCHIKI EIJIFUJITA YUJI
    • C08F8/00C08F255/02
    • PURPOSE:To obtain the subject polymer having printability, adhesion, hydrophilicity, etc., imparted thereto by reacting a graft copolymer prepared by graft copolymerization of polypropylene with a specific modifying monomer with other kinds of monomers reactive with the functional group in the modifying monomer. CONSTITUTION:The objective polymer is obtained by carrying out the graft copolymerization of (A) an unsaturated carboxylic acid (anhydride) [preferably a dicarboxylic acid (anhydride) such as maleic acid], (B) an unsaturated epoxy compound (e.g. glycidyl acrylate), (C) an unsaturated amine or an unsaturated amide (preferably acrylamide) and (D) an unsaturated compound containing hydroxyl group (preferably allyl alcohol) or (E) a vinyloxazoline-based compound (preferably 2-vinyl-2-oxazoline) with polypropylene and making the resultant graft copolymer react with a compound which is a kind different from the grafted compound and composed of one of the components (A) to (E) except the combination of the components (C) with (E) and the components (D) with (E).
    • 100. 发明专利
    • MULTI-LAYERED RESIN FUEL TANK
    • JPH06171042A
    • 1994-06-21
    • JP35123592
    • 1992-12-07
    • TONEN SEKIYUKAGAKU KK
    • MATSUMOTO NORIYAYAMAZAKI MASAYUKI
    • B32B27/08B32B27/32
    • PURPOSE:To make it possible to improve impact resistance by a method wherein polyamide-based resin layer contains the specified wt.% of polyamide and the specified wt.% of modified olefin-based elastomer, which is prepared by graft- polymerizing the specified wt.% of glycidyl compound represented by the specified general formula to some part of or entire olefin-based elastomer. CONSTITUTION:The multi-layered resin fuel tank concerned is produced by laminating high density polyethylene layer and polyamide-based resin layer to each other through high density polyethylene layer modified by unsaturated carboxylic acid or its derivative. The polyamide-based resin layer in the tank is made of composition containing 65-95wt.% of polyamide and 5-35wt.% of modified olefin-based elastomer, which is prepared by graft-polymerizing 0.01-25wt.% of glycidyl compound represented by the formula, in which R represents hydrogen atom or alkyl group having the number of carbon atoms of 6-20, Ar is aromatic hydrocarbon, which has at least one glycidyloxy group and the number of carbon atoms of 6-20, (m) represents the integers from 1 through 4.